DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
- Product Name
- DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
- CAS No.
- 19529-00-1
- Chemical Name
- DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
- Synonyms
- Dihydridotetrakis(triphenyL;ruthenium,triphenylphosphane;Dihydrotetrakis(triphenylphosphine)ruthenium;Tetrakis(triphenylphosphine)ruthenium dihydride;Dihydridotetrakis(triphenylphosphine)ruthenium(Ⅱ);TETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) HYDRIDE;dihydridotetrakis(triphenylphosphine)-ruthenium(I;DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II);Dihydridotetrakis(triphenylphosphine)ruthenium(Il);DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
- CBNumber
- CB5288861
- Molecular Formula
- C72H62P4Ru
- Formula Weight
- 1152.23
- MOL File
- 19529-00-1.mol
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Property
- Melting point:
- 181-183 °C(lit.)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Slightly soluble in benzene, toluene, and THF.
- form
- Lustrous Powder
- color
- Ochre
- Sensitive
- air sensitive
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 335037
- Product name
- Dihydridotetrakis(triphenylphosphine)ruthenium(II)
- Packaging
- 500mg
- Price
- $144
- Updated
- 2024/03/01
- Product number
- 44-0460
- Product name
- Dihydrotetrakis(triphenylphosphine)ruthenium(II), 95%
- Packaging
- 250mg
- Price
- $73
- Updated
- 2024/03/01
- Product number
- 44-0460
- Product name
- Dihydrotetrakis(triphenylphosphine)ruthenium(II), 95%
- Packaging
- 1g
- Price
- $219
- Updated
- 2024/03/01
- Product number
- 300383
- Product name
- Dihydridotetrakis(triphenylphosphine)ruthenium(II), Ru 8.7%
- Packaging
- 2g
- Price
- $259.6
- Updated
- 2021/12/16
- Product number
- ING0016416
- Product name
- DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $266.78
- Updated
- 2021/12/16
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Chemical Properties,Usage,Production
Chemical Properties
ochre lustrous powder
Uses
Catalyst for hydration of nitriles, isomerization of alkynes,Knoevenagel reactions and conjugate additions, and transferhydrogenation
reaction suitability
core: ruthenium
reagent type: catalyst
Synthesis
The Preparative Method of Dihydridotetrakis(triphenylphosphine)ruthenium(II): prepared from Ruthenium(III) Chloride or ruthenium(III) acetylacetonate by reduction with Triethylaluminum in the presence of Triphenylphosphine in THF or benzene under nitrogen at room temperature. The complex can also be prepared by reacting Dichlorotris(triphenylphosphine)ruthenium(II) with Sodium Borohydride and triphenylphosphine.
Purification Methods
Dihydridotetrakis(triphenylphosphine)ruthenium(II) could be recrystallized from benzene, toluene, or THF.
Precautions
Dihydridotetrakis(triphenylphosphine)ruthenium(II) is air and light-sensitive and should be stored under argon in the dark.
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) manufacturers
- Product
- DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) 19529-00-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1KG, 5KG, 50KG
- Release date
- 2020-01-14