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ChemicalBook > CAS DataBase List > (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE

(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE

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Product Name
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
CAS No.
71042-54-1
Chemical Name
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
Synonyms
(S,S)-NORPHOS;(2S,3S)-(+)-Norphos;(1R,4S,5S,6S)-5,6-Dibenzhydrylbicyclo[2.2.1]hept-2-ene;(1S,4R)-5α,6β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene;(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene,95%;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene >(1R,4S,5S,6S)-5,6-Bis(diphenylphosphaneyl)bicyclo[2.2.1]hept-2-ene
CBNumber
CB0148870
Molecular Formula
C31H28P2
Formula Weight
462.5
MOL File
71042-54-1.mol
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Property

Melting point:
120 °C
alpha 
+47° (c 1, CHCl3)
Boiling point:
577.0±50.0 °C(Predicted)
form 
crystal
color 
white
Sensitive 
air sensitive
CAS DataBase Reference
71042-54-1
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
TSCA 
No
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3450
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
Purity
>98.0%(GC)
Packaging
100mg
Price
$245
Updated
2024/03/01
Strem Chemicals
Product number
15-0141
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (S,S)-NORPHOS
Packaging
250mg
Price
$239
Updated
2024/03/01
Strem Chemicals
Product number
15-0141
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (S,S)-NORPHOS
Packaging
1g
Price
$718
Updated
2024/03/01
TRC
Product number
B430440
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene
Packaging
1mg
Price
$45
Updated
2021/12/16
TRC
Product number
B430440
Product name
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene
Packaging
2mg
Price
$60
Updated
2021/12/16
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Chemical Properties,Usage,Production

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  1. Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
  2. Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
  3. Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.

Chemical Properties

White crystalline powder

(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Suppliers

J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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China
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View Lastest Price from (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene 71042-54-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

71042-54-1, (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENERelated Search:


  • (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
  • (S,S)-NORPHOS
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene,min.95%(S,S)-NORPHOS
  • (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE (S,S)-NORPHOS, (C 1,CHCL3)
  • (1S,4R)-5α,6β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene
  • [[1R,4S,(+)]-Bicyclo[2.2.1]hept-5-ene-2α,3β-diyl]bis(diphenylphosphine)
  • [[1R,4S,(+)]-Bicyclo[2.2.1]hepta-5-ene-2α,3β-diyl]bis(diphenylphosphine)
  • [1R,2S,3S,4S,(+)]-2α,3β-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
  • [1R,2S,3S,4S,(+)]-2α,3β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-5-ene
  • (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene,95%
  • (2S,3S)-(+)-Norphos
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95%
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene (S,S)-NORPHOS
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene, Min. 97% (S,S)-NORPHOS
  • (1R,2S,3S,4S)-Bicyclo[2.2.1]hept-5-ene-2,3-diylbis[diphenylphosphine]
  • Phosphine,1,1'-(1R,2S,3S,4S)-bicyclo[2.2.1]hept-5-ene-2,3-diylbis[1,1-diphenyl-
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene, (S,S)-NORPHOS
  • (1R,4S,5S,6S)-5,6-Dibenzhydrylbicyclo[2.2.1]hept-2-ene
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene &gt
  • (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene
  • (1R,4S,5S,6S)-5,6-Bis(diphenylphosphaneyl)bicyclo[2.2.1]hept-2-ene
  • 71042-54-1
  • Chiral Phosphine
  • NORPhos Series
  • organophosphine ligand