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Tetradecafluorohexane

Product Name
Tetradecafluorohexane
CAS No.
355-42-0
Chemical Name
Tetradecafluorohexane
Synonyms
FC-72;FLUORINERT;TETRADECAFLUOROHEXANE;PFC-51-14;FLUORINERT FC-72;PERFLUOROHEXANES;n-Perfluorohexane;PF5060;Hexane, tetradecafluoro-;PerfL
CBNumber
CB2743404
Molecular Formula
C6F14
Formula Weight
338.04
MOL File
355-42-0.mol
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Tetradecafluorohexane Property

Melting point:
−4 °C(lit.)
Boiling point:
58-60 °C(lit.)
Density 
1.669 g/mL at 25 °C(lit.)
vapor pressure 
26.5kPa at 25℃
refractive index 
n20/D 1.252(lit.)
Flash point:
56-60°C
form 
Liquid
Specific Gravity
1.699
color 
Clear colorless
Water Solubility 
Immiscible with water.
Merck 
14,7157
BRN 
1802113
Dielectric constant
1.5700000000000001
Dielectric constant
1.5700000000000001
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
ZJIJAJXFLBMLCK-UHFFFAOYSA-N
LogP
4.5 at 20℃ and pH7
CAS DataBase Reference
355-42-0(CAS DataBase Reference)
EPA Substance Registry System
Perfluorohexane (355-42-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
2810
WGK Germany 
3
RTECS 
MO4310000
Hazard Note 
Irritant
TSCA 
T
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29033990
Hazardous Substances Data
355-42-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
379247
Product name
Tetradecafluorohexane
Purity
A mixture of perfluorinated hexanes, 95%
Packaging
50ml
Price
$104
Updated
2024/03/01
Sigma-Aldrich
Product number
281042
Product name
Tetradecafluorohexane
Purity
99%
Packaging
25ml
Price
$114
Updated
2024/03/01
Alfa Aesar
Product number
015812
Product name
Perfluorohexanes, 98+%
Packaging
25g
Price
$30.2
Updated
2023/06/20
Alfa Aesar
Product number
015812
Product name
Perfluorohexanes, 98+%
Packaging
100g
Price
$83.8
Updated
2023/06/20
Strem Chemicals
Product number
09-6072
Product name
Perfluorohexane, 98+% (85% n-isomer)
Packaging
10g
Price
$23
Updated
2024/03/01
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Tetradecafluorohexane Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

In the electronics industry as a coolant and test bath medium. Non-toxic, non-ozone-depleting, inert reaction medium.

Uses

Perfluorohexanes is used as a coolant, photosensitizer in fluorous biphasic singlet oxygenation and an inert reaction medium. It is used in the electronic cooling liquid and insulator. It plays a vital role as a reaction medium, especially for photooxidation reactions. Further, it finds application as an ultrasound contrast agent.

Uses

Tetradecafluorohexane has been used:

  • as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
  • to investigate boiling heat transfer mechanisms
  • as a photosensitizer in fluorous biphasic singlet oxygenation
  • as a novel reaction medium for photooxidation reactions

Definition

ChEBI: Perfluorohexane is a fluoroalkane that is hexane in which all of the hydrogens have been replaced by fluorines. It has a role as a radioopaque medium and a non-polar solvent. It is a fluorocarbon, a fluoroalkane and a volatile organic compound. It derives from a hydride of a hexane.

Application

Perfluorohexane uses and applications include: dispersant for lubricants, mold release agents, protective coatings; reaction media for polymerizations, purification, separation processes; solvent for removal of halogenated lubricants, oils, greases; carrier for halogenated material; for quick-cooling or freezing foods; heat-transfer fluid.
Because it is biologically inert and chemically stable, perfluorohexane has attracted attention in medicine. Like other fluorocarbons, perfluorohexane dissolves gases, including oxygen from the air, to a higher concentration than ordinary organic solvents. This effect is attributed to the weak intermolecular forces between perfluorohexane molecules, which allows "space" for gas molecules to partition into the liquid. Animals can be submerged in a bath of perfluorohexane without drowning, as there is sufficient oxygen available in the solvent to allow respiration to continue. This effect has led to the experimental use of perfluorohexane in treating burn victims, as their lungs can be filled with either perfluorohexane vapor or in extreme cases liquid perfluorohexane, allowing breathing to continue without the problems normally seen with pulmonary edema that sometimes occur when the inside of the lungs have been burnt e.g. by inhalation of hot smoke.

General Description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Purification Methods

Purify the fluorohexane by fractional freezing. The methods described for perfluoroheptane should be applicable here. [Beilstein 1 IV 348.]

Tetradecafluorohexane Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetradecafluorohexane Suppliers

Yangzhou modier Electronic Materials Co., Ltd
Tel
0514-82098883; 13761402923
Email
market@modeltemol.com
Country
China
ProdList
906
Advantage
58
Wuhan Silworld Chemical Co.,Ltd
Tel
027-85613400 15827173649
Fax
027-85613419
Email
info@silworldchemical.com
Country
China
ProdList
325
Advantage
58
Hubei Shishun Biotechnology Co. Ltd
Tel
027-59223025 15107168801
Fax
027-59223025
Email
1718480011@qq.com
Country
China
ProdList
9866
Advantage
58
Shandong Hemao New Material Co., Ltd.
Tel
13061243681
Email
hemiao66@163.com
Country
China
ProdList
226
Advantage
58
Suzhou Biosyntech Co., Ltd.
Tel
0512-63001269 15720870325
Email
sales2@biosyntech-suzhou.com
Country
China
ProdList
55
Advantage
58
Shangfluoro
Tel
021-65170832 17301729617
Email
qinba_2@163.com
Country
China
ProdList
269
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
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View Lastest Price from Tetradecafluorohexane manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
Perfluorohexane 355-42-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20
Hebei Mojin Biotechnology Co.,Ltd
Product
PERFLUOROHEXANE 355-42-0
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-08-09
Shaanxi Dideu Medichem Co. Ltd
Product
Tetradecafluorohexane 355-42-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20T
Release date
2024-06-11

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