3-BROMO-4-CHLOROTOLUENE

Product Name: 3-BROMO-4-CHLOROTOLUENE
CAS No.: 57310-39-1
Chemical Name: 3-BROMO-4-CHLOROTOLUENE
Synonyms: 3-BROMO-4-CHLOROTOLUENE;4-Chluoro-3-bromotoluene;3 3-Bromo-4-Chloro Toluene;Benzene, 2-bromo-1-chloro-4-methyl-
CBNumber: CB0468671
Molecular Formula: C7H6BrCl
Formula Weight: 205.48
MOL File: 57310-39-1.mol

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3-BROMO-4-CHLOROTOLUENE Property

Boiling point:: 112 °C
Density: 1,55 g/cm³
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform, Methanol (Slightly)
form: liquid
Specific Gravity: 1.55
color: Colourless
InChI: InChI=1S/C7H6BrCl/c1-5-2-3-7(9)6(8)4-5/h2-4H,1H3
InChIKey: UWXPTVKKHVOZLJ-UHFFFAOYSA-N
SMILES: C1(Cl)=CC=C(C)C=C1Br
CAS DataBase Reference: 57310-39-1(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,N,Xn
Risk Statements: 22-51/53
Safety Statements: 61
RIDADR: UN 2811 6.1 / PGIII
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 2903998090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC

Product number: B682495
Product name: 2-Bromo-1-chloro-4-methyl-benzene
Packaging: 5g
Price: $130
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB43405
Product name: 3-Bromo-4-chlorotoluene
Packaging: 50g
Price: $140.5
Updated: 2021/12/16

Apolloscientific

Product number: OR6447
Product name: 3-Bromo-4-chlorotoluene
Packaging: 100g
Price: $189
Updated: 2021/12/16

SynQuest Laboratories

Product number: 1700-D-X8
Product name: 3-Bromo-4-chlorotoluene
Packaging: 100g
Price: $208
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB43405
Product name: 3-Bromo-4-chlorotoluene
Packaging: 100g
Price: $225
Updated: 2021/12/16

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3-BROMO-4-CHLOROTOLUENE Chemical Properties,Usage,Production

Uses

2-Bromo-1-chloro-4-methyl-benzene is a useful synthetic intermediate. It can be used to synthesize N-heterocycle-fused phenanthridines via palladium-catalyzed tandem N-H/C-H arylation of aryl-N-heteroarenes with dihaloarenes. It can also be used to synthesize substituted fluorenes.

Synthesis

583-68-6

57310-39-1

General procedure for the synthesis of 4-chloro-3-bromotoluene from 2-bromo-4-methylaniline: tert-butyl nitrite (48 mmol, 6.34 mL) and anhydrous copper(II) chloride (60 mmol, 8.07 g) were mixed at 65 °C in anhydrous acetonitrile (100 mL). 2-Bromo-4-methylaniline (30 mmol) was slowly added under vigorous stirring for 30 min. Subsequently, the reaction mixture was continued to be stirred at 65 °C for 2 hours. After completion of the reaction, the mixture was cooled, poured into 20% hydrochloric acid (400 mL) and extracted with ether (3 x 120 mL). The organic phases were combined, washed with brine (100 mL), dried over anhydrous Na2SO4 and the solvent was subsequently evaporated. The crude product was purified by fast column chromatography.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2016, vol. 26, # 22, p. 5568 - 5572

3-BROMO-4-CHLOROTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-4-CHLOROTOLUENE Suppliers

China 151 Germany 2 India 6 United Kingdom 10 United States 22 Global 191

Shanghai Harvest Chemical Industrial Co., Ltd.

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View Lastest Price from 3-BROMO-4-CHLOROTOLUENE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: 3-BROMO-4-CHLOROTOLUENE 57310-39-1
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-08-11

Career Henan Chemical Co

Product: 3-BROMO-4-CHLOROTOLUENE 57310-39-1
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: JD 603
Release date: 2019-09-01

Career Henan Chemical Co

Product: 3-BROMO-4-CHLOROTOLUENE 57310-39-1
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: JD 624
Release date: 2019-09-01

57310-39-1, 3-BROMO-4-CHLOROTOLUENERelated Search:

3-BROMO-2,4-DICHLOROTOLUENE Pigment Green 36 3-BROMO-4-CHLOROTOLUENE 4'-BROMO-3-CHLOROPROPIOPHENONE 3-Bromo-4-chlorobenzotrifluoride 5-BROMO-4-CHLORO-2-FLUOROBENZOIC ACID 2-BROMO-3-CHLOROTOLUENE 2-BROMO-4-CHLOROTOLUENE 6-Bromo-2-chlorotoluene,2-BROMO-6-CHLOROTOLUENE 2-bromo-à-chlorotoluene,2-BROMOBENZYL CHLORIDE / 2-BROMO-ALPHA-CHLOROTOLUENE,2-Bromo-alpha-chlorotoluene 6-BROMO-3-CHLOROTOLUENE,2-BROMO-5-CHLOROTOLUENE 99%,2-BROMO-5-CHLOROTOLUENE 4-BROMO-2-CHLOROTOLUENE,4-Bromo-2-chlorotoluene,98% 4-Amino-5-bromo-2-chlorotoluene 6-Amino-3-bromo-2-chlorotoluene ALPHA-BROMO-4-CHLOROTOLUENE,à-bromo-4-chlorotoluene 3-BROMO-ALPHA-CHLOROTOLUENE,3-BROMOBENZYL CHLORIDE / 3-BROMO-ALPHA-CHLOROTOLUENE,3-bromo-à-chlorotoluene,3-bromo-α-chlorotoluene 4-BROMO-3-CHLOROTOLUENE 4-bromo-à-chlorotoluene,4-Bromobenzyl chloride/4-Bromo-alpha-chlorotoluene,4-BROMO-ALPHA-CHLOROTOLUENE

3-BROMO-4-CHLOROTOLUENE

3 3-Bromo-4-Chloro Toluene

4-Chluoro-3-bromotoluene

Benzene, 2-bromo-1-chloro-4-methyl-

57310-39-1

Aromatic Halides (substituted)

Halogen toluene

Bromine Compounds

Chlorine Compounds