ChemicalBook > CAS DataBase List > (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
Reaction- Product Name
- (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
- CAS No.
- 71042-54-1
- Chemical Name
- (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
- Synonyms
- (S,S)-NORPHOS;(2S,3S)-(+)-Norphos;(1R,4S,5S,6S)-5,6-Dibenzhydrylbicyclo[2.2.1]hept-2-ene;(1S,4R)-5α,6β-Bis(diphenylphosphino)bicyclo[2.2.1]hepta-2-ene;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicylo[2.2.1]hept-5-ene;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicycle(2.2.1)hept-5-ene;(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE;(2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene,95%;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene >(1R,4S,5S,6S)-5,6-Bis(diphenylphosphaneyl)bicyclo[2.2.1]hept-2-ene
- CBNumber
- CB0148870
- Molecular Formula
- C31H28P2
- Formula Weight
- 462.5
- MOL File
- 71042-54-1.mol
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Property
- Melting point:
- 120 °C
- alpha
- +47° (c 1, CHCl3)
- Boiling point:
- 577.0±50.0 °C(Predicted)
- form
- crystal
- color
- white
- Sensitive
- air sensitive
- CAS DataBase Reference
- 71042-54-1
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Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- TSCA
- No
- HS Code
- 29310099
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- B3450
- Product name
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene
- Purity
- >98.0%(GC)
- Packaging
- 100mg
- Price
- $245
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0141
- Product name
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (S,S)-NORPHOS
- Packaging
- 250mg
- Price
- $239
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0141
- Product name
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene, min. 95% (S,S)-NORPHOS
- Packaging
- 1g
- Price
- $718
- Updated
- 2024/03/01
TRC
- Product number
- B430440
- Product name
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene
- Packaging
- 1mg
- Price
- $45
- Updated
- 2021/12/16
TRC
- Product number
- B430440
- Product name
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)-bicyclo[2.2.1]hept-5-ene
- Packaging
- 2mg
- Price
- $60
- Updated
- 2021/12/16
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Chemical Properties,Usage,Production
Reaction
- Ligand used in the enantioselective rhodium catalyzed hydrogenation of α–dehydroaminoesters and enamides.
- Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.
- Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
Chemical Properties
White crystalline powder
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Preparation Products And Raw materials
Raw materials
Preparation Products
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(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE Suppliers
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View Lastest Price from (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE manufacturers
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene 71042-54-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
71042-54-1, (2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENERelated Search:
(2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE
Diphenylphosphine
(S)-(-)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE
1,2-Bis(diphenylphosphino)ethane
1,5-Bis(diphenylphosphino)pentane
1,2-BIS(PHENYLPHOSPHINO)ETHANE
diphenyl(2-phosphinoethyl)phosphine
(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh
1,2-Bis-(diphenylphosphino)propane
Norbornene
(2S,3S)-(+)-2,3-BIS(DIPHENYLPHOSPHINO)-BICYCLO[2.2.1]HEPT-5-ENE
(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE