4'-Bromoacetophenone

Product Name: 4'-Bromoacetophenone
CAS No.: 99-90-1
Chemical Name: 4'-Bromoacetophenone
Synonyms: 2-BROMO-1-(4-BROMOPHENYL)ETHAN-1-ONE;PBPB;1-(4-Bromophenyl)ethanone;p-Bromoacetophenone;P-BROMOPHENACYL BROMIDE;para-BROMOACETOPHENONE;p-BROMOACETOPHENONE pure;4-BroMobenz;ROMOACETOPHENONE;AKOS BBS-00000865
CBNumber: CB2204949
Molecular Formula: C8H7BrO
Formula Weight: 199.04
MOL File: 99-90-1.mol

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4'-Bromoacetophenone Property

Melting point:: 108-110 °C(lit.)
Boiling point:: 255 °C(lit.)
Density: 1.64
refractive index: 1.5540 (estimate)
Flash point:: >230 °F
storage temp.: Store below +30°C.
solubility: methanol: 0.1 g/mL, clear
form: Crystals or Crystalline Flakes
color: White to light yellow
Water Solubility: Soluble in Chloroform. Insoluble in water.
Merck: 14,1403
BRN: 386015
InChIKey: WYECURVXVYPVAT-UHFFFAOYSA-N
CAS DataBase Reference: 99-90-1(CAS DataBase Reference)
NIST Chemistry Reference: Ethanone, 1-(4-bromophenyl)-(99-90-1)
EPA Substance Registry System: Ethanone, 1-(4-bromophenyl)- (99-90-1)

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Safety

Hazard Codes: C,Xi,Xn
Risk Statements: 34-36/38-42/43-36/37/38-22
Safety Statements: 26-36/37/39-45-22-36/37
RIDADR: UN 3261 8/PG 2
WGK Germany: 2
RTECS: AM6950000
F: 19-21
Hazard Note: Irritant
TSCA: Yes
HS Code: 29147090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: B56404
Product name: 4′-Bromoacetophenone
Purity: 98%
Packaging: 25g
Price: $33.3
Updated: 2025/07/31

Sigma-Aldrich

Product number: B56404
Product name: 4′-Bromoacetophenone
Purity: 98%
Packaging: 100g
Price: $82.7
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.21968
Product name: 4′-Bromoacetophenone
Purity: for synthesis
Packaging: 25G
Price: $44.4
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.21968
Product name: 4′-Bromoacetophenone
Purity: for synthesis
Packaging: 100G
Price: $99
Updated: 2025/07/31

TCI Chemical

Product number: B0537
Product name: 4'-Bromoacetophenone
Purity: >98.0%(GC)
Packaging: 25g
Price: $33
Updated: 2025/07/31

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4'-Bromoacetophenone Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystals. soluble in alcohol, ether, glacial acetic acid, benzene, carbon disulfide and petroleum ether, insoluble in water. Easy to volatilize with water vapor.

Uses

4'-Bromoacetophenone is an important organic synthesis intermediate, widely used in synthetic medicine, pesticides, dyes, flavors and fragrances, perfumes, Intermediates of Liquid Crystals etc.

Uses

Labeled 4?-Bromoacetophenone possess activity against positive phototaxis of Chlamydomonas cells. A fundamental starting material for organic synthesis.

Preparation

4'-Bromoacetophenone is synthesized by the reaction of bromobenzene and acetic anhydride in the presence of aluminum trichloride.
Add bromobenzene and dry carbon disulfide into the reactor, put in powdered anhydrous aluminum trichloride, heat until it starts to reflux, stop heating, add acetic anhydride dropwise, and then reflux for 1 hour after adding, steam out carbon disulfide, and put it while it is still hot. The reactant was poured into the hydrochloric acid ice-water mixture, filtered to dryness, and distilled under reduced pressure to obtain p-bromoacetophenone.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 5400, 1986 DOI: 10.1021/jo00376a064
Tetrahedron Letters, 26, p. 4657, 1985 DOI: 10.1016/S0040-4039(00)98778-1

Purification Methods

Crystallise it from EtOH, MeOH or from pet ether (b 80-100o). [Tanner J Org Chem 52 2142 1987, Beilstein 7 IV 647.]

