ChemicalBook > CAS DataBase List > Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
Reaction- Product Name
- Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
- CAS No.
- 488809-34-3
- Chemical Name
- Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
- Synonyms
- (S)-[(RuCl(SEGPHOS;))?(μ-Cl)?][NH?Me?];NH2ME2][(RUCL((S)-SEGPHOS))2(U-CL)3;(S)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2];[NH2ME2][(RUCL((S)-SEGPHOS))2(Μ-CL)3];[NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3];(S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2];(S)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2];[NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3];DiMethylaMMoniuMdichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
- CBNumber
- CB31181091
- Molecular Formula
- C78H68Cl5NO8P4Ru2
- Formula Weight
- 1650.69
- MOL File
- 488809-34-3.mol
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Property
- Melting point:
- >100°C
- storage temp.
- 2-8°C
- Water Solubility
- Insoluble in water
- form
- Powder
- color
- light brown
- Sensitive
- air sensitive
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Safety
- WGK Germany
- 3
- HS Code
- 2843.90.0000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H360May damage fertility or the unborn child
H371May cause damage to organs
H373May cause damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P314Get medical advice/attention if you feel unwell.
P405Store locked up.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 693162
- Product name
- (S)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2]
- Packaging
- 50mg
- Price
- $25.5
- Updated
- 2023/01/07
Sigma-Aldrich
- Product number
- 693162
- Product name
- (S)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2]
- Packaging
- 100mg
- Price
- $44
- Updated
- 2023/01/07
TCI Chemical
- Product number
- N1022
- Product name
- [NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3]
- Packaging
- 200mg
- Price
- $56
- Updated
- 2024/03/01
TCI Chemical
- Product number
- N1022
- Product name
- [NH2Me2][(RuCl((S)-segphos[R]))2(μ-Cl)3]
- Packaging
- 1g
- Price
- $180
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0519
- Product name
- Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos(R))}2(μ-Cl)3]
- Packaging
- 250mg
- Price
- $53
- Updated
- 2024/03/01
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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Chemical Properties,Usage,Production
Reaction
- Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature.
- Catalyst for enantioselective hydrogenation of enamines.
Uses
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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488809-34-3, Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)Related Search:
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Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]
Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]
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