4-Bromobenzyl chloride
- Product Name
- 4-Bromobenzyl chloride
- CAS No.
- 589-17-3
- Chemical Name
- 4-Bromobenzyl chloride
- Synonyms
- 1-Bromo-4-(chloromethyl)benzene;P-BROMOBENZYL CHLORIDE;4-BROMOBENZYL CHLORIDE;4-bromo-à-chlorotoluene;4-Bromo-α-chlorotoluene;α-Chloro-4-bromotoluene;4-Bromobenzylchloride,97%;4-Bromobenzyl chloride,98%;4-Bromobenzyl Chloride >4-BROMO-ALPHA-CHLOROTOLUENE
- CBNumber
- CB6708142
- Molecular Formula
- C7H6BrCl
- Formula Weight
- 205.48
- MOL File
- 589-17-3.mol
4-Bromobenzyl chloride Property
- Melting point:
- 36-40 °C
- Boiling point:
- 136-139 °C (27 mmHg)
- Density
- 1.3431 (rough estimate)
- refractive index
- 1.5750 (estimate)
- Flash point:
- 106-107°C/10mm
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder and Granules
- color
- White
- Water Solubility
- Insoluble in water.
- Merck
- 14,1410
- BRN
- 6123220
- InChI
- InChI=1S/C7H6BrCl/c8-7-3-1-6(5-9)2-4-7/h1-4H,5H2
- InChIKey
- BSIIGUGKOPPTPZ-UHFFFAOYSA-N
- SMILES
- C1(Br)=CC=C(CCl)C=C1
- CAS DataBase Reference
- 589-17-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, 1-bromo-4-(chloromethyl)-(589-17-3)
Safety
- Hazard Codes
- C
- Risk Statements
- 36/37-34
- Safety Statements
- 45-36/37/39-25-26
- RIDADR
- 3261
- WGK Germany
- 3
- Hazard Note
- Corrosive/Lachrymator
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29039990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- 726362
- Product name
- 4-Bromobenzyl chloride
- Purity
- ≥97.0% (GC)
- Packaging
- 5g
- Price
- $36.3
- Updated
- 2023/06/20
- Product number
- 726362
- Product name
- 4-Bromobenzyl chloride
- Purity
- ≥97.0% (GC)
- Packaging
- 25g
- Price
- $140
- Updated
- 2023/06/20
- Product number
- B3042
- Product name
- 4-Bromobenzyl Chloride
- Packaging
- 5G
- Price
- $17
- Updated
- 2025/07/31
- Product number
- B3042
- Product name
- 4-Bromobenzyl Chloride
- Packaging
- 25G
- Price
- $49
- Updated
- 2025/07/31
- Product number
- B810748
- Product name
- 4-Bromobenzyl chloride
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
4-Bromobenzyl chloride Chemical Properties,Usage,Production
Chemical Properties
light yellow crystal powder to light yellow liqui
Uses
4-Bromobenzyl chloride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.
Synthesis
873-75-6
589-17-3
General procedure for the synthesis of 4-bromobenzyl chloride from 4-bromobenzyl alcohol: 4-bromobenzyl alcohol (0.6 g, 0.6 mmol) and dichloromethane (5 mL) were added to a round bottom flask. After stirring for 10 min, oxalyl chloride or oxalyl bromide (0.6 mmol) was slowly added. The reaction mixture was magnetically stirred at room temperature. After the gas was released, 4-bromobenzyl alcohol (0.5 mmol) was added and the reaction mixture was heated to reflux. The progress of the reaction was monitored by TLC and after completion of the reaction, the mixture was cooled to room temperature and filtered. The solid on the funnel was washed with dichloromethane (3 x 10 mL), the filtrate was combined and concentrated under reduced pressure. The purity of the resulting 4-bromobenzyl chloride was confirmed by 1H NMR and 13C NMR spectral analysis.
Purification Methods
Crystallise the chloride from EtOH and distil it in a vacuum. [Beilstein 5 IV 832.] LACHRYMATORY.
References
[1] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 1397 - 1405
[2] Organic Letters, 2013, vol. 15, # 1, p. 108 - 111
[3] Organic and Biomolecular Chemistry, 2013, vol. 11, # 24, p. 4016 - 4024
[4] Bulletin of the Korean Chemical Society, 2010, vol. 31, # 11, p. 3434 - 3436
[5] Organic Letters, 2018, vol. 20, # 10, p. 3061 - 3064
4-Bromobenzyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Bromobenzyl chloride manufacturers
- Product
- 4-Bromobenzyl chloride 589-17-3
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- Customise
- Release date
- 2025-11-11
- Product
- 4-Bromobenzyl chloride 589-17-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-02