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ChemicalBook > CAS DataBase List > Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)

Reaction
Product Name
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
CAS No.
488809-34-3
Chemical Name
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
Synonyms
(S)-[(RuCl(SEGPHOS;))?(μ-Cl)?][NH?Me?];NH2ME2][(RUCL((S)-SEGPHOS))2(U-CL)3;(S)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2];[NH2ME2][(RUCL((S)-SEGPHOS))2(Μ-CL)3];[NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3];(S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2];(S)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2];[NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3];Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
CBNumber
CB31181091
Molecular Formula
C78H68Cl5NO8P4Ru2
Formula Weight
1650.69
MOL File
488809-34-3.mol
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Property

Melting point:
>100°C
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
Powder
color 
light brown
Sensitive 
air sensitive
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Safety

WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H360May damage fertility or the unborn child

H371May cause damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
693162
Product name
(S)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2]
Packaging
50mg
Price
$25.5
Updated
2023/01/07
Sigma-Aldrich
Product number
693162
Product name
(S)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2]
Packaging
100mg
Price
$44
Updated
2023/01/07
TCI Chemical
Product number
N1022
Product name
[NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3]
Packaging
200mg
Price
$56
Updated
2024/03/01
TCI Chemical
Product number
N1022
Product name
[NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3]
Packaging
1g
Price
$180
Updated
2024/03/01
Strem Chemicals
Product number
44-0519
Product name
Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos(R))}2(μ-Cl)3]
Packaging
250mg
Price
$53
Updated
2024/03/01
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Chemical Properties,Usage,Production

Reaction

  1. Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature. 
  2. Catalyst for enantioselective hydrogenation of enamines. 

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Suppliers

Americas 1 China 20 Europe 1 India 1 Japan 1 Switzerland 1 United States 5 Global 30
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488809-34-3, Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)Related Search:

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　 Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

  • [NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3]
  • [NH2ME2][(RUCL((S)-SEGPHOS))2(Μ-CL)3]
  • DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]DIRUTHENATE(II),[NH2ME2][
  • Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
  • (S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2]
  • Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II)
  • Dimethylammonium dichlorotri(chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(Cl)3]
  • DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(μ-Cl)3]
  • (S)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2]
  • Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos(R))}2(μ-Cl)3]
  • [NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3]
  • (S)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2]
  • NH2ME2][(RUCL((S)-SEGPHOS))2(U-CL)3
  • (S)-[(RuCl(SEGPHOS
  • ))?(μ-Cl)?][NH?Me?]
  • Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
  • 488809-34-3
  • CH32NH2C76H56Cl5O8P4Ru28722
  • Ru