ChemicalBook > CAS DataBase List > 4-Bromobenzyl chloride

4-Bromobenzyl chloride

Product Name
4-Bromobenzyl chloride
CAS No.
589-17-3
Chemical Name
4-Bromobenzyl chloride
Synonyms
1-Bromo-4-(chloromethyl)benzene;P-BROMOBENZYL CHLORIDE;4-BROMOBENZYL CHLORIDE;4-bromo-à-chlorotoluene;4-Bromo-α-chlorotoluene;α-Chloro-4-bromotoluene;4-Bromobenzylchloride,97%;4-Bromobenzyl chloride,98%;4-Bromobenzyl Chloride >4-BROMO-ALPHA-CHLOROTOLUENE
CBNumber
CB6708142
Molecular Formula
C7H6BrCl
Formula Weight
205.48
MOL File
589-17-3.mol
More
Less

4-Bromobenzyl chloride Property

Melting point:
36-40 °C
Boiling point:
136-139 °C (27 mmHg)
Density 
1.3431 (rough estimate)
refractive index 
1.5750 (estimate)
Flash point:
106-107°C/10mm
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder and Granules
color 
White
Water Solubility 
Insoluble in water.
Merck 
14,1410
BRN 
6123220
InChI
InChI=1S/C7H6BrCl/c8-7-3-1-6(5-9)2-4-7/h1-4H,5H2
InChIKey
BSIIGUGKOPPTPZ-UHFFFAOYSA-N
SMILES
C1(Br)=CC=C(CCl)C=C1
CAS DataBase Reference
589-17-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-4-(chloromethyl)-(589-17-3)
More
Less

Safety

Hazard Codes 
C
Risk Statements 
36/37-34
Safety Statements 
45-36/37/39-25-26
RIDADR 
3261
WGK Germany 
3
Hazard Note 
Corrosive/Lachrymator
HazardClass 
8
PackingGroup 
III
HS Code 
29039990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
726362
Product name
4-Bromobenzyl chloride
Purity
≥97.0% (GC)
Packaging
5g
Price
$36.3
Updated
2023/06/20
Sigma-Aldrich
Product number
726362
Product name
4-Bromobenzyl chloride
Purity
≥97.0% (GC)
Packaging
25g
Price
$140
Updated
2023/06/20
TCI Chemical
Product number
B3042
Product name
4-Bromobenzyl Chloride
Packaging
5G
Price
$17
Updated
2025/07/31
TCI Chemical
Product number
B3042
Product name
4-Bromobenzyl Chloride
Packaging
25G
Price
$49
Updated
2025/07/31
TRC
Product number
B810748
Product name
4-Bromobenzyl chloride
Packaging
100mg
Price
$60
Updated
2021/12/16
More
Less

4-Bromobenzyl chloride Chemical Properties,Usage,Production

Chemical Properties

light yellow crystal powder to light yellow liqui

Uses

4-Bromobenzyl chloride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Synthesis

873-75-6

589-17-3

General procedure for the synthesis of 4-bromobenzyl chloride from 4-bromobenzyl alcohol: 4-bromobenzyl alcohol (0.6 g, 0.6 mmol) and dichloromethane (5 mL) were added to a round bottom flask. After stirring for 10 min, oxalyl chloride or oxalyl bromide (0.6 mmol) was slowly added. The reaction mixture was magnetically stirred at room temperature. After the gas was released, 4-bromobenzyl alcohol (0.5 mmol) was added and the reaction mixture was heated to reflux. The progress of the reaction was monitored by TLC and after completion of the reaction, the mixture was cooled to room temperature and filtered. The solid on the funnel was washed with dichloromethane (3 x 10 mL), the filtrate was combined and concentrated under reduced pressure. The purity of the resulting 4-bromobenzyl chloride was confirmed by 1H NMR and 13C NMR spectral analysis.

Purification Methods

Crystallise the chloride from EtOH and distil it in a vacuum. [Beilstein 5 IV 832.] LACHRYMATORY.

References

[1] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 1397 - 1405
[2] Organic Letters, 2013, vol. 15, # 1, p. 108 - 111
[3] Organic and Biomolecular Chemistry, 2013, vol. 11, # 24, p. 4016 - 4024
[4] Bulletin of the Korean Chemical Society, 2010, vol. 31, # 11, p. 3434 - 3436
[5] Organic Letters, 2018, vol. 20, # 10, p. 3061 - 3064

4-Bromobenzyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-Bromobenzyl chloride Suppliers

