ChemicalBook > CAS DataBase List > Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Product Name
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
CAS No.
346457-41-8
Chemical Name
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms
(R)-Ru(OAc)2(BINAP);(R)-[(RUCL(SEGPHOS)2(Μ-CL)3[NH2ME2];NH2ME2][(RUCL((R)-SEGPHOS))2(U-CL)3;(R)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2];[NH2ME2][(RUCL((R)-SEGPHOS))2(Μ-CL)3];(R)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2];[NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3];(R)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2];[NH2Me2][(RuCl((R)-segphos(regR)))2(mu-Cl)3];-bi-1,3-benzodioxole]diruthenate(II),[NH2Me2][
CBNumber
CB11181057
Molecular Formula
2C38H28O4P2.C2H7N.Cl.Cl3Ru2.ClH
Formula Weight
1646.66
MOL File
346457-41-8.mol
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Property

Melting point:
>100°C
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
Powder
color 
light brown
Sensitive 
air sensitive
CAS DataBase Reference
346457-41-8
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Safety

WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H360May damage fertility or the unborn child

H371May cause damage to organs

H373May cause damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692204
Product name
(R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2]
Packaging
50mg
Price
$32.8
Updated
2024/03/01
Sigma-Aldrich
Product number
692204
Product name
(R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2]
Packaging
100mg
Price
$54.9
Updated
2023/06/20
TCI Chemical
Product number
N1021
Product name
[NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3]
Packaging
200mg
Price
$52
Updated
2024/03/01
TCI Chemical
Product number
N1021
Product name
[NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3]
Packaging
1g
Price
$162
Updated
2024/03/01
Strem Chemicals
Product number
44-0518
Product name
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos(R))}2(μ-Cl)3]
Packaging
250mg
Price
$53
Updated
2024/03/01
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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties,Usage,Production

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

General Description

(R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS?, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Suppliers

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346457-41-8, Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)Related Search:

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　 Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Tris(triphenylphosphine)ruthenium(II) chloride (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) RUTHENIUM(III) CHLORIDE TRIHYDRATE Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole]diruthenate(II)

  • Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
  • (R)-Ru(OAc)2(BINAP)
  • Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos)}2(Cl)3]
  • (R)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2]
  • (R)-[(RUCL(SEGPHOS)2(Μ-CL)3[NH2ME2]
  • [NH2Me2][(RuCl((R)-segphos(regR)))2(mu-Cl)3]
  • (R)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2]
  • [NH2ME2][(RUCL((R)-SEGPHOS))2(Μ-CL)3]
  • (R)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2]
  • Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II)
  • -bi-1,3-benzodioxole]diruthenate(II),[NH2Me2][
  • DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(R)-(+)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]DIRUTHENATE(II),[NH2ME2][
  • Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos(R))}2(μ-Cl)3]
  • [NH2Me2][(RuCl((R)-segphos[R]))2(μ-Cl)3]
  • NH2ME2][(RUCL((R)-SEGPHOS))2(U-CL)3
  • DiMethylaMMoniuMdichlorotri(μ-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
  • Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II), [NH2Me2][{RuCl((R)-segphos)}2(μ-Cl)3
  • 346457-41-8
  • C78H55Cl5NO8P4Ru2
  • C78H64Cl5NO8P4Ru2
  • C78H64Cl5O8P4Ru2N
  • C76H56Cl5O8P4Ru2C2H7NH
  • C48H38O4P2Ru
  • CH32NH2C76H56Cl5O8P4Ru2
  • Ru