Tris(triphenylphosphine)ruthenium(II) chloride

Product Name: Tris(triphenylphosphine)ruthenium(II) chloride
CAS No.: 15529-49-4
Chemical Name: Tris(triphenylphosphine)ruthenium(II) chloride
Synonyms: DICHLOROTRIS(TRIPH;Tris(triphenylphosph;RUTHENIUM DICHLOROTRIS(;Tris(triphenylphosphine)ruthen;Triphenylphosphine rutheniuM chloride;TRIS(TRIPHENYLPHOSPHINE) RUTHENIUM II;Ruthenium chloride triphenyl phosphine;TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CH;Tris(triphenylphosphine)dichlororutheniuM;dichlorotris(triphenylphosphine)ruthenium
CBNumber: CB3343551
Molecular Formula: C54H45Cl2P3Ru
Formula Weight: 958.83
MOL File: 15529-49-4.mol

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Tris(triphenylphosphine)ruthenium(II) chloride Property

Melting point:: 159 °C
storage temp.: Inert atmosphere,Room Temperature
solubility: Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
form: Solution
color: Clear
Water Solubility: insoluble
Sensitive: Air & Moisture Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 4935939
InChI: InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChIKey: QUVLSIIMVTXAPD-UHFFFAOYSA-M
SMILES: P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
CAS DataBase Reference: 15529-49-4(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-20/21
Safety Statements: 36/37-22
RIDADR: 2811
WGK Germany: 3
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 223662
Product name: Tris(triphenylphosphine)ruthenium(II) dichloride
Purity: 97%
Packaging: 1g
Price: $70.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 223662
Product name: Tris(triphenylphosphine)ruthenium(II) dichloride
Purity: 97%
Packaging: 5g
Price: $172
Updated: 2024/03/01

TCI Chemical

Product number: D1997
Product name: Tris(triphenylphosphine)ruthenium(II) Dichloride
Purity: >90.0%(T)
Packaging: 1g
Price: $52
Updated: 2024/03/01

TCI Chemical

Product number: D1997
Product name: Tris(triphenylphosphine)ruthenium(II) Dichloride
Purity: >90.0%(T)
Packaging: 5g
Price: $166
Updated: 2024/03/01

Alfa Aesar

Product number: 010504
Product name: Dichlorotris(triphenylphosphine)ruthenium(II), Premion?, 99.95% (metals basis), Ru 10.2% min
Packaging: 1g
Price: $57.65
Updated: 2024/03/01

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Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties,Usage,Production

Chemical Properties

black crystals

Uses

suzuki reaction

Uses

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Preparation

Tris(triphenylphosphine)ruthenium(II) chloride can be prepared by refluxing hydrated Ruthenium(III) Chloride and Triphenylphosphine in ethanol according to the procedure of Wilkinson.

General Description

Tris(triphenylphosphine)ruthenium(II) chloride can be used in the hydrogenation of nitro groups, imines, and ketones, and the selective oxidation of alcohols.

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials

Raw materials

Hydrazinium hydroxide solution Ethanol Tetrahydrofuran Dichloromethane Triphenylphosphine Isopropyl alcohol Ruthenium(III) chloride hydrate Lithium

Preparation Products

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Tris(triphenylphosphine)ruthenium(II) chloride Suppliers

Americas 1 Australia 1 Belgium 2 China 269 Europe 1 France 1 Germany 6 India 9 Japan 2 Singapore 1 Switzerland 3 United Kingdom 3 United States 24 Global 323

Beijing Guofang Dingsheng Technology Co., Ltd.

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Leshan Bangsheng New Materials Co., Ltd

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Email: lsbangsheng@126.com
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Panjin Greenchem Technology Co., Ltd.

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Changsha Shunyan New Materials Technology Co., Ltd

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J & K SCIENTIFIC LTD.

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Meryer (Shanghai) Chemical Technology Co., Ltd.

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Alfa Aesar

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Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
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TCI (Shanghai) Development Co., Ltd.

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ShangHai DEMO Chemical Co.,Ltd

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Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
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ProdList: 8418
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View Lastest Price from Tris(triphenylphosphine)ruthenium(II) chloride manufacturers

henan kanbei chemical co.,ltd

Product: Tris(triphenylphosphine)ruthenium(II) chloride 15529-49-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-20

Henan Aochuang Chemical Co.,Ltd.

Product: Tris(triphenylphosphine)ruthenium(II) chloride 15529-49-4
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-16

Longyan Tianhua Biological Technology Co., Ltd

Product: Tris(triphenylphosphine)ruthenium(II) chloride 15529-49-4
Price: US $50.00/KG
Min. Order: 1KG
Purity: 99
Supply Ability: 100KG
Release date: 2020-11-11

15529-49-4, Tris(triphenylphosphine)ruthenium(II) chlorideRelated Search:

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15529-49-4

C54H45Cl2P3Ru

RuCl2PPh33

C6H53P3RuCl2

RuCl2PC5H634

RuCl2PC6H533

C54H45P3Cl2Ru

3C18H15PCl2Ru

Catalysis and Inorganic Chemistry