ChemicalBook > CAS DataBase List > 1,8-Diaminonaphthalene

1,8-Diaminonaphthalene

Product Name
1,8-Diaminonaphthalene
CAS No.
479-27-6
Chemical Name
1,8-Diaminonaphthalene
Synonyms
Naphthalene-1,8-diamine;1,8-NAPHTHALENEDIAMINE;1,8-Diaminonaphthalene,99%;1,8-DiaminonaphthaL;8-Diaminonaphthalene;1,8-Diaminonaphthale;1,8-Naphthylendiamin;1,8-DIAMINONAPHTHALONE;1,8-Diaminonaphthalane;DIAMINONAPHTHALENE-1,8
CBNumber
CB2728423
Molecular Formula
C10H10N2
Formula Weight
158.2
MOL File
479-27-6.mol
More
Less

1,8-Diaminonaphthalene Property

Melting point:
60-65 °C (lit.)
Boiling point:
205 °C/12 mmHg (lit.)
Density 
1.1265
vapor pressure 
0.011Pa at 25℃
refractive index 
1.6829
Flash point:
205°C/12mm
storage temp. 
Store below +30°C.
solubility 
methanol: soluble
form 
Chunks or Crystalline Mass
pka
4.46±0.10(Predicted)
color 
Grayish-red to gray or dark brown
Water Solubility 
slightly soluble
Merck 
14,6372
BRN 
742841
Stability:
Air Sensitive
InChIKey
YFOOEYJGMMJJLS-UHFFFAOYSA-N
LogP
1.335
CAS DataBase Reference
479-27-6(CAS DataBase Reference)
NIST Chemistry Reference
1,8-Naphthalenediamine(479-27-6)
EPA Substance Registry System
1,8-Naphthalenediamine (479-27-6)
More
Less

Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-40-43-36/37/38
Safety Statements 
36/37-36/37/39-26-24-36
RIDADR 
2811
WGK Germany 
3
F 
8
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29215940
Toxicity
LD50 orally in Rabbit: 800 mg/kg
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D21405
Product name
1,8-Diaminonaphthalene
Purity
99%
Packaging
5g
Price
$37.6
Updated
2024/03/01
Sigma-Aldrich
Product number
D21405
Product name
1,8-Diaminonaphthalene
Purity
99%
Packaging
100g
Price
$110
Updated
2024/03/01
Sigma-Aldrich
Product number
8.06206
Product name
1,8-Naphthalenediamine
Purity
for synthesis
Packaging
100g
Price
$91.1
Updated
2024/03/01
Sigma-Aldrich
Product number
8.06206
Product name
1,8-Naphthalenediamine
Purity
for synthesis
Packaging
500g
Price
$300
Updated
2024/03/01
TCI Chemical
Product number
D0102
Product name
1,8-Diaminonaphthalene
Purity
>98.0%(T)
Packaging
25g
Price
$45
Updated
2024/03/01
More
Less

1,8-Diaminonaphthalene Chemical Properties,Usage,Production

Chemical Properties

Off white powder. 1,8-Naphthalenediamine [479-27-6]. 1,8-diaminonaphthalene, Deltamin, C10H10N2, Mr 158.2, turns brown in air even in the absence of light. Its solutions give a brown precipitate on addition of iron(III) chloride. Treatment with boiling aqueous sodium bisulfite followed by addition of alkali gives 8-amino-1-hydroxynaphthalene. Sulfonation takes place in the 4- position. Coupling with azo compounds also occurs in the 4-position, but in almost neutral solution 4,5-bis coupling can occur. The resulting bisazo compound is reduced with SnCl2– HCl to give 1,4,5,8-tetraaminonaphthalene.

Uses

Lubricating-oil antioxidant, analytical reagent

Uses

1,8-Diaminonaphthalene is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. 1,8-Naphthalenediamine has minor use as an antioxidant for lubricating oils and as an analytical reagent for the detection of selenium and nitrites.

Production Methods

Reduction of 1,8-dinitronaphthalene is carried out with iron and acetic acid in xylene or by catalytic hydrogenation.

Flammability and Explosibility

Non flammable

Purification Methods

Crystallise 1,8-diaminonaphthalene from water or aqueous EtOH, and sublime it in a vacuum. The N,N'-dimethyl derivative [20734-56-9] has m 103-104o and pK2 5 5.61, the N,N,N'-trimethyl-derivative [20734-57-0] has m 29-30o and pK2 5 6.43. [Hodgson et al. J Chem Soc 202 1945, Beilstein 13 IV 344.]

