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1-Benzyloxynaphthalene

Product Name
1-Benzyloxynaphthalene
CAS No.
607-58-9
Chemical Name
1-Benzyloxynaphthalene
Synonyms
NSC 4044;1-Naphtylbenzyl ether;Naphthyl benzyl ether;Benzyl naphthyl ether;1-Benzyloxynaphthalene;(1-Naphtyl)benzyl ether;Benzyl 1-Naphthyl Ether;1-Naphthyl Benzyl Ether;9-(benzyloxy)phenanthrene;Benzyl alpha-naphthyl ether
CBNumber
CB31106517
Molecular Formula
C17H14O
Formula Weight
234.29
MOL File
607-58-9.mol
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1-Benzyloxynaphthalene Property

Melting point:
73.5-74 °C
Boiling point:
237-240 °C(Press: 13 Torr)
Density 
1.125±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
form 
Solid
color 
Pale Orange to Light Orange
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S648094
Product name
BENZYL 1-NAPHTHYL ETHER
Purity
Aldrich<sup>CPR</sup>
Packaging
1 unit
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
S648094
Product name
BENZYL 1-NAPHTHYL ETHER
Purity
Aldrich
Packaging
250mg
Price
$179
Updated
2024/03/01
TRC
Product number
B286950
Product name
1-(Benzyloxy)naphthalene
Packaging
1g
Price
$545
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM1047419
Product name
1-(BENZYLOXY)NAPHTHALENE
Purity
95.00%
Packaging
5MG
Price
$495.53
Updated
2021/12/16
AK Scientific
Product number
4447BA
Product name
1-(Benzyloxy)naphthalene
Packaging
1g
Price
$243
Updated
2021/12/16
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1-Benzyloxynaphthalene Chemical Properties,Usage,Production

Uses

1-Benzyloxynaphthalene is a naphthyl ether used in studies for the improvement of coal direct liquefaction by steam pretreatment.

Synthesis

90-15-3

100-39-0

28178-96-3

607-58-9

General procedure for the synthesis of compounds (CAS:28178-96-3) and 1-(benzyloxy)naphthalene from 1-naphthol and benzyl bromide: 0.14 g (1.0 mmol) of a mixture of 1-naphthol and 2-naphthol (1) and (6), mixed with 1.0 mmol of an alkali metal carbonate (0.14 g of K2CO3 or 0.33 g of Cs2CO3), was specified by 11.4 mg (0.05 mmol) of TEBAC and 1.2 mmol of alkyl halide (0.14 ml of benzyl bromide, 0.10 ml of ethyl iodide, 0.12 ml of butyl bromide, or 0.11 ml of isopropyl bromide) were added to a closed vial and reacted at 125°C for the appropriate reaction time using a 20-30 W light source or in a CEM Discover [300 W] microwave reactor. time. After completion of the reaction, the mixture was dissolved in 25 ml of ethyl acetate and the suspension was filtered. The volatile components were removed by evaporation to give the crude product. The crude product was initially purified by passing through a silica gel layer of about 2-3 cm thickness, using ethyl acetate as eluent, and the product was analyzed by GC-MS or GC. Similar reactions were carried out under 3 ml MeCN as solvent. The post-treatment step was similar to the solvent-free alkylation reaction described above, but in this case the addition of ethyl acetate was not necessary. Compounds 2, 7, 8, 10a-c and 13a, b can be obtained from the above reactions mainly in pure form by repetitive chromatography.Control experiments were carried out using benzyl bromide under conventional heating conditions with similar procedure.

References

[1] Letters in Organic Chemistry, 2013, vol. 10, # 5, p. 330 - 336

1-Benzyloxynaphthalene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1-Benzyloxynaphthalene manufacturers

Henan Fengda Chemical Co., Ltd
Product
1-Benzyloxynaphthalene 607-58-9
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28