ChemicalBook > CAS DataBase List > METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE

METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE

Product Name
METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE
CAS No.
550998-53-3
Chemical Name
METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE
Synonyms
METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE;7-Bromo-benzo[b]thiophene-2-carboxylic acid methyl ester;Benzo[b]thiophene-2-carboxylic acid, 7-bromo-, methyl ester
CBNumber
CB2798383
Molecular Formula
C10H7BrO2S
Formula Weight
271.13
MOL File
Mol file
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METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE Property

Melting point:
99-102°C
storage temp. 
2-8°C(protect from light)
form 
solid
color 
Off-white
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Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

SynQuest Laboratories
Product number
6H23-9-05
Product name
Methyl 7-bromobenzo[b]thiophene-2-carboxylate
Packaging
1g
Price
$104
Updated
2021/12/16
Matrix Scientific
Product number
047092
Product name
Methyl 7-bromo-1-benzothiophene-2-carboxylate
Purity
>95%
Packaging
500mg
Price
$109
Updated
2021/12/16
Matrix Scientific
Product number
047092
Product name
Methyl 7-bromo-1-benzothiophene-2-carboxylate
Purity
>95%
Packaging
1g
Price
$145
Updated
2021/12/16
AK Scientific
Product number
8024AB
Product name
Methyl7-bromobenzo[b]thiophene-2-carboxylate
Packaging
250mg
Price
$154
Updated
2021/12/16
AK Scientific
Product number
8024AB
Product name
Methyl7-bromobenzo[b]thiophene-2-carboxylate
Packaging
1g
Price
$176
Updated
2021/12/16
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METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE Chemical Properties,Usage,Production

Synthesis

149947-15-9

2365-48-2

550998-53-3

GENERAL METHOD: Under stirring conditions, 3-bromo-2-fluorobenzaldehyde (9.90 mmol) was dissolved in DMF (20 mL) and methyl mercaptoacetate (10.9 mmol) and potassium carbonate (39.6 mmol) were added sequentially. The reaction mixture was stirred continuously at 60 °C for 15 hours. After completion of the reaction, the DMF solvent was removed by distillation under reduced pressure. Water (50 mL) was added to the residue, which was subsequently extracted with ethyl acetate (2 x 40 mL). The organic phases were combined, dried with anhydrous sodium sulfate, filtered, and concentrated under reduced pressure to remove the solvent to afford the target product, methyl 7-bromobenzo[b]thiophene-2-carboxylate.

References

[1] European Journal of Medicinal Chemistry, 2017, vol. 125, p. 538 - 550
[2] Patent: KR2015/117318, 2015, A. Location in patent: Paragraph 0181; 0187; 0188; 0189

METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE Suppliers

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550998-53-3, METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATERelated Search:

Coumarin 7-BROMO-ISOQUINOLIN-1-YLAMINE 7-BROMO-1-CHLOROISOQUINOLINE 7-BROMO-1-HYDROXYISOQUINOLINE 7-BROMO-1-METHYL-1H-INDAZOLE

  • METHYL 7-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLATE
  • 7-Bromo-benzo[b]thiophene-2-carboxylic acid methyl ester
  • Benzo[b]thiophene-2-carboxylic acid, 7-bromo-, methyl ester
  • 550998-53-3