4-Aminodiphenylamine
- Product Name
- 4-Aminodiphenylamine
- CAS No.
- 101-54-2
- Chemical Name
- 4-Aminodiphenylamine
- Synonyms
- N-PHENYL-P-PHENYLENEDIAMINE;4-ADPA;P-AMINODIPHENYLAMINE;VARIAMINE BLUE RT;Variamine Blue RT Base;N-Phenyl-1,4-benzenediamine;N1-phenylbenzene-1,4-diamine;4-N-phenylbenzene-1,4-diamine;UBOB;Semidin
- CBNumber
- CB9418967
- Molecular Formula
- C12H12N2
- Formula Weight
- 184.24
- MOL File
- 101-54-2.mol
4-Aminodiphenylamine Property
- Melting point:
- 69 °C
- Boiling point:
- 354 °C
- Density
- 1.09
- vapor pressure
- 1 hPa
- refractive index
- 1.6266 (estimate)
- Flash point:
- 193°C
- storage temp.
- Store below +30°C.
- solubility
- ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution)
- pka
- 5.20±0.10(Predicted)
- form
- Liquid
- Colour Index
- 37240
- color
- Clear
- PH
- 8.9 (0.5g/l, H2O, 20℃)
- Water Solubility
- Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol.
- BRN
- 908935
- Stability:
- Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics.
- LogP
- 1.82 at 20℃ and pH7
- Dissociation constant
- 5.45-5.47 at 20℃
- CAS DataBase Reference
- 101-54-2(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,4-Benzenediamine, N-phenyl-(101-54-2)
- EPA Substance Registry System
- p-Aminodiphenylamine (101-54-2)
Safety
- Hazard Codes
- Xn,Xi,N
- Risk Statements
- 22-36-43-42/43-36/37/38-20/22-50/53
- Safety Statements
- 26-36-45-36/37/39-61-60-36/37
- RIDADR
- UN3077
- WGK Germany
- 3
- RTECS
- ST3150000
- F
- 8
- Autoignition Temperature
- >500 °C
- Hazard Note
- Irritant
- TSCA
- Yes
- HazardClass
- 9
- PackingGroup
- III
- HS Code
- 29215990
- Hazardous Substances Data
- 101-54-2(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 241393
- Product name
- N-Phenyl-p-phenylenediamine
- Purity
- 98%
- Packaging
- 100g
- Price
- $51.6
- Updated
- 2024/03/01
- Product number
- 241393
- Product name
- N-Phenyl-p-phenylenediamine
- Purity
- 98%
- Packaging
- 1kg
- Price
- $196
- Updated
- 2024/03/01
- Product number
- 8.14648
- Product name
- 4-Aminodiphenylamine
- Purity
- for synthesis
- Packaging
- 100g
- Price
- $34.1
- Updated
- 2022/05/15
- Product number
- 8.14648
- Product name
- 4-Aminodiphenylamine
- Purity
- for synthesis
- Packaging
- 1kg
- Price
- $141
- Updated
- 2022/05/15
- Product number
- P0203
- Product name
- Azoic Diazo Component 22
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $18
- Updated
- 2024/03/01
4-Aminodiphenylamine Chemical Properties,Usage,Production
Description
p-Aminodiphenylamine hydrochloride was formerly used as a hair dye. Sensitization, when deteeted by patch testing, is relatively low in hairdressers.
Chemical Properties
Dark grey flake
Uses
Dye intermediate, pharmaceuticals, photographic chemicals.
Uses
4-Aminodiphenylamine is used as an oxidation dye color in hair dyes. It is also promoted as an efficient reagent for oxidase enzymes, including glucose, lactate, xanthine, and lysine oxidases.
Uses
p-Anilinoaniline is an antioxidant that has shown to cause a reduction of NOx emissions from soybean biodiesel powered DI diesel engines but has increased CO and HC emissions. It is also used to produce dyes, pharmaceuticals, and photographic chemicals and frmerly used as a hair dye.
Definition
ChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine.
General Description
Odorless purple-black solid or flake or dark purple chips.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
4-Aminodiphenylamine is incompatible with strong oxidizers. 4-Aminodiphenylamine is also incompatible with strong acids. 4-Aminodiphenylamine may react with plastics.
Fire Hazard
4-Aminodiphenylamine is combustible.
Contact allergens
This substance was formerly used as a hair dye. Sensitization, when detected by patch testing, is relatively low in hairdressers.
Purification Methods
It crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.]
4-Aminodiphenylamine Preparation Products And Raw materials
Raw materials
Preparation Products
4-Aminodiphenylamine Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
- Tel
- --
- Fax
- --
- sales-dev@seiko-chem.co.jp
- Country
- Japan
- ProdList
- 33
- Advantage
- 58
- Tel
- --
- Fax
- --
- support@jp-noc.co.jp
- Country
- Japan
- ProdList
- 185
- Advantage
- 71
- Tel
- --
- Fax
- --
- labchem-tec@wako-chem.co.jp
- Country
- Japan
- ProdList
- 6819
- Advantage
- 80
- Tel
- --
- Fax
- --
- reag-info@gms.kanto.co.jp
- Country
- Japan
- ProdList
- 6756
- Advantage
- 74
- Tel
- --
- Fax
- --
- shiyaku@junsei.co.jp
- Country
- Japan
- ProdList
- 3096
- Advantage
- 46
View Lastest Price from 4-Aminodiphenylamine manufacturers
- Product
- 4-Aminodiphenylamine 101-54-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-10-28
- Product
- 4-Aminodiphenylamine 101-54-2
- Price
- US $70.00/kg
- Min. Order
- 10kg
- Purity
- 99 %
- Supply Ability
- 10000kg
- Release date
- 2024-08-21
- Product
- 4-Aminodiphenylamine 101-54-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-09-07