Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

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Product Name: Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
CAS No.: 204933-84-6
Chemical Name: Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
Synonyms: NH2ME2][(RUCL((R)-H8-BINAP))2(U-CL)3;(S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3];[NH2Me2][[RuCl((R)-H8-binap)]2(mu-Cl)3];Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II);Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]　
CBNumber: CB31181086
Molecular Formula: 2C44H40P2.C2H7N.Cl.Cl3Ru2.ClH
Formula Weight: 1686.99
MOL File: 204933-84-6.mol

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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Property

Melting point:: >100°C
storage temp.: 2-8°C
form: Powder
color: red-brown
Sensitive: air sensitive

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692190
Product name: (R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]
Packaging: 50mg
Price: $108
Updated: 2023/06/20

Strem Chemicals

Product number: 44-0516
Product name: Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
Packaging: 250mg
Price: $332
Updated: 2021/12/16

Strem Chemicals

Product number: 44-0516
Product name: Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
Packaging: 50mg
Price: $83
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0013152
Product name: DIMETHYLAMMONIUM DICHLORO-TRI-(MU-CHLORO)-BIS-[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL]DIRUTHENATE-(II)
Purity: 95.00%
Packaging: 5MG
Price: $497.76
Updated: 2021/12/16

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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Chemical Properties,Usage,Production

Reaction

Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Suppliers

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204933-84-6, Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)Related Search:

DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Tris(triphenylphosphine)ruthenium(II) chloride (R)-H8-BINAP Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

(S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II)

Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]　

DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]

[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]

(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]

Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II)

[NH2Me2][[RuCl((R)-H8-binap)]2(mu-Cl)3]

Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]

NH2ME2][(RUCL((R)-H8-BINAP))2(U-CL)3

Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

204933-84-6

C90H87Cl5NP4Ru2

C88H80Cl5P4Ru2C2H7NH

CH32NH2C88H80Cl5P4Ru28722

CH32NH2C88H80Cl5P4Ru2

Ru