ChemicalBook > CAS DataBase List > Tetradecafluorohexane

Tetradecafluorohexane

Product Name
Tetradecafluorohexane
CAS No.
355-42-0
Chemical Name
Tetradecafluorohexane
Synonyms
FC-72;FLUORINERT;TETRADECAFLUOROHEXANE;PFC-51-14;FLUORINERT FC-72;PERFLUOROHEXANES;n-Perfluorohexane;PF5060;Hexane, tetradecafluoro-;PerfL
CBNumber
CB2743404
Molecular Formula
C6F14
Formula Weight
338.04
MOL File
355-42-0.mol
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Tetradecafluorohexane Property

Melting point:
−4 °C(lit.)
Boiling point:
58-60 °C(lit.)
Density 
1.669 g/mL at 25 °C(lit.)
vapor pressure 
26.5kPa at 25℃
refractive index 
n20/D 1.252(lit.)
Flash point:
56-60°C
form 
Liquid
Specific Gravity
1.699
color 
Clear colorless
Water Solubility 
Immiscible with water.
Merck 
14,7157
BRN 
1802113
Dielectric constant
1.5700000000000001
Dielectric constant
1.5700000000000001
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
ZJIJAJXFLBMLCK-UHFFFAOYSA-N
LogP
4.5 at 20℃ and pH7
CAS DataBase Reference
355-42-0(CAS DataBase Reference)
EPA Substance Registry System
Perfluorohexane (355-42-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
2810
WGK Germany 
3
RTECS 
MO4310000
Hazard Note 
Irritant
TSCA 
T
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29033990
Hazardous Substances Data
355-42-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
379247
Product name
Tetradecafluorohexane
Purity
A mixture of perfluorinated hexanes, 95%
Packaging
50ml
Price
$104
Updated
2024/03/01
Sigma-Aldrich
Product number
281042
Product name
Tetradecafluorohexane
Purity
99%
Packaging
25ml
Price
$114
Updated
2024/03/01
Alfa Aesar
Product number
015812
Product name
Perfluorohexanes, 98+%
Packaging
25g
Price
$30.2
Updated
2023/06/20
Alfa Aesar
Product number
015812
Product name
Perfluorohexanes, 98+%
Packaging
100g
Price
$83.8
Updated
2023/06/20
Strem Chemicals
Product number
09-6072
Product name
Perfluorohexane, 98+% (85% n-isomer)
Packaging
10g
Price
$23
Updated
2024/03/01
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Tetradecafluorohexane Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

In the electronics industry as a coolant and test bath medium. Non-toxic, non-ozone-depleting, inert reaction medium.

Uses

Perfluorohexanes is used as a coolant, photosensitizer in fluorous biphasic singlet oxygenation and an inert reaction medium. It is used in the electronic cooling liquid and insulator. It plays a vital role as a reaction medium, especially for photooxidation reactions. Further, it finds application as an ultrasound contrast agent.

Uses

Tetradecafluorohexane has been used:

  • as a fluorocarbon organic solvent in the preparation of temperature-induced phase-separation solution
  • to investigate boiling heat transfer mechanisms
  • as a photosensitizer in fluorous biphasic singlet oxygenation
  • as a novel reaction medium for photooxidation reactions

Definition

ChEBI: Perfluorohexane is a fluoroalkane that is hexane in which all of the hydrogens have been replaced by fluorines. It has a role as a radioopaque medium and a non-polar solvent. It is a fluorocarbon, a fluoroalkane and a volatile organic compound. It derives from a hydride of a hexane.

Application

Perfluorohexane uses and applications include: dispersant for lubricants, mold release agents, protective coatings; reaction media for polymerizations, purification, separation processes; solvent for removal of halogenated lubricants, oils, greases; carrier for halogenated material; for quick-cooling or freezing foods; heat-transfer fluid.
Because it is biologically inert and chemically stable, perfluorohexane has attracted attention in medicine. Like other fluorocarbons, perfluorohexane dissolves gases, including oxygen from the air, to a higher concentration than ordinary organic solvents. This effect is attributed to the weak intermolecular forces between perfluorohexane molecules, which allows "space" for gas molecules to partition into the liquid. Animals can be submerged in a bath of perfluorohexane without drowning, as there is sufficient oxygen available in the solvent to allow respiration to continue. This effect has led to the experimental use of perfluorohexane in treating burn victims, as their lungs can be filled with either perfluorohexane vapor or in extreme cases liquid perfluorohexane, allowing breathing to continue without the problems normally seen with pulmonary edema that sometimes occur when the inside of the lungs have been burnt e.g. by inhalation of hot smoke.