1,8-Diaminonaphthalene Preparation Products And Raw materials

Raw materials

Preparation Products

Solvent Red 179 Solvent Red 135 C.I. 564100
More
Less

1,8-Diaminonaphthalene Suppliers

Americas 1 Belgium 3 China 299 Europe 4 France 3 Germany 9 India 15 Japan 8 Norway 1 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 1 Ukraine 2 United Kingdom 13 United States 53 Global 416
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
AbaChemScene
Tel
732-484-9848
Fax
888-484-5008
Email
sales@chemscene.com
Country
United States
ProdList
3982
Advantage
60
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Aceschem Inc.
Tel
+1-817863-6948 +1-（817）863-6948
Email
sales@aceschem.com
Country
United States
ProdList
19632
Advantage
58
Alfa Chemistry
Tel
Email
info@alfa-chemistry.com
Country
United States
ProdList
2344
Advantage
58
Aston Chemical
Tel
13000000000
Email
sales@astonchem.com
Country
United States
ProdList
1634
Advantage
58
Sphinx Scientific Laboratory, LLC
Tel
--
Fax
--
Email
sales@sphinxscientificlab.com
Country
United States
ProdList
3343
Advantage
50
AccuStandard Inc
Tel
--
Fax
--
Email
info@bester.nl
Country
United States
ProdList
5300
Advantage
76
2A Biotech USA
Tel
--
Fax
--
Email
info@2abiotech.com
Country
United States
ProdList
1785
Advantage
58
Combi-Blocks, Inc.
Tel
--
Fax
--
Email
les@combi-blocks.com
Country
United States
ProdList
2555
Advantage
58
SynQuest Laboratories, Inc.,
Tel
--
Fax
--
Country
United States
ProdList
2301
Advantage
58
SynQuest Laboratories, Inc. (Part of Central Glass Co., Ltd.)
Tel
--
Fax
--
Email
nfo@synquestlabs.com
Country
United States
ProdList
1897
Advantage
58
VWR International, LLC.
Tel
--
Fax
--
Email
@sargentwelch.com
Country
United States
ProdList
6262
Advantage
58
eNovation Chemicals LLC
Tel
--
Fax
--
Email
ales@eNovationChem.com
Country
United States
ProdList
1673
Advantage
58
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
MilliporeSigma (Sigma-Aldrich Corp.)
Tel
--
Fax
--
Email
@sial.com
Country
United States
ProdList
5414
Advantage
58
Crescent Chemical Company
Tel
--
Fax
--
Email
fran@creschem.com
Country
United States
ProdList
1441
Advantage
58
MP Biomedicals, LLC. (Division of Valiant FC Co., Ltd.)
Tel
--
Fax
--
Email
serv@mpbio.com
Country
United States
ProdList
1854
Advantage
58
TCI America, Inc. (Tokyo Chemical Industry Co., Ltd.)
Tel
--
Fax
--
Email
.Crew@tcichemicals.com
Country
United States
ProdList
3164
Advantage
58
Fluorochem Ltd.
Tel
--
Fax
--
Email
enquiries@fluorochem.co.uk
Country
United States
ProdList
4583
Advantage
58
CALSAK CORPORATION
Tel
--
Fax
--
Email
calsak@calsak.com
Country
United States
ProdList
430
Advantage
58
Spectrum Chemical Mfg. Corp.
Tel
--
Fax
--
Email
marketing@spectrumchemical.com
Country
United States
ProdList
3113
Advantage
60
Catapharma
Tel
--
Fax
--
Email
sales@catapharma.com
Country
United States
ProdList
77
Advantage
38
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Frontier Scientific, Inc.
Tel
--
Fax
--
Email
sales@frontiersci.com
Country
United States
ProdList
6222
Advantage
86
Anvia Chemicals, LLC
Tel
--
Fax
--
Email
sales@anviachem.com
Country
United States
ProdList
3933
Advantage
0
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
AlliChem, LLC
Tel
--
Fax
--
Email
sales@allichemllc.com
Country
United States
ProdList
6516
Advantage
60
ChemService Inc.
Tel
--
Fax
--
Country
United States
ProdList
6379
Advantage
68
Advanced Synthesis Technologies
Tel
--
Fax
--
Email
sales@advancedsynthesis.com
Country
United States
ProdList
4775
Advantage
61
Pfaltz & Bauer, Inc.
Tel
--
Fax
--
Email
sales@pfaltzandbauer.com
Country
United States
ProdList
6828
Advantage
72
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
PHT International Inc.
Tel
--
Fax
--
Email
pht@phtchemical.com
Country
United States
ProdList
97
Advantage
65
Sciencelab.com, Inc.
Tel
--
Fax
--
Email
accounting@sciencelab.com
Country
United States
ProdList
4159
Advantage
82
Advance Scientific & Chemical
Tel
--
Fax
--
Email
sales@advance-scientific.com
Country
United States
ProdList
6419
Advantage
71
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
ChemPacific Corporation
Tel
--
Fax
--
Email
sales@chempacific.com
Country
United States
ProdList
6891
Advantage
51
Richman Chemical Inc.
Tel
--
Fax
--
Email
kac@richmanchemical.com
Country
United States
ProdList
692
Advantage
67
Eastern Chemical Corp.
Tel
--
Fax
--
Email
eastern@u-g.com
Country
United States
ProdList
2786
Advantage
34
City Chemicals Corporation
Tel
--
Fax
--
Country
United States
ProdList
6460
Advantage
72
Fisher Scientific
Tel
--
Fax
--
Email
sales@fishersci.com
Country
United States
ProdList
2337
Advantage
86
Acros Organics USA
Tel
--
Fax
--
Email
eveleth@fisherchem.com
Country
United States
ProdList
3846
Advantage
81
American Custom Chemicals Corporation
Tel
--
Fax
--
Email
sales@acccorporation.com
Country
United States
ProdList
6820
Advantage
51
Aceto Corporation
Tel
--
Fax
--
Email
contact@aceto.com
Country
United States
ProdList
2619
Advantage
75
More
Less

