ChemicalBook > CAS DataBase List > Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Product Name
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
CAS No.
220114-38-5
Chemical Name
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
Synonyms
(R) -DM-BINAP RUCL2 (R.R)-DPEN;RuCl?[(R)-DM-BINAP][(R,R)-DPEN];RuCl2[(R)-xylbinap][(R,R)-dpen];RuCl2[(R)-DM-BINAP][(R,R)-DPEN];RUCL2[(R)-DM-BINAP][(R,R)-DPEN] 1G;Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl};-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(;Dichloro[(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(R,R)-1,2-diphenylethylenediamine]ruthenium(II);Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II);Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
CBNumber
CB31181071
Molecular Formula
C66H64Cl2N2P2Ru
Formula Weight
1119.17
MOL File
220114-38-5.mol
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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Property

storage temp. 
2-8°C
form 
Powder
color 
yellow
Sensitive 
air sensitive
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Safety

WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692301
Product name
RuCl2[(R)?DM?BINAP][(R,R)?DPEN]
Packaging
50mg
Price
$33.8
Updated
2024/03/01
Sigma-Aldrich
Product number
692301
Product name
RuCl2[(R)?DM?BINAP][(R,R)?DPEN]
Packaging
100mg
Price
$48.6
Updated
2023/06/20
TCI Chemical
Product number
R0135
Product name
RuCl2[(R)-xylbinap][(R,R)-dpen]
Packaging
200mg
Price
$75
Updated
2024/03/01
TCI Chemical
Product number
R0135
Product name
RuCl2[(R)-xylbinap][(R,R)-dpen]
Packaging
1g
Price
$253
Updated
2024/03/01
Strem Chemicals
Product number
44-0226
Product name
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
Packaging
250mg
Price
$64
Updated
2024/03/01
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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Chemical Properties,Usage,Production

Uses

RuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.

General Description

The product is a bis-naphthalene containing phosphine ligand, in conjugation with a ruthenium complex.

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) Suppliers

China 22 India 3 Japan 2 Switzerland 1 United States 4 Global 32
TCI Chemicals (India) Pvt. Ltd.
Tel
--
Fax
--
Email
sales-in@tcichemicals.com
Country
India
ProdList
6768
Advantage
58
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View Lastest Price from Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) manufacturers

Career Henan Chemical Co
Product
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) 220114-38-5
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

220114-38-5, Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)Related Search:

1,2-Diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (R)-DM-BINAP DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

  • Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
  • RuCl2[(R)-DM-BINAP][(R,R)-DPEN]
  • RuCl2[(R)-xylbinap][(R,R)-dpen]
  • Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
  • -binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(
  • RUCL2[(R)-DM-BINAP][(R,R)-DPEN] 1G
  • DICHLORO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[(
  • Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}
  • Dichloro[(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(R,R)-1,2-diphenylethylenediamine]ruthenium(II)
  • (R) -DM-BINAP RUCL2 (R.R)-DPEN
  • RuCl?[(R)-DM-BINAP][(R,R)-DPEN]
  • Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
  • 1,1′-(1R)-[1,1′-Binaphthalene]-2,2′-diylbis[1,1-bis(3,5-dimethylphenyl)phosphine-κP]]dichloro[(1R,2R)-1,2-diphenyl-1,2-ethanediamine-κN1,κN2]ruthenium
  • Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(R)-xylbinap][(R,R)-dpen]
  • 220114-38-5
  • C66H64Cl2N2P2Ru
  • Ru