ChemicalBook > CAS DataBase List > 4-Aminodiphenylamine

4-Aminodiphenylamine

Product Name
4-Aminodiphenylamine
CAS No.
101-54-2
Chemical Name
4-Aminodiphenylamine
Synonyms
N-PHENYL-P-PHENYLENEDIAMINE;4-ADPA;P-AMINODIPHENYLAMINE;VARIAMINE BLUE RT;Variamine Blue RT Base;N-Phenyl-1,4-benzenediamine;N1-phenylbenzene-1,4-diamine;4-N-phenylbenzene-1,4-diamine;UBOB;Semidin
CBNumber
CB9418967
Molecular Formula
C12H12N2
Formula Weight
184.24
MOL File
101-54-2.mol
More
Less

4-Aminodiphenylamine Property

Melting point:
69 °C
Boiling point:
354 °C
Density 
1.09
vapor pressure 
1 hPa
refractive index 
1.6266 (estimate)
Flash point:
193°C
storage temp. 
Store below +30°C.
solubility 
ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution)
pka
5.20±0.10(Predicted)
form 
Liquid
Colour Index 
37240
color 
Clear
PH
8.9 (0.5g/l, H2O, 20℃)
Water Solubility 
Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol.
BRN 
908935
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics.
LogP
1.82 at 20℃ and pH7
Dissociation constant
5.45-5.47 at 20℃
CAS DataBase Reference
101-54-2(CAS DataBase Reference)
NIST Chemistry Reference
1,4-Benzenediamine, N-phenyl-(101-54-2)
EPA Substance Registry System
p-Aminodiphenylamine (101-54-2)
More
Less

Safety

Hazard Codes 
Xn,Xi,N
Risk Statements 
22-36-43-42/43-36/37/38-20/22-50/53
Safety Statements 
26-36-45-36/37/39-61-60-36/37
RIDADR 
UN3077
WGK Germany 
3
RTECS 
ST3150000
F 
8
Autoignition Temperature
>500 °C
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29215990
Hazardous Substances Data
101-54-2(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
241393
Product name
N-Phenyl-p-phenylenediamine
Purity
98%
Packaging
100g
Price
$51.6
Updated
2024/03/01
Sigma-Aldrich
Product number
241393
Product name
N-Phenyl-p-phenylenediamine
Purity
98%
Packaging
1kg
Price
$196
Updated
2024/03/01
Sigma-Aldrich
Product number
8.14648
Product name
4-Aminodiphenylamine
Purity
for synthesis
Packaging
100g
Price
$34.1
Updated
2022/05/15
Sigma-Aldrich
Product number
8.14648
Product name
4-Aminodiphenylamine
Purity
for synthesis
Packaging
1kg
Price
$141
Updated
2022/05/15
TCI Chemical
Product number
P0203
Product name
Azoic Diazo Component 22
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$18
Updated
2024/03/01
More
Less

4-Aminodiphenylamine Chemical Properties,Usage,Production

Description

p-Aminodiphenylamine hydrochloride was formerly used as a hair dye. Sensitization, when deteeted by patch testing, is relatively low in hairdressers.

Chemical Properties

Dark grey flake

Uses

Dye intermediate, pharmaceuticals, photographic chemicals.

Uses

4-Aminodiphenylamine is used as an oxidation dye color in hair dyes. It is also promoted as an efficient reagent for oxidase enzymes, including glucose, lactate, xanthine, and lysine oxidases.

Uses

p-Anilinoaniline is an antioxidant that has shown to cause a reduction of NOx emissions from soybean biodiesel powered DI diesel engines but has increased CO and HC emissions. It is also used to produce dyes, pharmaceuticals, and photographic chemicals and frmerly used as a hair dye.

Definition

ChEBI: An aromatic amine that is the 4-amino derivative of diphenylamine.

General Description

Odorless purple-black solid or flake or dark purple chips.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Aminodiphenylamine is incompatible with strong oxidizers. 4-Aminodiphenylamine is also incompatible with strong acids. 4-Aminodiphenylamine may react with plastics.

Fire Hazard

4-Aminodiphenylamine is combustible.

Contact allergens

This substance was formerly used as a hair dye. Sensitization, when detected by patch testing, is relatively low in hairdressers.

Purification Methods

It crystallises from EtOH with m 66o, and from ligroin with m 75o. It can be distilled at high vacuum. [Beilstein 13 IV 113.]

