POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
- Product Name
- POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
- CAS No.
- 54575-49-4
- Chemical Name
- POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE
- Synonyms
- K-selectride;K-SELECTRIDE(R);insuresealtmbottle;k-selectride solution;Potassium tri-sec-butyL;K-Selectride(R) solution;Tributyl potassium borohydride;(ca. 1.0Mol/L in Tetrahydrofuran);Potassium tri(s-butyl)borohydride;Potassium tri-sec-butylborohyride
- CBNumber
- CB3113796
- Molecular Formula
- C12H25BK
- Formula Weight
- 219.24
- MOL File
- 54575-49-4.mol
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Property
- Density
- 0.913 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- Flammables + water-Freezer (-20°C)e area
- form
- Solution
- color
- Clear slightly yellow
- Sensitive
- moisture sensitive
- EPA Substance Registry System
- Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-15-34-37-19-14/15-40
- Safety Statements
- 16-26-36/37/39-43-45
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 3
- F
- 10
- HS Code
- 29310099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H260In contact with water releases flammable gases which may ignite spontaneously
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232Handle under inert gas. Protect from moisture.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378In case of fire: Use … for extinction.
P402+P404Store in a dry place. Store in a closed container.
P403+P235Store in a well-ventilated place. Keep cool.
N-Bromosuccinimide Price
- Product number
- 220760
- Product name
- K-Selectride? solution
- Purity
- 1.0 M potassium tri-sec-butylborohydride in THF
- Packaging
- 100ml
- Price
- $207
- Updated
- 2024/03/01
- Product number
- 220760
- Product name
- K-Selectride? solution
- Purity
- 1.0 M potassium tri-sec-butylborohydride in THF
- Packaging
- 800ml
- Price
- $886
- Updated
- 2024/03/01
- Product number
- 19-1965
- Product name
- Potassium tri-sec-butylborohydride, 1.0M in THF, in Sure/Seal(TM) bottle
- Packaging
- 0.1mole
- Price
- $274
- Updated
- 2024/03/01
- Product number
- 19-1965
- Product name
- Potassium tri-sec-butylborohydride, 1.0M in THF, in Sure/Seal(TM) bottle
- Packaging
- 0.5mole
- Price
- $1091
- Updated
- 2024/03/01
- Product number
- S247980
- Product name
- K-SelectrideSolution(1.0 MinTHF)
- Packaging
- 100ml
- Price
- $385
- Updated
- 2021/12/16
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Chemical Properties,Usage,Production
Description
Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes.
Chemical Properties
clear slightly yellow solution
Uses
Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions.
Uses
- Reducing reagent
Reactant for:
- Preparation of a PCP-pincer palladium hydride-K-Selectride complex
- Formation of P-H, P-C, and C-H bonds by hydride attack
- Stereoselective conjugate hydride reduction reactions
Uses
Mild reducing agents in organic synthesis.
reaction suitability
reagent type: reductant
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Preparation Products And Raw materials
Raw materials
Preparation Products
POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Suppliers
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View Lastest Price from POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE manufacturers
- Product
- POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE 54575-49-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 97%-99.9%
- Supply Ability
- 100kg
- Release date
- 2019-12-26