METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID
- Product Name
- METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID
- CAS No.
- 167300-06-3
- Chemical Name
- METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID
- Synonyms
- 3-(Methoxycarbonyl);METHY-2-METHYL-5-CARBOXYLICBENZOIC ACID;3-(Methoxycarbonyl)-4-Methylbenzoic acid;4-METHYL-3-(METHOXYCARBONYL)BENZOIC ACID;METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID;1,3-Benzenedicarboxylic acid, 4-methyl-, 3-methyl ester
- CBNumber
- CB2781790
- Molecular Formula
- C10H10O4
- Formula Weight
- 194.18
- MOL File
- 167300-06-3.mol
METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID Property
- Boiling point:
- 349.9±30.0 °C(Predicted)
- Density
- 1.243±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 4.00±0.10(Predicted)
- Appearance
- White to off-white Solid
Safety
- HS Code
- 2917399590
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M331698
- Product name
- 3-(Methoxycarbonyl)-4-methylbenzoicAcid
- Packaging
- 1g
- Price
- $310
- Updated
- 2021/12/16
- Product number
- 8530AA
- Product name
- 3-(Methoxycarbonyl)-4-methylbenzoicacid
- Packaging
- 250mg
- Price
- $139
- Updated
- 2021/12/16
- Product number
- CHM0299451
- Product name
- METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $496.75
- Updated
- 2021/12/16
- Product number
- 8530AA
- Product name
- 3-(Methoxycarbonyl)-4-methylbenzoicacid
- Packaging
- 5g
- Price
- $784
- Updated
- 2021/12/16
- Product number
- A213451
- Product name
- 3-(Methoxycarbonyl)-4-methylbenzoicacid
- Purity
- 98%
- Packaging
- 250mg
- Price
- $101
- Updated
- 2021/12/16
METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID Chemical Properties,Usage,Production
Synthesis
675148-96-6
167300-06-3
Methyl 5-formyl-2-methylbenzoate (268 mg, 1.5 mmol) was used as starting material and dissolved in N,N-dimethylformamide (DMF, 5 mL). Subsequently, Oxone (1.110 g, 1.8 mmol) was added to the solution and the reaction mixture was stirred at room temperature for 18 hours. After completion of the reaction, the reaction mixture was diluted with ethyl acetate (EtOAc, 10 mL) followed by 0.5 M aqueous hydrochloric acid (20 mL). The organic phase was separated, dried with anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to afford the target product 3-(methoxycarbonyl)-4-methylbenzoic acid as an off-white powder (247 mg, 1% yield). The structure of the product was confirmed by 1H NMR (500 MHz, DMSO-d6): δ 8.38 (d, J = 1.8 Hz, 1H), 8.01 (dd, J = 7.9, 1.9 Hz, 1H), 7.48 (d, J = 8.0 Hz, 1H), 3.86 (s, 3H), 2.59 (s, 3H).
References
[1] Patent: WO2018/89433, 2018, A1. Location in patent: Paragraph 00317
METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID Suppliers
- Tel
- --
- Fax
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- enquiry@leancare.co.uk
- Country
- United Kingdom
- ProdList
- 6446
- Advantage
- 42
View Lastest Price from METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID manufacturers
- Product
- METHYL-2-METHYL-5-CARBOXYLICBENZOIC ACID 167300-06-3
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2020-01-13