4'-Bromoacetophenone Preparation Products And Raw materials

Raw materials

Bromobenzene Aluminium chloride hexahydrate

Preparation Products

ETHYL 4-ACETYLBENZOATE 4-Acetyl-2-fluorobiphenyl 1-(2-amino[1,1'-biphenyl]-4-yl)ethan-1-one 2,4'-Dibromoacetophenone 1-(2-NITRO-BIPHENYL-4-YL)-ETHANONE 1,3,5-Tris(4-bromophenyl)benzene 4-Bromomandelic acid 5-(4-BROMO-PHENYL)-3H-THIENO[2,3-D]PYRIMIDIN-4-ONE ETHYL 2-AMINO-4-(4-BROMOPHENYL)-3-THIOPHENECARBOXYLATE 2-(4-BROMO-PHENYL)-1H-INDOLE 4-Acetylphenylboronic acid 4-(4-BROMOPHENYL)-1,2,3-THIADIAZOLE 4-Bromophenethyl alcohol

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4'-Bromoacetophenone Suppliers

Americas 1 Belgium 3 Canada 5 China 377 Europe 3 France 2 Germany 6 India 73 Italy 1 Japan 9 Russia 1 Slovakia 1 Switzerland 3 The Netherlands 1 Ukraine 1 United Kingdom 23 United States 52 Global 562

Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd.

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View Lastest Price from 4'-Bromoacetophenone manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: 4'-Bromoacetophenone 99-90-1
Price: US $100.00-75.00/ton
Min. Order: 1ton
Purity: 99%
Supply Ability: 5000
Release date: 2024-08-23

Hebei Chuanghai Biotechnology Co., Ltd

Product: 4'-Bromoacetophenone 99-90-1
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

Henan Aochuang Chemical Co.,Ltd.

Product: 4'-Bromoacetophenone 99-90-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-27

99-90-1, 4'-BromoacetophenoneRelated Search:

Acetophenone 4'-Methoxyacetophenone 3-Nitroacetophenone Acetylacetone Bromobenzene L-PICEIN 3-Aminoacetophenone Acetyl chloride 4'-Chloroacetophenone 4'-Hydroxyacetophenone 4-Nitroacetophenone 2',4'-Dichloroacetophenone 4'-Methylacetophenone 3-BROMOACETOPHENONE,3'-BROMOACETOPHENONE,M-BROMOACETOPHENONE,BROMOACETOPHENONE-3 OMEGA-BROMOACETOPHENONE,-Bromoacetophenon 4,4'-Dibromobenzophenone 3-Nitro-4-bromoacetophenone 4-BROMOBENZOPHENONE

p-BROMOACETOPHENONE pure

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DIBROMOACETOPHENONE-2,4

GSK-3BETA INHIBITOR VII

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ALPHA,4'-DIBROMOACETOPHENONE

ALPHA-4-DIBROMOACETOPHENONE

ALPHA,P-DIBROMOACETOPHENONE

AKOS BBS-00000865

4,OMEGA-DIBROMOACETOPHENONE

4-Bromophenaeyl bromide

p-Bromoacetophenones

4'-Bromoacetophenone 1-(4-Bromophenyl)ethanone 1-Acetyl-4-Bromobenzene

4-Bromoacetophenone99%

4-BromoacetophenoneForSynthesis

4-Bromoacetophenone,98%

4-Bromophenyl methyl ketone

p-Acetylbromobenzene

p-Bromphenyl methyl ketone

1-(4-Bromophenyl)ethane-1-one

Methyl 4-bromophenyl ketone

1-acytyl-4-bromobenzene

4′-Bromoacetophenone,1-Acetyl-4-bromobenzene

Of broMoacetophenone

1-(4-Bromophenyl)ethan-1-one, 1-(4-Bromophenyl)-1-oxoethane

The broMine acetophenone

1-(p-BroMophenyl)ethanone

1-BroMo-4-acetylbenzene

4-Acetyl-1-broMobenzene

4-AcetylbroMobenzene

4-Acetylphenyl BroMide

4-BroMobenz

1-(4-broMophenyl)-1-ethanone

OMEGA-BROMOACETOPHENONE

PBPB

P-BROMOPHENACYL BROMIDE

1-(4-bromophenyl)-ethanon

Acetophenone, 4'-bromo-

Ethanone,1-(4-bromophenyl)-

para-BROMOACETOPHENONE

4''-BROMOACETOPHENONE 99%

1-(4-Bromophenyl)ethanone

1-Acetyl-4-bromobenzene

4'-Bromoacetophenone

p-Bromoacetophenone

4’-Bromoacetophene

4'-Bromoacetophenone, 98%, for synthesis

4'-Bromoacetophenone &gt

ROMOACETOPHENONE

p-Bromoacetophenone,98%

4-Bromoacetophenone pure, 98%

4'-Bromacetophenon

4′-Bromoacetophenone, CAS 99-90-1

99-90-1

Derivatization agents

Ketones

Luminescent Compounds/Detection

Organic Building Blocks