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ChemicalBook > CAS DataBase List > (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh

(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh

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Product Name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh
CAS No.
78355-59-6
Chemical Name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh
Synonyms
(S,S)-NORPHOS-Rh;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-NORPHOS-Rh;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh;(1Z,5Z)-cycloocta-1,5-diene:[(1R,2S,3S,4S)-2-diphenylphosphanyl-3-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane:rhodium:tetrafluoroborate;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh
CBNumber
CB31180968
Molecular Formula
C39H38BF4P2Rh
Formula Weight
758.39
MOL File
78355-59-6.mol
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(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh Property

form 
Powder
color 
red-orange
Sensitive 
air sensitive
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals
Product number
45-0185
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh
Packaging
100mg
Price
$129
Updated
2024/03/01
Strem Chemicals
Product number
45-0185
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh
Packaging
500mg
Price
$512
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0001177
Product name
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
Purity
95.00%
Packaging
100MG
Price
$657.31
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0001177
Product name
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
Purity
95.00%
Packaging
500MG
Price
$994.46
Updated
2021/12/16
Arctom
Product number
AS616907
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate
Purity
98%
Packaging
100mg
Price
$103
Updated
2021/12/16
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(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh Chemical Properties,Usage,Production

Reactions

  1. Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
  2. Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
  3. Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines. 

(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh Preparation Products And Raw materials

Raw materials

Preparation Products

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(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh Suppliers

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78355-59-6, (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-RhRelated Search:

(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh (S)-(-)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE 1,2-Bis(diphenylphosphino)ethane 1,5-Bis(diphenylphosphino)pentane

  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-<br />cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh
  • (1Z,5Z)-cycloocta-1,5-diene:[(1R,2S,3S,4S)-2-diphenylphosphanyl-3-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane:rhodium:tetrafluoroborate
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-NORPHOS-Rh
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
  • (S,S)-NORPHOS-Rh
  • 78355-59-6
  • organometallic complex