ChemicalBook > CAS DataBase List > ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
- Product Name
- ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
- CAS No.
- 116399-78-1
- Chemical Name
- ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
- Synonyms
- (E)-(4-Chlorobut-2-en-2-yl)trimethylsilane;((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE;(E)-(3-Chloro-1-methyl-1-propenyl)trimethylsilane;Silane, (3-chloro-1-methyl-1-propen-1-yl)trimethyl-
- CBNumber
- CB2838869
- Molecular Formula
- C7H15ClSi
- Formula Weight
- 162.73
- MOL File
- 116399-78-1.mol
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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Property
- Boiling point:
- 167.7±15.0 °C(Predicted)
- Density
- 0.881±0.06 g/cm3(Predicted)
- solubility
- freely sol organic solvents.
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N-Bromosuccinimide Price
American Custom Chemicals Corporation
- Product number
- ORS0001263
- Product name
- ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $497.83
- Updated
- 2021/12/16
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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Chemical Properties,Usage,Production
Physical properties
bp 92–94°C/74 mmHg.
Uses
(E)-(3-Chloro-1-methyl-1-propenyl)-
trimethylsilane acts as the alkylative
equivalent of 3-buten-2-one (methyl vinyl ketone), permitting
regiospecific enolate alkylation under nonequilibrating conditions.
As a vinylsilane it can be converted,via the corresponding
α,β-epoxy silane, into a 3-oxobutyl moiety, and hence used
in an alkylative equivalent of Robinson annulation.Application
of such methodology can be seen (eq 1) in the preparation of
bicyclodecenones via the alkylation of dihydrocarvone with this
reagent.Apart from this application, and its use in combination
with potassium iodide, it has seen little use so far.
((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Preparation Products And Raw materials
Raw materials
Preparation Products
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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Suppliers
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