ChemicalBook > CAS DataBase List > Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
Reaction- Product Name
- Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
- CAS No.
- 204933-84-6
- Chemical Name
- Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
- Synonyms
- NH2ME2][(RUCL((R)-H8-BINAP))2(U-CL)3;(S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3];[NH2Me2][[RuCl((R)-H8-binap)]2(mu-Cl)3];Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II);Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
- CBNumber
- CB31181086
- Molecular Formula
- 2C44H40P2.C2H7N.Cl.Cl3Ru2.ClH
- Formula Weight
- 1686.99
- MOL File
- 204933-84-6.mol
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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Property
- Melting point:
- >100°C
- storage temp.
- 2-8°C
- form
- Powder
- color
- red-brown
- Sensitive
- air sensitive
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Safety
- WGK Germany
- 3
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 692190
- Product name
- (R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]
- Packaging
- 50mg
- Price
- $108
- Updated
- 2023/06/20
Strem Chemicals
- Product number
- 44-0516
- Product name
- Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
- Packaging
- 250mg
- Price
- $332
- Updated
- 2021/12/16
Strem Chemicals
- Product number
- 44-0516
- Product name
- Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
- Packaging
- 50mg
- Price
- $83
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- ING0013152
- Product name
- DIMETHYLAMMONIUM DICHLORO-TRI-(MU-CHLORO)-BIS-[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL]DIRUTHENATE-(II)
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $497.76
- Updated
- 2021/12/16
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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Chemical Properties,Usage,Production
Reaction
- Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
- The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Suppliers
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204933-84-6, Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)Related Search:
DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
Tris(triphenylphosphine)ruthenium(II) chloride
(R)-H8-BINAP
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II)
DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)