6-Nitro-1,2,3,4-tetrahydroquinoline
- Product Name
- 6-Nitro-1,2,3,4-tetrahydroquinoline
- CAS No.
- 14026-45-0
- Chemical Name
- 6-Nitro-1,2,3,4-tetrahydroquinoline
- Synonyms
- Quinoline, 1,2,3,4-tetrahydro-6-nitro-
- CBNumber
- CB31117320
- Molecular Formula
- C9H10N2O2
- Formula Weight
- 178.19
- MOL File
- 14026-45-0.mol
6-Nitro-1,2,3,4-tetrahydroquinoline Property
- Melting point:
- 161-162 °C(Solv: acetic acid, 50% (64-19-7))
- Boiling point:
- 341.4±31.0 °C(Predicted)
- Density
- 1.236±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- pka
- 0.87±0.20(Predicted)
- Appearance
- Yellow to brown Solid
- InChI
- InChI=1S/C9H10N2O2/c12-11(13)8-3-4-9-7(6-8)2-1-5-10-9/h3-4,6,10H,1-2,5H2
- InChIKey
- ASVYHMUYLBMSKW-UHFFFAOYSA-N
- SMILES
- N1C2=C(C=C([N+]([O-])=O)C=C2)CCC1
Safety
- HS Code
- 2933499090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- N497665
- Product name
- 6-nitro-1,2,3,4-tetrahydroquinoline
- Packaging
- 100mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- N497665
- Product name
- 6-nitro-1,2,3,4-tetrahydroquinoline
- Packaging
- 500mg
- Price
- $240
- Updated
- 2021/12/16
- Product number
- P000390818
- Product name
- 6-Nitro-1,2,3,4-tetrahydroquinoline
- Purity
- 95+%
- Packaging
- 5g
- Price
- $498
- Updated
- 2021/12/16
- Product number
- V3050
- Product name
- 6-Nitro-1,2,3,4-tetrahydroquinoline
- Packaging
- 5g
- Price
- $651
- Updated
- 2021/12/16
- Product number
- CHM0097540
- Product name
- 6-NITRO-1,2,3,4-TETRAHYDROQUINOLINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $677.91
- Updated
- 2021/12/16
6-Nitro-1,2,3,4-tetrahydroquinoline Chemical Properties,Usage,Production
Synthesis
613-50-3
14026-45-0
General procedure for the synthesis of 6-nitro-1,2,3,4-tetrahydroquinoline from 6-nitroquinoline: in a 10 mL Schlenk tube, Fe(OTf)2 (0.005 mmol, 1.8 mg), 6-nitroquinoline (0.5 mmol, 72 mg), Hantzsch ester A (1.25 mmol, 318 mg) and 1.0 mL of CHCl3. The reaction mixture was stirred at 40 °C for 2 hours. After completion of the reaction, the reaction solution was concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography to afford the target product 6-nitro-1,2,3,4-tetrahydroquinoline (63.8 mg, 96% yield).
References
[1] Tetrahedron Letters, 2004, vol. 45, # 16, p. 3215 - 3217
[2] ChemCatChem, 2017, vol. 9, # 13, p. 2496 - 2505
[3] Tetrahedron Letters, 2017, vol. 58, # 36, p. 3571 - 3573
[4] Chemical Communications, 2018, vol. 54, # 62, p. 8622 - 8625
[5] Chemical Science, 2017, vol. 8, # 12, p. 8164 - 8169
6-Nitro-1,2,3,4-tetrahydroquinoline Preparation Products And Raw materials
Raw materials
Preparation Products
View Lastest Price from 6-Nitro-1,2,3,4-tetrahydroquinoline manufacturers
- Product
- 6-Nitro-1,2,3,4-tetrahydroquinoline 14026-45-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-09