HAFNIUM TRIFLUOROMETHANESULFONATE
- Product Name
- HAFNIUM TRIFLUOROMETHANESULFONATE
- CAS No.
- 161337-67-3
- Chemical Name
- HAFNIUM TRIFLUOROMETHANESULFONATE
- Synonyms
- Hf(OTf)4;HAFNIUM(IV) TRIFLATE;Hafnium trif;HAFNIUM TRIFLATE;HAFNIUM TRIFLUOROMETHANESULFONATE;Hafnium trifluoromethanesulphonate;HAFNIUM(IV) TRIFLUOROMETHANESULFONATE;HAFNIUM (IV) TRIFLUOROMETHANESULPHONATE;HAFNIUM TRIFLUOROMETHANESULFONATE HYDRAT E;Hafnium(IV) trifluoromethanesulphonate 98%
- CBNumber
- CB3104785
- Molecular Formula
- CHF3HfO3S
- Formula Weight
- 328.56
- MOL File
- 161337-67-3.mol
HAFNIUM TRIFLUOROMETHANESULFONATE Property
- Melting point:
- >350 °C(lit.)
- Flash point:
- None
- solubility
- Soluble in methyl cyanide, dicholomethane, dichloroethane, nitromethane, dioxane, terahydrofuran and toluene.
- form
- powder to crystal
- color
- White to Light yellow
- Sensitive
- Hygroscopic
- Exposure limits
- ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3 - CAS DataBase Reference
- 161337-67-3(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 469041
- Product name
- Hafnium(IV) trifluoromethanesulfonate hydrate
- Packaging
- 1g
- Price
- $223
- Updated
- 2024/03/01
- Product number
- T1708
- Product name
- Hafnium(IV) Trifluoromethanesulfonate
- Purity
- >90.0%(T)
- Packaging
- 1g
- Price
- $28
- Updated
- 2024/03/01
- Product number
- T1708
- Product name
- Hafnium(IV) Trifluoromethanesulfonate
- Purity
- >90.0%(T)
- Packaging
- 5g
- Price
- $93
- Updated
- 2024/03/01
- Product number
- L19688
- Product name
- Hafnium trifluoromethanesulfonate, 98%
- Packaging
- 5g
- Price
- $103
- Updated
- 2023/06/20
- Product number
- L19688
- Product name
- Hafnium trifluoromethanesulfonate, 98%
- Packaging
- 25g
- Price
- $326
- Updated
- 2023/06/20
HAFNIUM TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production
Uses
Hafnium trifluoromethanesulfonate is a recyclable catalyst for the mononitration of o-nitrotoluene. It serves as a catalyst for homogeneous methoxycarbonylation and hydrocarboxylation reactions of phenylacetylene. It is also used as a reactant for direct Friedel-Crafts reactions of chromene hemiacetals, aminomethylation reactions under Lewis acidic conditions and prins-type cyclization reactions. It is also involved in the direct polycondensation of lactic acid. Further, it is used in cationic benzylation reactions, chemoselective thioacetalization and transthioacetalization of carbonyl compounds.
Uses
Catalyst for:
- Homogeneous methoxycarbonylation and hydrocarboxylation reactions of phenylacetylene
- Direct Friedel-Crafts reactions of chromene hemiacetals
- Aminomethylation reactions under Lewis acidic conditions
- Prins-type cyclization reactions
- Direct polycondensation of lactic acid
- Cationic benzylation reactions
- Chemoselective thioacetalization and transthioacetalization of carbonyl compounds