4-Aminodiphenylamine Preparation Products And Raw materials

Raw materials

Anhydrous hydrogen chloride METANIL YELLOW Diphenyl 4-Chloronitrobenzene 4-NITROSODIPHENYLAMINE Sodium sulfide Potassium carbonate Formic acid Cupric oxide Aniline Hydrogen N-Nitrosodiphenylamine 4-Nitrodiphenylamine Nitrobenzene FORMANILIDE

Preparation Products

Direct Blue 106 N-(1,3-Dimethylbutyl)-N'-phenyl-p-phenylenediamine 4-Diazodiphenylamine sulfate N-Isopropyl-N'-phenyl-1,4-phenylenediamine 4-Aminodiphenylamine
More
Less

4-Aminodiphenylamine Suppliers

Americas 1 Belgium 2 China 162 Europe 6 France 2 Germany 7 India 14 Italy 2 Japan 6 Russia 1 Slovakia 1 South Korea 1 Switzerland 3 The Netherlands 1 United Kingdom 8 United States 29 Global 246
SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-69106960 13701823733
Fax
021-69106780
Email
13701823733@163.com
Country
China
ProdList
4767
Advantage
60
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9413
Advantage
66
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Chemwill Asia Co.,Ltd.
Tel
86-21-51086038
Fax
86-21-51861608
Country
China
ProdList
2930
Advantage
58
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
13350
Advantage
58
Suzhou yacoo science co.,Ltd
Tel
0512-87182056 18013166090
Fax
0512-87182056
Email
lingling.qi@yacoo.com.cn
Country
China
ProdList
7295
Advantage
60
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Shanghai Song Yuan Chemical Technology Co., Ltd.
Tel
010-1234567 18521000990
Fax
86-021-33275113
Email
sonyuanchemical@163.com
Country
China
ProdList
6479
Advantage
50
Shanghai YouPeng Chemical Co. Ltd.
Tel
021-69005955 13701776567
Fax
021-69005775
Email
youpengchem@163.com
Country
China
ProdList
4293
Advantage
56
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 18112977050
Email
cb6@aikonchem.com
Country
China
ProdList
16684
Advantage
50
Shanghai TongYuan Chemical Co., Ltd.
Tel
021-021-69182866 13701855675
Fax
021-69182022
Email
tongyuanchem@126.com
Country
China
ProdList
4321
Advantage
58
Shanghai Kaisai Chemical Co., Ltd
Tel
021-33516722 13701817765
Fax
021-33516776
Email
kaisaichem@163.com
Country
China
ProdList
4741
Advantage
58
Shanghai LanRun Chemical Co., Ltd.
Tel
021-69515658 ; 69515628 13701998368
Fax
021-69515998
Email
longrunchem@163.com
Country
China
ProdList
3912
Advantage
50
Shanghai Rolead Chemical Technology Co., Ltd.
Tel
021-69992220 13701886816
Fax
021-69992237
Email
roleadchem@163.com
Country
China
ProdList
4750
Advantage
50
Shanghai Kangtuo Chemical Co., Ltd.
Tel
021-69185552 13701777608
Fax
021-69186006
Email
kangtuochem@163.com
Country
China
ProdList
4360
Advantage
55
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Giant chemicals
Tel
028-85434334 18108076537
Fax
QQ：245797092
Email
market@gianthx.com
Country
China
ProdList
4505
Advantage
56
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
17687
Advantage
55
Shanghai Xilong Biochemical Technology Co., Ltd.
Tel
021-52907766-8042
Fax
021-52906523
Country
China
ProdList
9941
Advantage
58
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20806
Advantage
60
Chengdu Dianchun Technology Co., Ltd
Tel
400-1166-196 18502815961
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
14603
Advantage
60
Grader reagent
Tel
18221735425
Email
sales@xinpingchem.com
Country
China
ProdList
9942
Advantage
58
Shenzhen Simeiquan Biotechnology Co. Ltd
Tel
18126413629 0755-23311925 2355327053
Fax
0755-23311925
Email
abel@ycgmp.com
Country
China
ProdList
5113
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Guangdong wengjiang Chemical Reagent Co., Ltd.
Tel
0751-2886750 13927877953
Fax
0751-2886750
Email
3005811397@qq.com
Country
China
ProdList
13320
Advantage
58
Shenzhen Sendi Biological Technology Co., Ltd.
Tel
18124570582 TEL：0755-23574479 2355327139
Fax
0755-23229476 QQ: 2355327139
Email
siliao02@yccreate.com
Country
China
ProdList
6116
Advantage
58
Guangzhou Kafen Biotech Co.,Ltd
Tel
18029243487 2355327168
Fax
020-31121510
Email
gy@yccreate.com
Country
China
ProdList
4749
Advantage
55
Wuhai Shuou Technology Co., Ltd.
Tel
17792809151
Fax
18872220797
Email
2355916837@ycphar.com
Country
China
ProdList
6133
Advantage
55
Beyond IndustriesChina Limited
Tel
15021878111
Fax
021-62570268
Email
2355354501@qq.com
Country
China
ProdList
937
Advantage
55
Taian Jiaye Biotechnology Co.Ltd
Tel
13127280945
Email
285424065@qq.com
Country
China
ProdList
9976
Advantage
55
Guangzhou Jhd Chemical Reagent Co., Ltd.
Tel
020-84383047
Fax
020-84380294
Email
sales@jhd.com.cn
Country
China
ProdList
9186
Advantage
65
Shanghai Orgchem Co.,Ltd.
Tel
+86-21-5877 1921
Fax
+86-21-5877 1925
Email
info@chemofchina.com
Country
China
ProdList
9653
Advantage
55
Shandong Ono Chemical Co., Ltd.
Tel
0539-6362799 20）
Fax
0539-6362799（To 20）
Country
China
ProdList
9998
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
021-021-52271985 17721149837
Fax
+86 (21) 52271987
Email
sales@9dingchem.com
Country
China
ProdList
19800
Advantage
60
Shanghai BaiShun Biological Technology Co., Ltd
Tel
021-37581181
Fax
021-57456066
Email
sales@chem-mall.com
Country
China
ProdList
10330
Advantage
58
More
Less

