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4-Aminodiphenylamine

Product Name
4-Aminodiphenylamine
CAS No.
101-54-2
Chemical Name
4-Aminodiphenylamine
Synonyms
N-PHENYL-P-PHENYLENEDIAMINE;4-ADPA;P-AMINODIPHENYLAMINE;VARIAMINE BLUE RT;Variamine Blue RT Base;N-Phenyl-1,4-benzenediamine;N1-phenylbenzene-1,4-diamine;4-N-phenylbenzene-1,4-diamine;UBOB;Semidin
CBNumber
CB9418967
Molecular Formula
C12H12N2
Formula Weight
184.24
MOL File
101-54-2.mol
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4-Aminodiphenylamine Property

Melting point:
69 °C
Boiling point:
354 °C
Density 
1.09
vapor pressure 
1 hPa
refractive index 
1.6266 (estimate)
Flash point:
193°C
storage temp. 
Store below +30°C.
solubility 
ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution)
pka
5.20±0.10(Predicted)
form 
Liquid
Colour Index 
37240
color 
Clear
PH
8.9 (0.5g/l, H2O, 20℃)
Water Solubility 
Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol.
BRN 
908935
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics.
LogP
1.82 at 20℃ and pH7
Dissociation constant
5.45-5.47 at 20℃
CAS DataBase Reference
101-54-2(CAS DataBase Reference)
NIST Chemistry Reference
1,4-Benzenediamine, N-phenyl-(101-54-2)
EPA Substance Registry System
p-Aminodiphenylamine (101-54-2)
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Safety

Hazard Codes 
Xn,Xi,N
Risk Statements 
22-36-43-42/43-36/37/38-20/22-50/53
Safety Statements 
26-36-45-36/37/39-61-60-36/37
RIDADR 
UN3077
WGK Germany 
3
RTECS 
ST3150000
8
Autoignition Temperature
>500 °C
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29215990
Hazardous Substances Data
101-54-2(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
241393
Product name
N-Phenyl-p-phenylenediamine
Purity
98%
Packaging
100g
Price
$51.6
Updated
2024/03/01
Sigma-Aldrich
Product number
241393
Product name
N-Phenyl-p-phenylenediamine
Purity
98%
Packaging
1kg
Price
$196
Updated
2024/03/01
Sigma-Aldrich
Product number
8.14648
Product name
4-Aminodiphenylamine
Purity
for synthesis
Packaging
100g
Price
$34.1
Updated
2022/05/15
Sigma-Aldrich
Product number
8.14648
Product name
4-Aminodiphenylamine
Purity
for synthesis
Packaging
1kg
Price
$141
Updated
2022/05/15
TCI Chemical
Product number
P0203
Product name
Azoic Diazo Component 22
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$18
Updated
2024/03/01
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4-Aminodiphenylamine Chemical Properties,Usage,Production

Description

p-Aminodiphenylamine hydrochloride was formerly used as a hair dye. Sensitization, when deteeted by patch testing, is relatively low in hairdressers.

Chemical Properties

Dark grey flake

Uses

Dye intermediate, pharmaceuticals, photographic chemicals.

Uses

4-Aminodiphenylamine is used as an oxidation dye color in hair dyes. It is also promoted as an efficient reagent for oxidase enzymes, including glucose, lactate, xanthine, and lysine oxidases.

Uses

p-Anilinoaniline is an antioxidant that has shown to cause a reduction of NOx emissions from soybean biodiesel powered DI diesel engines but has increased CO and HC emissions. It is also used to produce dyes, pharmaceuticals, and photographic chemicals and frmerly used as a hair dye.

Definition

ChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine.

General Description

Odorless purple-black solid or flake or dark purple chips.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Aminodiphenylamine is incompatible with strong oxidizers. 4-Aminodiphenylamine is also incompatible with strong acids. 4-Aminodiphenylamine may react with plastics.

Fire Hazard

4-Aminodiphenylamine is combustible.

Contact allergens

This substance was formerly used as a hair dye. Sensitization, when detected by patch testing, is relatively low in hairdressers.

Purification Methods

It crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.]

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4-Aminodiphenylamine Suppliers

SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-69106960 13701823733
Fax
021-69106780
Email
13701823733@163.com
Country
China
ProdList
4776
Advantage
60
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9555
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Beckmann-Kenko GmbH
Tel
+49 4241 9308 88
Fax
+49 4241 9308 89
Email
info@beckmann-kenko.com
Country
Germany
ProdList
479
Advantage
62
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18736
Advantage
57
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View Lastest Price from 4-Aminodiphenylamine manufacturers

Hebei Duling International Trade Co. LTD
Product
4-Aminodiphenylamine 101-54-2
Price
US $67.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 Ton
Release date
2023-04-14
Hebei Mojin Biotechnology Co., Ltd
Product
4-Aminodiphenylamine 101-54-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-07
Hebei Mojin Biotechnology Co., Ltd
Product
4-Aminodiphenylamine 101-54-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-01

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