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ChemicalBook > CAS DataBase List > Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)

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Product Name
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
CAS No.
204933-84-6
Chemical Name
Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
Synonyms
NH2ME2][(RUCL((R)-H8-BINAP))2(U-CL)3;(S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2];[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3];[NH2Me2][[RuCl((R)-H8-binap)]2(mu-Cl)3];Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II);Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II);Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3] 
CBNumber
CB31181086
Molecular Formula
2C44H40P2.C2H7N.Cl.Cl3Ru2.ClH
Formula Weight
1686.99
MOL File
204933-84-6.mol
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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Property

Melting point:
>100°C
storage temp. 
2-8°C
form 
Powder
color 
red-brown
Sensitive 
air sensitive
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692190
Product name
(R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]
Packaging
50mg
Price
$108
Updated
2023/06/20
Strem Chemicals
Product number
44-0516
Product name
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
Packaging
250mg
Price
$332
Updated
2021/12/16
Strem Chemicals
Product number
44-0516
Product name
Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
Packaging
50mg
Price
$83
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0013152
Product name
DIMETHYLAMMONIUM DICHLORO-TRI-(MU-CHLORO)-BIS-[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-5,5',6,6',7,7',8,8'-OCTAHYDRO-1,1'-BINAPHTHYL]DIRUTHENATE-(II)
Purity
95.00%
Packaging
5MG
Price
$497.76
Updated
2021/12/16
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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Chemical Properties,Usage,Production

Reaction

  1. Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
  2. The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.

Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) Suppliers

TAKASAGO INTERNATIONAL CORPORATION
Tel
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Fax
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Email
finechemicals@takasago.com
Country
Japan
ProdList
203
Advantage
75

204933-84-6, Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)Related Search:


  • Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
  • (S)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]
  • Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II)
  • Dimethylammoniumdichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)[NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3] 
  • DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
  • [NH2Me2][{RuCl((R)-H8-binap)}2(μ-Cl)3]
  • (R)-[(RuCl(H8-BINAP))2(μ-Cl)3][NH2Me2]
  • Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]diruthenate(II)
  • [NH2Me2][[RuCl((R)-H8-binap)]2(mu-Cl)3]
  • Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]
  • NH2ME2][(RUCL((R)-H8-BINAP))2(U-CL)3
  • Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II)
  • 204933-84-6
  • C90H87Cl5NP4Ru2
  • C88H80Cl5P4Ru2C2H7NH
  • CH32NH2C88H80Cl5P4Ru28722
  • CH32NH2C88H80Cl5P4Ru2
  • Ru