View Lastest Price from 1,8-Diaminonaphthalene manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
1,8-Diaminonaphthalene 479-27-6
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-11
Hebei Mojin Biotechnology Co., Ltd
Product
1,8-naphthalenediamine 479-27-6
Price
US $200.00/KG
Min. Order
1KG
Purity
99.99%
Supply Ability
20 ton
Release date
2020-06-30
Zhuozhou Wenxi import and Export Co., Ltd
Product
1,8-Diaminonaphthalene 479-27-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

479-27-6, 1,8-DiaminonaphthaleneRelated Search:

N,N-Dimethyl-1,4-phenylenediamine 2-Naphthylamine 2,3-DIAMINOTOLUENE Iminodiacetonitrile 4,4'-Diaminodiphenylsulfone Iminodiacetic acid 4,4'-Methylenedianiline 1,8-Dinitronaphthalene 2-AMINOPERIMIDINE HYDROCHLORIDE Mordant Black 38 Solvent Black 3 1,8-Bis(dimethylamino)naphthalene 2-Aminoperimidine Hydrobromide Solvent Red 179 perimidine Acid Black 60 2,3-diaminonaphthalene 5,6-diaminonaphthalene-1,3-disulphonic acid

  • 1,8-Diaminonaphthalene (1,8-Naphthalene diamine)
  • 1,8-DIAMINONAPHTHALONE
  • 1.8-DIAMINA-NAPTHALENE 99.6+%
  • 1,8-Diaminonaphthalene,99%
  • 1,8-Diaminonaphthalene,90%,tech.
  • 1,8-Diaminonaphthale
  • 8-Diaminonaphthalene
  • Naphthalene-1,8-diamine 99%
  • 1,8-DiaMinonaphthalene, 97% 100GR
  • 1,8-DiaMinonaphthalene, 97% 5GR
  • 1,8-NAPHTHALENEDIAMINE FOR SYNTHESIS
  • 1,8-Diaminonaphthalane
  • 1,8-DiaminonaphthaL
  • Naphthalene-1,8-diamine, technical
  • Naphthalene-1,8-diamine 479-27-6 1,8-Diaminonaphthalene
  • 1,8-Diaminonaphthalene 479-27-6
  • Naphthalene-1,8-diamine
  • DIAMINONAPHTHALENE-1,8
  • 1,8-NAPHTHALENEDIAMINE
  • 1,8-NAPHTHYLENEDIAMINE
  • 1,8-DIAMINONAPHTHALENE
  • 1,8-DIAMINONAPHTHALENE, FOR FLUORESCENCE
  • 1,8-Diaminonaphthalene,~97%
  • 1,8-Diaminonaphthalene, tech., 90%
  • 1,8-Diaminonaphthalene 96%
  • 1,8-Naphthylendiamin
  • 1,8-Diaminonaphthalene(Technical)
  • 1,8-Diaminonaphthalene&gt
  • 1,8-Diaminonaphthalene@100 μg/mL in Toluene
  • 1,8-Diaminonaphthalene CAS.479-27-6
  • 1,8-Diaminonaphthalene, ≥ 98.0%
  • 479-27-6
  • Detection
  • Fluorescent Probes, Labels, Particles and Stains
  • BioChemical
  • Biochemicals and Reagents
  • Building Blocks
  • Organic Building Blocks
  • Nitrogen Compounds
  • Polyamines
  • Building Blocks
  • Chemical Synthesis
  • Nitrogen Compounds
  • Organic Building Blocks
  • Polyamines
  • Organics
  • Benzene derivatives
  • Intermediates of Dyes and Pigments