Americas 1 Belgium 1 China 135 Europe 3 Germany 2 India 5 Japan 2 Slovakia 1 Switzerland 1 Ukraine 1 United Kingdom 13 United States 20 Global 185
Qingzhou dafeng import and export Co. LTD
Tel
16773308882
Email
927608786@qq.com
Country
China
ProdList
3051
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15838
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
Tel
+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
Country
China
ProdList
11598
Advantage
64
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9883
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Beijing Eternalchem Co,. Ltd.
Tel
010-59484199 18611897322
Email
sales@eternalchem.com
Country
China
ProdList
4383
Advantage
60
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Beijing Taiya Jie Technology Development Co., Ltd.
Tel
021-33690831-8001 13552411790
Fax
021-33690831
Email
postmaster@tyjchem.cn
Country
China
ProdList
1542
Advantage
55
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Candia Thamtech Company Limited
Tel
0371-86615086 18203638366 0371-86159066 13526786601
Fax
0371-86159066
Country
China
ProdList
2015
Advantage
60
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9899
Advantage
55
Wuxi Zhangkun Biochemical Technology Co., Ltd.
Tel
+86 0510-85629785
Fax
+86 0510-85625359
Country
China
ProdList
2327
Advantage
58
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9979
Advantage
55
Huainan Kedi Chemical Factory
Tel
0554-2106669
Fax
0554-2666215
Email
sales1@kedichem.com
Country
China
ProdList
4924
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
13350
Advantage
58
Wuxi Zhongkun Biochemical Technology Co., Ltd.
Tel
0510-85629785 18013409632
Fax
051085625359
Email
sales@reading-chemicals.com
Country
China
ProdList
15178
Advantage
58
Hangzhou J&H Chemical Co., Ltd.
Tel
0571-87396432
Fax
0571-87396431
Email
sales@jhechem.com
Country
China
ProdList
14912
Advantage
59
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66028182 18626450290
Email
yftan@aikonchem.com
Country
China
ProdList
16679
Advantage
50
Chengdu RunZeBenTu Chemical Co., Ltd
Tel
13096311329 028-88469284 616445927
Fax
028-88469284
Email
616445927@qq.com
Country
China
ProdList
2874
Advantage
50
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51395
Advantage
80
AN PharmaTech Co Ltd
Tel
86(21)68097365
Fax
86(21)33321566
Email
sales@anpharma.net
Country
China
ProdList
4891
Advantage
55
Alta Scientific Co., Ltd.
Tel
022-6537-8550 15522853686
Fax
022-2532-9655
Email
sales@altasci.com.cn
Country
China
ProdList
4511
Advantage
55
Chengdu Research Accelerators Technology Co., Ltd.
Tel
028-64353063
Fax
028-64353063 QQ:784253935
Email
reacchemical@163.com
Country
China
ProdList
5253
Advantage
58
Chengdu RunZeBenTu Chemical Co., Ltd
Tel
028-88469284 18000562381
Email
rzbtsj@163.com
Country
China
ProdList
9951
Advantage
56
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
6687
Advantage
55
Nanjing Vital Chemical Co., Ltd.
Tel
025-87193546 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
9021
Advantage
60
ShangHai Siyan Biological Technology Co., Ltd.
Tel
021-50908862，442785678，326799392 18721037013
Fax
021-50908862
Email
siyansales@126.com
Country
China
ProdList
9627
Advantage
58
Shanghai Xilong Biochemical Technology Co., Ltd.
Tel
021-52907766-8042
Fax
021-52906523
Country
China
ProdList
9941
Advantage
58
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20794
Advantage
60
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Chengdu Synguider Technology Co., Ltd.
Tel
400-086-3412 028-85062459
Fax
028-85062459
Email
synguider@163.com
Country
China
ProdList
3295
Advantage
55
Shanghai CR Corporation Limited
Tel
13062833949; 4006653949 4006653949
Fax
QQ: 2136646215
Email
fred.wen@crcorporation.cn
Country
China
ProdList
9755
Advantage
58
JinJin Le Chemical Co., Ltd
Tel
18001959627(微信同号) 18001959627
Email
jjlchem2@163.com
Country
China
ProdList
9981
Advantage
58
Hangzhou Molcore Biopharmatech Co.,Ltd
Tel
400-711-5280 86-571-81025280
Fax
86-571-85806285
Email
sales@molcore.com
Country
China
ProdList
9967
Advantage
58
Shanghai Zhen Li Biological Technology Co., Ltd
Tel
021-16621358918; 18516310516
Fax
13045646768
Email
zhenlipharma888@163.com
Country
China
ProdList
19035
Advantage
58
Capot Chemical Co.,Ltd.
Tel
+86-（0）57185586718; +8613336195806
Fax
+86-571-85864795
Email
sales@capot.com
Country
China
ProdList
29735
Advantage
60
More
Less

View Lastest Price from 4-Bromobenzyl chloride manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
4-Bromobenzyl chloride 589-17-3
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-11-11
Career Henan Chemical Co
Product
4-Bromobenzyl chloride 589-17-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-02

589-17-3, 4-Bromobenzyl chlorideRelated Search:

Benzyl chloroformate Calcium chloride 1-Bromo-3-chloro-5,5-dimethylhydantoin Polyvinyl chloride Bromoxynil octanoate 4-Bromobenzoic acid Sulfuryl chloride Ferric chloride 4-Bromomethylbenzoic acid 2-Bromobenzonitrile 4'-Bromoacetophenone 4'-Bromopropiophenone 4-Bromobenzaldehyde 3-Chlorobenzyl chloride Choline chloride Bromobenzene 2-Bromofluorobenzene Benzene

  • 4-Bromo-α-chlorotoluene
  • 1-Bromo-4-(chloromethyl)benzene, 4-Bromo-alpha-chlorotoluene
  • 4-Bromobenzyl chloride >=97.0% (GC)
  • 1-Bromo-4-(chloromethyl)benzene
  • 4-BROMOBENZYL CHLORIDE
  • 4-BROMO-ALPHA-CHLOROTOLUENE
  • P-BROMOBENZYL CHLORIDE
  • 4-Bromobenzyl chloride/4-Bromo-alpha-chlorotoluene
  • 4-Bromobenzylchloride,97%
  • Benzene, 1-bromo-4-(chloromethyl)-
  • 4-bromo-à-chlorotoluene
  • α-Chloro-4-bromotoluene
  • 4-Bromobenzyl chloride,98%
  • 4-Bromobenzyl chloride Solution, 1000ppm
  • 4-Bromobenzyl Chloride &gt
  • 589-17-3