ChemicalBook > CAS DataBase List > 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate
1-(Diphenylmethyl)-3-azetidinyl methanesulfonate
- Product Name
- 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate
- CAS No.
- 33301-41-6
- Chemical Name
- 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate
- Synonyms
- 1-BENZHYDRYLAZETIDIN-3-YL METHANESULFONATE;BUTTPARK 37\04-14;1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE;1-(Diphenylmethyl)-3-(mesyloxy)azetidine;1-BENZHYDRYL-3-METHANESULFONYLOXY AZETIDINE;1-Benzhydryl-3-methanesulphonyloxyazetidine;1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE 98%;1-Benzhydryl-3-azetidinylMethanesulfonate>1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE CAS;1-DIPHENYLMETHYL-3-AZETIDINYL METHANESULFONATE
- CBNumber
- CB3111828
- Molecular Formula
- C17H19NO3S
- Formula Weight
- 317.4
- MOL File
- 33301-41-6.mol
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1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Property
- Melting point:
- 111-112°C
- Boiling point:
- 459.9±34.0 °C(Predicted)
- Density
- 1.28±0.1 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Dichloromethane, Ether, Ethyl Acetate, Methanol
- form
- Solid
- pka
- 5.67±0.10(Predicted)
- color
- White
- InChI
- InChI=1S/C17H19NO3S/c1-22(19,20)21-16-12-18(13-16)17(14-8-4-2-5-9-14)15-10-6-3-7-11-15/h2-11,16-17H,12-13H2,1H3
- InChIKey
- MSVZMUILYMLJCF-UHFFFAOYSA-N
- SMILES
- N1(C(C2=CC=CC=C2)C2=CC=CC=C2)CC(OS(C)(=O)=O)C1
- CAS DataBase Reference
- 33301-41-6(CAS DataBase Reference)
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Safety
- Safety Statements
- 24/25
- HazardClass
- IRRITANT
- HS Code
- 29339900
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- S906700
- Product name
- 1-(DIPHENYLMETHYL)-3-AZETIDINYL METHANESULFONATE
- Purity
- Aldrich
- Packaging
- 50mg
- Price
- $29.8
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D4131
- Product name
- 1-Benzhydryl-3-azetidinyl Methanesulfonate
- Purity
- >95.0%(HPLC)(T)
- Packaging
- 1g
- Price
- $205
- Updated
- 2023/06/20
Alfa Aesar
- Product number
- H57822
- Product name
- 1-Benzhydryl-3-azetidinyl methanesulfonate, 95%
- Packaging
- 500mg
- Price
- $18.4
- Updated
- 2022/04/27
Alfa Aesar
- Product number
- H57822
- Product name
- 1-Benzhydryl-3-azetidinyl methanesulfonate, 95%
- Packaging
- 250mg
- Price
- $13.5
- Updated
- 2021/12/16
TRC
- Product number
- B196875
- Product name
- 1-Benzhydryl-3-methanesulfonatoazetidine
- Packaging
- 10g
- Price
- $45
- Updated
- 2021/12/16
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1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Chemical Properties,Usage,Production
Chemical Properties
White Crystalline Solid
Uses
A proline analog and proline formation inhibitor
Synthesis
Preparation procedure of 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate: To a reaction flask was charged 632 g (2.64 mol) of 1-benzhydrylazetidin- 3-ol, acetonitrile (1.9 L), and triethylamine (601 g, 1.5 equiv). The mixture was cooled in an ice-acetone bath (-5 °C). Methanesulfonyl chloride (436 g, 1.20 equiv) was added via a drop funnel while keeping the reaction temperature at less than5 °C. HPLC showed reaction completion after 15 min. Water (6.3 L) was added, and the reaction mixture was stirred for 2 h at room temperature and filtered. The filter cake was rinsed with water (2 x 1 L), pulled dry under vacuum, and directly subjected to the amination reaction in the next step. Yield 100%.
1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Suppliers
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View Lastest Price from 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate manufacturers
Henan Fengda Chemical Co., Ltd
- Product
- 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate 33301-41-6
- Price
- US $31.00-1.50/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-10
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate 33301-41-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate 33301-41-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09
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