General Description

Tetradecafluorohexane in the gas phase reacts spontaneously with lithium amalgam, to give a solid and intimate mixture of lithium fluoride and elemental polymeric carbon with a small amount of superstoichiometric lithium.

Purification Methods

Purify the fluorohexane by fractional freezing. The methods described for perfluoroheptane should be applicable here. [Beilstein 1 IV 348.]

Tetradecafluorohexane Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetradecafluorohexane Suppliers

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View Lastest Price from Tetradecafluorohexane manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
Perfluorohexane 355-42-0
Price
US $10.00/kg
Min. Order
1kg
Purity
99.6%
Supply Ability
100000
Release date
2024-04-24
Henan Fengda Chemical Co., Ltd
Product
PERFLUOROHEXANE 355-42-0
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28
Hebei Guanlang Biotechnology Co,.LTD
Product
Perfluorohexane 355-42-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2023-07-26

355-42-0, TetradecafluorohexaneRelated Search:

1H,1H,2H,2H-Perfluorodecyltrichlorosilane (Perfluorohexyl)ethylene 1H,4H-OCTAFLUOROBUTANE 1,1,1,2,2-PENTAFLUOROPROPANE 1,2,2,2-tetrafluoroethane Tetradecafluorohexane 1H-Perfluorohexane98%,1H-Perfluorohexane 98%,1H-Perfluorohexane,97%,1H-PERFLUOROHEXANE 1-FLUOROPENTANE 1-FLUOROHEXANE 1,1,1,3,3-Pentafluoropropane 1,1,1,3-TETRAFLUOROPROPANE 1,1,2,2,3,3-HEXAFLUOROPROPANE ammonium perfluorohexane-1-sulphonate 1,6-Diiodododecafluorohexane 1-BROMOPERFLUOROHEXANE Perfluoro-1-iodohexane potassium perfluorohexane-1-sulphonate PERFLUOROCYCLOHEXYL CARBOXYLIC ACID FLUORIDE: 65% IN PERFLUOROHEXANE

  • Perfluorohexane Mixed isomers
  • Perfluorohexanes, 98+%
  • 3M FC-72 Fluorinet, PF-5060 3M
  • PFC-51-14
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  • Perfluoro-compound FC-72§3
  • Tetradecafluorohexane A Mixture of perfluorinated hexanes, 95%
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  • Perfluorohexanes, 85% n-isomer, 98%
  • TETRADECAFLUOROHEXANE
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  • PERFLUORO-N-HEXANE
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  • FLUTEC PP1
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  • Perfluor-VerbindungFC-72
  • Perfluor-VerbindungFC-72?Perfluorohexanes
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  • tetradecafluoro-hexan
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  • Perfluorohexanenisomercolorlessliq
  • Tetradecafluoro-n-hexane
  • PERFLUOROHEXANE MIXTURE OF ISOMERS
  • PerfL
  • uorohexane
  • 1,1,1,2,2,3,3,4,4,5,5,6,6,6-Tetradecafluorohexane
  • 1,1,1,2,2,3,3,4,4,5,5,6,6,6-Tetradecafluoro-hexane
  • FluorinertLiquidFC72
  • FluorinertPF5060
  • Hexane, tetradecafluoro-
  • hexane,tetradecafluoro-
  • n-Tetradecafluorohexane
  • perfluorohexane(tetradecafluorohexane)
  • TETRADECAFLUOROHEXANE, MIXT. OF ISOMERS
  • Perflutel(R)RM56
  • Perfluorohexane,95+%
  • Perfluoro-n-hexane,99%
  • FC-51-14
  • Perfluorohexane98.n-isomer
  • FLUORINERT
  • FLUORINERT (TM) (FC-72) (R)
  • FLUORINERT(R) FC-72
  • Perfluorohexane,98+%(85%n-isomer)
  • Perfluorohexane 98% Mixed isomers
  • Perfluorohexane 98.5% n-isomer
  • Tetradecafluorhexan
  • PERFLUOROHEXANE (85% N-ISOMER)
  • FLUTEC PP1 FOR ELECTRONIC APPLICATIONS
  • Perfluorohexane, 99%, mixture of isomers
  • Perfluorohexanes (Mixture of Isomers)