View Lastest Price from 4-Aminodiphenylamine manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
4-Aminodiphenylamine 101-54-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-10-28
Hebei Chuanghai Biotechnology Co,.LTD
Product
4-Aminodiphenylamine 101-54-2
Price
US $70.00/kg
Min. Order
10kg
Purity
99 %
Supply Ability
10000kg
Release date
2024-08-21
Hebei Mojin Biotechnology Co., Ltd
Product
4-Aminodiphenylamine 101-54-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-07

101-54-2, 4-AminodiphenylamineRelated Search:

4-(2,4-DINITROANILINO)PHENOL REACTIVE BLACK 5 ACID BLUE 41 HexanitrodiphenylaMine ACID BLUE 120 ACID BLUE 40 4-NITROSODIPHENYLAMINE Solvent Green 3 ACID BLACK 24 4-(PHENYLAZO)DIPHENYLAMINE LUXOL FAST BLUE ARN ACID BLUE 80 Benzenediamine, N,N'-diphenyl- ACID BLUE 113 Acid Green 25 2,4-Dinitrodiphenylamine REACTIVE BLUE 4 ACID GREEN 27 (C.I. 61580)

  • 4-(Phenylamino)aniline
  • 4-amino-diphenylamin
  • VARIAMINE BLUE RT
  • Variamine Blue RT Base
  • Fast Blue R Salt
  • fastbluersalt
  • FastblueRTbase
  • Luxan Black R
  • luxanblackr
  • n-(4-aminophenyl)aniline
  • n-(4-aminophenyl)aniline(ci
  • n-(4-aminophenyl)aniline(ci76085)
  • n,4’-bianiline
  • N-4'-Bianiline
  • Naphthoelan Navy Blue
  • naphthoelannavyblue
  • NCI-C02233
  • N-Fenyl-p-fenylendiamin
  • N-Phenyl-1,4-benzenediamine
  • n-phenyl-4-benzenediamine
  • N-Phenyl-p-aminoaniline
  • n-phenyl-p-phenylenediamin
  • Oxy Acid Black Base
  • oxyacidblackbase
  • p-(Phenylamino)aniline
  • p-Aminodifenylamin
  • p-aminodifenylamin(czech)
  • p-amino-diphenylamin
  • p-Anilinoaniline
  • Peltol BR
  • Peltol BR II
  • peltolbr
  • peltolbrii
  • p-Phenylenediamine, N-phenyl-
  • p-Semidine
  • rodolgraybbase
  • acnablackdfbase
  • Azosalt R
  • azosaltr
  • Benzenediamine, N-phenyl-
  • blackbasep
  • C.I. 76085
  • C.I. Azoic Diazo Component 22
  • C.I. Developer 15
  • C.I. Oxidation Base 2
  • c.i.76085
  • c.i.azoicdiazocomponent22
  • c.i.developer15
  • Semidin
  • Semidine
  • UBOB
  • Variamine Blue Salt RT
  • 1,4-Benzenediamine, N1-phenyl-
  • c.i.oxidationbase2
  • ci76085
  • ciazoicdiazocomponent22
  • cideveloper15
  • cioxidationbase2