ChemicalBook > CAS DataBase List > Tris(triphenylphosphine)ruthenium(II) chloride

Tris(triphenylphosphine)ruthenium(II) chloride

Product Name
Tris(triphenylphosphine)ruthenium(II) chloride
CAS No.
15529-49-4
Chemical Name
Tris(triphenylphosphine)ruthenium(II) chloride
Synonyms
DICHLOROTRIS(TRIPH;Tris(triphenylphosph;RUTHENIUM DICHLOROTRIS(;Tris(triphenylphosphine)ruthen;Dichlororuthenium-triphenylphosphine;Triphenylphosphine rutheniuM chloride;TRIS(TRIPHENYLPHOSPHINE) RUTHENIUM II;Ruthenium chloride triphenyl phosphine;TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CH;Tris(triphenylphosphine)dichlororutheniuM
CBNumber
CB3343551
Molecular Formula
C54H45Cl2P3Ru
Formula Weight
958.83
MOL File
15529-49-4.mol
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Tris(triphenylphosphine)ruthenium(II) chloride Property

Melting point:
159 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene
form 
Solution
color 
Clear
Water Solubility 
insoluble
Sensitive 
Air & Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
4935939
InChI
InChI=1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2
InChIKey
QUVLSIIMVTXAPD-UHFFFAOYSA-M
SMILES
P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1C=CC=CC=1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Ru](Cl)Cl
CAS DataBase Reference
15529-49-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-20/21
Safety Statements 
36/37-22
RIDADR 
2811
WGK Germany 
3
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
223662
Product name
Tris(triphenylphosphine)ruthenium(II) dichloride
Purity
97%
Packaging
1g
Price
$66.7
Updated
2025/07/31
Sigma-Aldrich
Product number
223662
Product name
Tris(triphenylphosphine)ruthenium(II) dichloride
Purity
97%
Packaging
5g
Price
$177
Updated
2025/07/31
TCI Chemical
Product number
D1997
Product name
Tris(triphenylphosphine)ruthenium(II) Dichloride
Purity
>90.0%(T)
Packaging
1g
Price
$52
Updated
2025/07/31
TCI Chemical
Product number
D1997
Product name
Tris(triphenylphosphine)ruthenium(II) Dichloride
Purity
>90.0%(T)
Packaging
5g
Price
$166
Updated
2025/07/31
Strem Chemicals
Product number
44-0500
Product name
Dichlorotris(triphenylphosphine)ruthenium(II), 99%
Packaging
1g
Price
$69
Updated
2024/03/01
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Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties,Usage,Production

Chemical Properties

black crystals

Uses

suzuki reaction

Uses

Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System

Preparation

Tris(triphenylphosphine)ruthenium(II) chloride can be prepared by refluxing hydrated Ruthenium(III) Chloride and Triphenylphosphine in ethanol  according to the procedure of Wilkinson.

General Description

Tris(triphenylphosphine)ruthenium(II) chloride can be used in the hydrogenation of nitro groups, imines, and ketones, and the selective oxidation of alcohols.

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: C-H Activation

Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials

Raw materials

Hydrazinium hydroxide solution Ethanol Tetrahydrofuran Dichloromethane Triphenylphosphine Isopropyl alcohol Ruthenium(III) chloride hydrate Lithium

Preparation Products

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View Lastest Price from Tris(triphenylphosphine)ruthenium(II) chloride manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Tris(triphenylphosphine)ruthenium(II) chloride 15529-49-4
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-19
Henan Aochuang Chemical Co.,Ltd.
Product
Tris(triphenylphosphine)ruthenium(II) chloride 15529-49-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-16
henan kanbei chemical co.,ltd
Product
Tris(triphenylphosphine)ruthenium(II) chloride 15529-49-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-20

15529-49-4, Tris(triphenylphosphine)ruthenium(II) chlorideRelated Search:

Tricine Ruthenium(III) chloride Ruthenium BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) TRIPHENYLPHOSPHINE DIBROMIDE BIS-Tris Triphenylphosphine cis-Bis(triphenylphosphine)platinum(II) chloride Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Triphenylphosphine oxide Bis(triphenylphosphine)palladium(II) chloride CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Tris(hydroxymethyl)aminomethane Potassium chloride Tris(triphenylphosphine)chlororhodium Tetrakis(triphenylphosphine)platinum Allylpalladium(II) Chloride Dimer Bis(tri-tert-butylphosphine)palladium(0)

  • RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE
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  • TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE
  • Tris(triphenylphosphine)ruthenium(II) chloride≥ 99.5% (Assay)
  • Tris(triphenylphosphine)ruthenium(II) chloride (10.5% Ru) for synthesis
  • DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II)
  • DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
  • DICHLOROTRIS(TRIPHENYLPHOSPHINO)RUTHENIUM (II)
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  • Tris(triphenylphosph
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  • Tris(triphenylphosphine)ruthenium(II)chloride,>10.3%(Ru)
  • Dichlorotris(triphenylphosphine)ruthenium (II) ,98%
  • Dichlorotris(triphenylphosphine)ruthenium(II), Premion(R), 99.95% (metals basis), Ru 10.2% min
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  • Tris(triphenylphosphine)dichlororutheniuM
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  • Ruthenium chloride triphenyl phosphine
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  • Dichlorotris(triphenylphosphine)ruthenium(II), Ruthenium(II)-tris(triphenylphosphine) dichloride
  • RUTHENIUM DICHLOROTRIS(
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  • DICHLOROTRIS(TRIPH
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  • Tris(triphenylphosphine)ruthenium(II) chloride ISO 9001：2015 REACH
  • Tris(triphenylphosphine) ruthenium( Ⅱ ) chloride
  • dichlorotris(triphenylphosphane)-ruthenium(II)
  • Tris(triphenylphosphinejruthenium(II) dichloride
  • Tris(triphenylphosphine)ruthenium(Ⅱ) chloride
  • Dichlororuthenium-triphenylphosphine (1:3)
  • Trichlororuthenium(III)triphenylphosphinecomplex
  • Dichlororuthenium-triphenylphosphine
  • 15529-49-4
  • 15529-45-4
  • C54H45Cl2P3Ru
  • RuCl2PPh33
  • C6H53P3RuCl2
  • RuCl2PC5H634
  • RuCl2PC6H533