(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

Uses

Product Name: (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS No.: 150971-43-0
Chemical Name: (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms: SL-A116-2;(S)-iPr-MeOBIPHEP;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine);(S)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diisopropylphosphine);(S)-(-)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy- 1,1'-biphenyl;(S)-(-)-2,2''-Bis(di-i-propylphosphino)-6,6''-dimethoxy-1,1''-biphenyl;(S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diisopropylphosphine);(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
CBNumber: CB31180988
Molecular Formula: C26H40O2P2
Formula Weight: 446.54
MOL File: 150971-43-0.mol

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(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property

Boiling point:: 517.2±50.0 °C(Predicted)
form: Powder
color: white
InChI: 1S/C26H40O2P2/c1-17(2)29(18(3)4)23-15-11-13-21(27-9)25(23)26-22(28-10)14-12-16-24(26)30(19(5)6)20(7)8/h11-20H,1-10H3
InChIKey: HLLUWVKDDQIKNF-UHFFFAOYSA-N
SMILES: COc1cccc(P(C(C)C)C(C)C)c1-c2c(OC)cccc2P(C(C)C)C(C)C

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Safety

WGK Germany: 3
HS Code: 29319090
Storage Class: 13 - Non Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-0655
Product name: (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 100mg
Price: $96
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0655
Product name: (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 500mg
Price: $355
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0655
Product name: (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 2g
Price: $1207
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0655
Product name: (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 10g
Price: $4824
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: ING0001337
Product name: (S)-(-)-2,2'-BIS(DI-I-PROPYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL
Purity: 95.00%
Packaging: 1G
Price: $1269.75
Updated: 2021/12/16

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(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production

Uses

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.

Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
Conjugate addition using 2-heteroaryl titanates and zinc reagents.

Chemical Properties

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% is off-white powder

Uses

Atropisomeric MeOBIPHEP ligands

General Description

sold in collaboration with Solvias AG

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

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View Lastest Price from (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers

Career Henan Chemical Co

Product: (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% 150971-43-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-08-08

150971-43-0, (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%Related Search:

(S)-(-)-2,2'-BIS(DICYCLOBUTYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy- 1,1'-biphenyl

(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97%, optical purity ee: >=99%

(S)-(-)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%

(S)-(-)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl

(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine)

(S)-iPr-MeOBIPHEP, SL-A116-2, (S)-2,2μ-Bis(diisopropylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl

(S)-iPr-MeOBIPHEP

SL-A116-2

Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(1-methylethyl)-

(S)-(-)-2,2''-Bis(di-i-propylphosphino)-6,6''-dimethoxy-1,1''-biphenyl

(S)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diisopropylphosphine)

(<i>S</i>)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diisopropylphosphine)

(S)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diisopropylphosphine), CAS 150971-43-0

150971-43-0

C26H40O2P2

Chiral Phosphine

MeOBIPHEP Series