ChemicalBook > CAS DataBase List > 4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER

4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER

Product Name
4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER
CAS No.
179117-44-3
Chemical Name
4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER
Synonyms
4-Carbamoylphenylboronic Acid Pinacol Ester;4-Carbamoylbenzeneboronic acid pinacol ester;4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER;4-(tetraMethyl-1,3,2-dioxaborolan-2-yl)benzaMide;4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-BENZAMIDE;Benzamide, 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
CBNumber
CB2765848
Molecular Formula
C13H18BNO3
Formula Weight
247.1
MOL File
179117-44-3.mol
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4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER Property

Melting point:
174.9-180.3 °C
Boiling point:
388.2±25.0 °C(Predicted)
Density 
1.11±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
pka
15.86±0.50(Predicted)
color 
White
CAS DataBase Reference
179117-44-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
WGK Germany 
3
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
BML00036
Product name
4-Aminocarbonylphenylboronic acid, pinacol ester
Purity
Aldrich
Packaging
1g
Price
$185
Updated
2025/07/31
TRC
Product number
A794828
Product name
4-Aminocarbonylphenylboronic acid, pinacol ester
Packaging
100mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
8660-1-T8
Product name
4-Aminocarbonylphenylboronic acid, pinacol ester
Packaging
500mg
Price
$48
Updated
2021/12/16
AK Scientific
Product number
AMTB358
Product name
4-Aminocarbonylphenylboronic acid, pinacol ester
Packaging
1g
Price
$20
Updated
2021/12/16
Apolloscientific
Product number
OR303954
Product name
4-Aminocarbonylphenylboronic acid, pinacol ester
Purity
98%
Packaging
500mg
Price
$44
Updated
2021/12/16
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4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER Chemical Properties,Usage,Production

Synthesis

73183-34-3

619-56-7

179117-44-3

Under argon protection, 1.4 mg (0.005 mmol) of dichlorobis(trimethylphosphine)nickel (NiCl2(PMe3)2), 77.4 mg (0.5 mmol) of 4-chlorobenzamide, 152 mg (1.0 mmol) of cesium fluoride (CsF), 140 mg (0.55 mmol) of bis(pinacolato)bis(boronic acid) ( B2pin2), 180 mg (1.05 mmol) trimethyl (2,2,5,5-tetrafluoroethoxy) silane (TMSEF), and 0.5 mL 1,4-dioxane. The reaction vessel was sealed and the mixture was stirred and reacted at 100°C for 12 hours. Upon completion of the reaction, the reaction vessel was cooled to room temperature and the reaction was quenched by the addition of 1 mL of saturated aqueous ammonium chloride. The mixture was extracted three times with 8 mL of ethyl acetate and the organic phases were combined. The solvent was removed by distillation under reduced pressure and the residue was purified by silica gel column chromatography (eluent gradient: hexane/chloroform/ethyl acetate = 4:1:0 to 4:1:1) to afford 92 mg (75% yield) of the target product 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzamide as a white solid.

References

[1] Organic and Biomolecular Chemistry, 2014, vol. 12, # 22, p. 3604 - 3610
[2] Organic Letters, 2011, vol. 13, # 21, p. 5766 - 5769
[3] Patent: JP5699037, 2015, B2. Location in patent: Paragraph 0091; 0092

4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER Suppliers

China 56 Germany 2 India 1 United Kingdom 7 United States 13 Global 79
J & K SCIENTIFIC LTD.
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9ding chemical ( Shanghai) Limited
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HBCChem, Inc.
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View Lastest Price from 4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER manufacturers

Career Henan Chemical Co
Product
4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER 179117-44-3
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000kg
Release date
2020-01-13

179117-44-3, 4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTERRelated Search:

1-BOC-4-[4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-BENZOYL]-PIPERAZINE (4-METHYL-PIPERAZINE-1-YL)-[4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-PHENYL]-METHANONE 4-(3-ETHOXYCARBONYLPIPERIDINE)CARBOXAMIDOPHENYLBORONIC ACID, PINACOL ESTER 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOHYDRAZIDE 4-(MORPHOLINE)CARBOXAMIDOPHENYLBORONIC ACID, PINACOL ESTER 3-(4-FLUOROPHENYL)AMINOCARBONYLPHENYLBORONIC ACID PINACOL ESTER 4-(N-CYCLOPROPYLAMINOCARBONYL)PHENYLBORONIC ACID, PINACOL ESTER PIPERAZIN-1-YL-[4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-PHENYL]-METHANONE N-[2-HYDROXYETHYL]BENZAMIDE-4-BORONIC ACID, PINACOL ESTER N-(3-DIMETHYLAMINOPROPYL)-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZAMIDE N-PYRIDIN-4-YLMETHYL-4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-BENZAMIDE 4-N-METHYLCARBOXAMIDOPHENYLBORONIC ACID, PINACOL ESTER 4-[4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-BENZOYL]-[1,4]DIAZEPANE-1-CARBOXYLIC ACID TERT-BUTYL ESTER N-PYRIDIN-2-YLMETHYL-4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-BENZAMIDE 4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER N-(2-DIMETHYLAMINOETHYL)-4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZAMIDE 4-(N,N-DIETHYLAMINOCARBONYL)PHENYLBORONIC ACID, PINACOL ESTER 3-(N,N-DIMETHYLAMINOCARBONYL)PHENYLBORONIC ACID, PINACOL ESTER

  • 4-AMINOCARBONYLPHENYLBORONIC ACID, PINACOL ESTER
  • 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)-BENZAMIDE
  • 4-(tetraMethyl-1,3,2-dioxaborolan-2-yl)benzaMide
  • Benzamide, 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
  • 4-Carbamoylphenylboronic Acid Pinacol Ester
  • 4-Carbamoylbenzeneboronic acid pinacol ester
  • 179117-44-3
  • blocks
  • BoronicAcids
  • Carboxes
  • Heterocyclic Compounds