Uses
ChemicalBook > CAS DataBase List > (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

Uses
Product Name
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS No.
150971-43-0
Chemical Name
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms
SL-A116-2;(S)-iPr-MeOBIPHEP;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine);(S)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diisopropylphosphine);(S)-(-)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy- 1,1'-biphenyl;(S)-(-)-2,2''-Bis(di-i-propylphosphino)-6,6''-dimethoxy-1,1''-biphenyl;(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(1-methylethyl)-
CBNumber
CB31180988
Molecular Formula
C26H40O2P2
Formula Weight
446.54
MOL File
150971-43-0.mol
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(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property

Boiling point:
517.2±50.0 °C(Predicted)
form 
Powder
color 
white
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Safety

WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-0655
Product name
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
15-0655
Product name
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
15-0655
Product name
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
2g
Price
$1207
Updated
2024/03/01
Strem Chemicals
Product number
15-0655
Product name
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging
10g
Price
$4824
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0001337
Product name
(S)-(-)-2,2'-BIS(DI-I-PROPYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL
Purity
95.00%
Packaging
1G
Price
$1269.75
Updated
2021/12/16
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(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production

Uses

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.

  1. Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
  2. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
  3. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
  4. Conjugate addition using 2-heteroaryl titanates and zinc reagents.

Chemical Properties

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% is off-white powder

Uses

Atropisomeric MeOBIPHEP ligands

General Description

sold in collaboration with Solvias AG

(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% manufacturers

Career Henan Chemical Co
Product
(S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% 150971-43-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

150971-43-0, (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%Related Search:


  • (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • (S)-(-)-2,2'-Bis(di-i-propylphosphino)-6,6'-dimethoxy- 1,1'-biphenyl
  • (S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diisopropylphosphine) >=97%, optical purity ee: >=99%
  • (S)-(-)-2,2''-BIS(DI-I-PROPYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
  • (S)-(-)-2,2'-Bis(di-isopropylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • (S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(diisopropylphosphine)
  • (S)-iPr-MeOBIPHEP, SL-A116-2, (S)-2,2μ-Bis(diisopropylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
  • (S)-iPr-MeOBIPHEP
  • SL-A116-2
  • Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(1-methylethyl)-
  • (S)-(-)-2,2''-Bis(di-i-propylphosphino)-6,6''-dimethoxy-1,1''-biphenyl
  • (S)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diisopropylphosphine)
  • 150971-43-0
  • C26H40O2P2
  • Chiral Phosphine
  • MeOBIPHEP Series