(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

Reaction

Product Name: (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CAS No.: 64536-78-3
Chemical Name: (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
Synonyms: CRABTREE'S CATALYST;CRABTREE CATALYST;[Ir(cod)(PCy3)(py)]PF6;tricyclohexylphosphinecyclooctadienepyridineiridium PF6;Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex;[Ir(PCy3)(COD)(Py)]+PF6-;Felkin-Crabtree catalyst;CRABTREE PRECURSOR COMPLEX;phosphine)iridium(I) hexafL;ooctadiene(pyridine)(tricycL
CBNumber: CB3108657
Molecular Formula: C31H47F6IrNP2
Formula Weight: 801.88
MOL File: 64536-78-3.mol

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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Property

Melting point:: 175 °C (dec.)(lit.)
Density: 1.67 g/cm3
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform (Slightly)
form: Crystalline Powder
color: Orange
Water Solubility: Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.
Sensitive: Moisture Sensitive
Merck: 13,2594

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 10-21
TSCA: No
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 337498
Product name: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate
Purity: 85%
Packaging: 50mg
Price: $27.48
Updated: 2024/03/01

Sigma-Aldrich

Product number: 29590
Product name: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate
Purity: ≥99.0% (C)
Packaging: 250mg
Price: $193
Updated: 2024/03/01

TCI Chemical

Product number: C2824
Product name: (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate
Packaging: 100mg
Price: $90
Updated: 2024/03/01

Alfa Aesar

Product number: 042057
Product name: 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%
Packaging: 50mg
Price: $50.6
Updated: 2023/06/20

Alfa Aesar

Product number: 042057
Product name: 1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%
Packaging: 250mg
Price: $189
Updated: 2023/06/20

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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Reaction

Iridium catalyst used for the highly enantioselective hydrogenation of α,β-unsaturated esters.
Iridium catalyst used for the stereoselective catalytic hydrogenation and conjugate reduction of 4methylitaconate derivatives bearing a chiral auxiliary.
Iridium catalyst used in the synthesis of thiophene-based TAK-779 analogues via C-H arylation.
Iridium catalyst used in the practical synthetic approach to chiral (α-chloroalkyl)boronic esters via an iridiumcatalyzed, chemoselective hydrogenation of chloro-substituted alkenyl boronates.
Iridium catalyst used in the regioselective C-H activation and hydrogen-isotope exchange of non-aromatic unsaturated functionality.

Chemical Properties

orange crystals

Uses

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Suppliers

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View Lastest Price from (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE manufacturers

Career Henan Chemical Co

Product: (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE 64536-78-3
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 200kg
Release date: 2020-01-10

64536-78-3, (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATERelated Search:

Ruthenium(III) chloride hydrate GRUBBS CATALYST 2ND GENERATION (1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLIDINIUM-CHLORIDE DICHLORO-[1,3-BIS(DIISOPROPYLPHENYL)IMIDAZOLYLIDENE]-(3-CHLOROPYRIDYL)PALLADIUM(II) Dimethyl sulfoxide DI-I-PROPYLPHOSPHINE Tricyclohexyl phosphine TRIHEXYLPHOSPHINE TRIISOPROPYLPHOSPHINE DICYCLOHEXYLPHOSPHINE 1,5-Cyclooctadiene CYCLOHEXYLPHOSPHINE (1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

tricyclohexylphosphinecyclooctadienepyridineiridium PF6

Crabtrees catalyst, (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6, Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex

(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTA- DIENE)(PYRIDINE)IRIDIUM(I) PF6

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,99%

(1,5-Cyclooctadiene)pyridine(tricyclohexylphosphine)iridium hexafluorophosphate

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I)hexafluorophosphate,99%CRABTREE'SCATALYST

1,5-Cyclooctadiene-(pyridyl)-(tricyclohexylphosphine)-iridium hexafluoropho

(cycloocta-1,5-diene)pyridyl(tricyclohexyl-phosphine)iridium(I)hexafluorophosphate Crabtree's catalyst

<br>(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluoro phosphate

Hexafluorophosphate (tricyclohexyl phosphine) (1,5-cyclooctadiene) (pyridine) iridium

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,98%

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiuM(I) hexafluorophosphate,98% CRABTREE'S CATALYST

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiuM(I)hexafluorophosphate,CRABTREE'S CATALYST

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridiuM(I)

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate >=99.0% (C)

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridiuM(I) hexafluorophosphate 85%

[Ir(cod)(PCy3)(py)]PF6

IRIDIUM(I) HEXAFLUOROPHOSPHATE (1,5-CYCLOOCTADIENE)-(PYRIDINE)-(TRICYCLOHEXYLPHOSPHINE) COMPLEX

CRABTREE CATALYST

CRABTREE PRECURSOR COMPLEX

CRABTREE'S CATALYST

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

(TRICYCLOHEXYLPHOSPHINE)(1,5-CYCLOOCTADIENE)(PYRIDINE)IRIDIUM (I) HEXAFLUOROPHOSPHATE

(1,5-cyclooctadiene)(pyrid.)(tric.hexyl-phosphine)irid(I)pf6

(Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate

Crabtrees Catalyst~(Tricyclohexyphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate

(1,5-CYCLOOCTADIENE)(PYRIDINE)(TRICYCLOHEXYLPHOSPHINE)IRIDIUM(I) PF6, 85%

[Ir(PCy3)(COD)(Py)]+PF6-

ooctadiene(pyridine)(tricycL

phosphine)iridium(I) hexafL

1,5-Cyclooctadiene(Pyridine)(Tricyclohexylphosphine)Iridium(I) Hexafluorophospha

(1, 5-Cyclooctadiene) (pyridine) (tricylocohexylphosphine) iridium(I) hexafluorophosphate

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridiu...

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate, 99%,

Iridium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-, hexafluorophosphate(1-) (1:1)

(1,2,5,6-η)-1,5-cyclooctadiene](pyridine)(tricyclohexylphosphine)-Iridium(1+) hexafluorophosphate(1-) (1:1)

Tricylocohexylphosphine(1,5-cyclooctadiene)(pyridine) iridium(I) hexafluorophosphate ["Crabtree Catalyst"

Felkin-Crabtree catalyst

(Tricyclohexylphosphine)(1,5-cyclooctadiene)(pyridine)iridium(I) hexafluorophosphate,98% CRABTREE'S CATALYST

64536-78-3

C31H50IrNPF6P

C6H113PC8H12C5H5NIrPF6

C31H50IrNPPF6

C31H50F6IrNP2

Catalysis and Inorganic Chemistry

Iridium

Ir