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ChemicalBook > CAS DataBase List > Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)

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Product Name
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
CAS No.
199541-17-8
Chemical Name
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
Synonyms
(S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2];[NH2ME2][(RUCL((S)-BINAP))2(Μ-CL)3];(S)-[(RuCl(BINAP))2(mu-Cl)3][NH2Me2];[NH2Me2][{RuCl((S)-binap)}2(mu-Cl)3];-binaphthyl]diruthenate(II),[NH2Me2][{RuCl((S);-Cl)3][NH2Me2];Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(d...;Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II);Dimethylammonium Dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II);Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
CBNumber
CB91181088
Molecular Formula
2C44H32P2.C2H7N.Cl.Cl3Ru2.ClH
Formula Weight
1670.87
MOL File
199541-17-8.mol
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Property

Melting point:
>100°C
storage temp. 
2-8°C
Water Solubility 
Insoluble in water
form 
Powder
color 
orange
Sensitive 
air sensitive
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Safety

Hazard Codes 
F
Risk Statements 
11
RIDADR 
UN 1325 4.1/PG 3
WGK Germany 
3
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H228Flammable solid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
693138
Product name
(S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2]
Packaging
500mg
Price
$154
Updated
2023/06/20
Sigma-Aldrich
Product number
693138
Product name
(S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2]
Packaging
100mg
Price
$32.5
Updated
2023/01/07
TCI Chemical
Product number
N1016
Product name
[NH2Me2][(RuCl((S)-binap))2(μ-Cl)3]
Packaging
200mg
Price
$43
Updated
2024/03/01
TCI Chemical
Product number
N1016
Product name
[NH2Me2][(RuCl((S)-binap))2(μ-Cl)3]
Packaging
1g
Price
$144
Updated
2024/03/01
Strem Chemicals
Product number
44-0511
Product name
Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-binap)}2(μ-Cl)3]
Packaging
250mg
Price
$53
Updated
2024/03/01
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Chemical Properties,Usage,Production

Reaction

  1. (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.
  2. Useful ligand in asymmetric Heck processes.
  3. 3. Ligand employed in palladium-catalyzed asymmetric arylation of ketones.
  4. 4. Ligand employed in rhodium-catalyzed 1,4-additions to enones.
  5. 5. Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.
  6. 6. Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.
  7. 7. Ligand employed in rhodium-catalyzed kinetic resolution of enynes.
  8. 8. Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.
  9. 9. Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.
  10. 10. Ligand employed in palladium-catalyzed synthesis of chiral allenes.
  11. 11. Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.
  12. 12. Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.
  13. 13. Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.
  14. 14. Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.
  15. 15. Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.



Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Suppliers

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199541-17-8, Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)Related Search:

Tris(triphenylphosphine)ruthenium(II) chloride DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) DIHYDRIDOTETRAKIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis[di-(3,5-xylyl)phosphino]-1,1μ-binaphthyl]diruthenate(II) CHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]diruthenate(II) DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)

  • [NH2Me2][{RuCl((S)-binap)}2(mu-Cl)3]
  • (S)-[(RuCl(BINAP))2(mu-Cl)3][NH2Me2]
  • [NH2ME2][(RUCL((S)-BINAP))2(Μ-CL)3]
  • -binaphthyl]diruthenate(II),[NH2Me2][{RuCl((S)
  • -Cl)<SUB>3</SUB>][NH<SUB>2</SUB>Me<SUB>2</SUB>]
  • DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II),[NH2ME2][{RUCL((S)
  • Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
  • (S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2]
  • Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II)
  • Dimethylammonium dichlorotri(chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-binap)}2(Cl)3]
  • DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-binap)}2(μ-Cl)3]
  • Dimethylammonium dichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((S)-binap)}2(mu-Cl)3]
  • Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(d...
  • Dimethylammonium Dichlorotri(μ-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
  • Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
  • 199541-17-8
  • CH32NH2C88H64Cl5P4Ru28722
  • Ru