Use Reaction
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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine

Use Reaction
Product Name
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine
CAS No.
932710-63-9
Chemical Name
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine
Synonyms
AMPhos;AMGN-Phos;4-(di-tert-butylphosphanyl)-N,N-dimethylaniline;95% A-taPhos;Di-tert-butyl(4-diMethylaMinophenyl)phosphine;4-(Di-tert-butylphosphino)-N,N-dimethylaniline;(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95%;(4-(N,N-DiMethylaMino)phenyl)di-tert-butyl phosphine,95% A-taPhos;AmtPhos;Aphos 95%
CBNumber
CB31180195
Molecular Formula
C16H28NP
Formula Weight
265.37
MOL File
932710-63-9.mol
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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Property

Melting point:
57-61°C
Boiling point:
349.1±25.0 °C(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
soluble in Acetone
pka
4.73±0.24(Predicted)
form 
crystal
color 
white to light-brown
InChI
InChI=1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3
InChIKey
IQTHEAQKKVAXGV-UHFFFAOYSA-N
SMILES
C1(N(C)C)=CC=C(P(C(C)(C)C)C(C)(C)C)C=C1
CAS DataBase Reference
932710-63-9
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
2931499090
Storage Class
8B - Non-combustible, corrosive hazardous materials
Hazard Classifications
Skin Corr. 1B
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
677264
Product name
(4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine
Purity
95%
Packaging
1g
Price
$87.9
Updated
2026/03/19
Sigma-Aldrich
Product number
677264
Product name
(4-(N,N-Dimethylamino)phenyl)di-tert-butyl phosphine
Purity
95%
Packaging
5g
Price
$222
Updated
2026/03/19
TCI Chemical
Product number
D4531
Product name
(4-Dimethylaminophenyl)di-tert-butylphosphine
Packaging
1g
Price
$84
Updated
2026/03/19
TCI Chemical
Product number
D4531
Product name
(4-Dimethylaminophenyl)di-tert-butylphosphine
Packaging
5g
Price
$260
Updated
2026/03/19
Strem Chemicals
Product number
15-1248
Product name
[4-(N,N-Dimethylamino)phenyl]di-t-butylphosphine, min. 95% amphos
Packaging
1g
Price
$58
Updated
2024/03/01
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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Chemical Properties,Usage,Production

Use

Bis(di-tert-butyl)-4-dimethylaminophenylphosphine is an organophosphine compound and can be used as an organophosphine ligand.

Reaction

  1. Ligand used in a highly-active palladium precatalyst for the efficient amination of aryl chloride.
  2. Ligand used in the palladium-catalyzed annulations under microwave enhanced conditions.

Uses

Amphos can be used as an electrophotographic photoreceptor, process cartridge, and image forming electrode.

Uses

Ligand used to prepare a palladium dichloride catalyst (678740) on treatment with PdCl2(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reagent type: ligand
reaction type: Cross Couplings

References

[1] Patent: CN105237568, 2017, B. Location in patent: Paragraph 0061-0063

Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(di-tert-butyl)-4-dimethylaminophenylphosphine Suppliers

Xinxiang Runyu Material Co., Ltd.
Tel
166-166-37336996 15690792173
Fax
0373-7759608
Email
chenxi.song@runvmat.com
Country
China
ProdList
282
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55
Beijing Guofang Dingsheng Technology Co., Ltd.
Tel
18610472091 18610472091;
Fax
010-59092859
Email
gfdskj@163.com
Country
China
ProdList
494
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58
Zhengzhou HQ Material Co., Ltd.
Tel
0371-67759225 13526468238
Fax
+86-37155919558
Email
sales@hqmat.com
Country
China
ProdList
812
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55
BeiJing Greenchem Technology Co.,Ltd.
Tel
131-21959385 18804271668
Fax
010-62925455
Email
chemrocking@bjgreenchem.com
Country
China
ProdList
273
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58
Unibest Pharmaceutical Technology Co., Ltd.
Tel
13735578103
Email
jzyz@unibestpharma.com
Country
China
ProdList
129
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58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-65511006 18737115891;18625597674
Email
info@kingorgchem.com;sales@kingorgchem.com
Country
China
ProdList
827
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55
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
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View Lastest Price from Bis(di-tert-butyl)-4-dimethylaminophenylphosphine manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine 932710-63-9
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2026-01-17
Shaanxi Dideu New Materials Co. Ltd
Product
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine 932710-63-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-02-23
XINXIANG RUNYU MATERIAL CO., LTD.
Product
Bis(di-tert-butyl)-4-dimethylaminophenylphosphine 932710-63-9
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
0.98
Supply Ability
500kg
Release date
2021-12-02

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