2-METHYLDIPHENYLAMINE

Product Name: 2-METHYLDIPHENYLAMINE
CAS No.: 1205-39-6
Chemical Name: 2-METHYLDIPHENYLAMINE
Synonyms: Phenyl o-tolylamine;2-METHYLDIPHENYLAMINE;2-Methyl-N-phenylephrine;N-Phenyl-2-methylaniline;2-Methyl-N-phenylaniline;2-Methyl-N-phenylbenzenamine;N-(2-Methylphenyl)benzenamine;Benzenamine, 2-methyl-N-phenyl-
CBNumber: CB3143689
Molecular Formula: C13H13N
Formula Weight: 183.25
MOL File: 1205-39-6.mol

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2-METHYLDIPHENYLAMINE Property

Melting point:: 130-140 °C
Boiling point:: 305 °C(Press: 727 Torr)
Density: 1.066±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
pka: 0.65±0.20(Predicted)
Appearance: Yellow to brown Solid
InChI: InChI=1S/C13H13N/c1-11-7-5-6-10-13(11)14-12-8-3-2-4-9-12/h2-10,14H,1H3
InChIKey: JTMODJXOTWYBOZ-UHFFFAOYSA-N
SMILES: C1(NC2=CC=CC=C2)=CC=CC=C1C

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Safety

HS Code: 2921440020

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M3718
Product name: 2-Methyl-N-phenylaniline
Purity: min. 98.0 %
Packaging: 200MG
Price: $117
Updated: 2025/07/31

TCI Chemical

Product number: M3718
Product name: 2-Methyl-N-phenylaniline
Purity: min. 98.0 %
Packaging: 1G
Price: $351
Updated: 2025/07/31

AK Scientific

Product number: 2698CS
Product name: 2-Methyl-N-phenylaniline
Packaging: 5g
Price: $385
Updated: 2021/12/16

Apolloscientific

Product number: OR54435
Product name: 2-Methyl-N-phenylaniline
Packaging: 1g
Price: $163
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3731-1-17
Product name: 2-Methyl-N-phenylaniline
Purity: 98%
Packaging: 1g
Price: $192
Updated: 2021/12/16

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2-METHYLDIPHENYLAMINE Chemical Properties,Usage,Production

Synthesis

16419-60-6

62-53-3

1205-39-6

GENERAL STEPS: In a typical experiment, 2-methylphenylboronic acid (1.22 g, 10 mmol) was added to a flask containing K2CO3 (2.76 g, 20 mmol) and water (2 mL) as solvent. Aniline (0.93 g, 10 mmol) and Cu-Mn catalyst were subsequently added and the reaction mixture was stirred at room temperature. The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, the base in the reaction mixture was neutralized with 2N HCl solution and the catalyst was removed by filtration. The filtrate was washed thoroughly with water and then extracted with ethyl acetate. The organic layer was separated and concentrated and dried under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: ethyl acetate/petroleum ether, ratio 1:5) to give white crystalline 2-methyldiphenylamine (1.60 g, 95% yield). All reactions were carried out in a similar manner.

References

[1] Tetrahedron Letters, 2013, vol. 54, # 39, p. 5351 - 5354
[2] RSC Advances, 2014, vol. 4, # 90, p. 49273 - 49279
[3] Bulletin of the Korean Chemical Society, 2012, vol. 33, # 5, p. 1785 - 1787
[4] Journal of Organic Chemistry, 2006, vol. 71, # 25, p. 9522 - 9524
[5] Tetrahedron Letters, 2014, vol. 55, # 17, p. 2813 - 2817

2-METHYLDIPHENYLAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-METHYLDIPHENYLAMINE Suppliers

China 59 India 1 United Kingdom 1 United States 4 Global 65

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View Lastest Price from 2-METHYLDIPHENYLAMINE manufacturers

Honest Joy Holdings Limited

Product: 2-Methyl-N-phenylaniline 1205-39-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100 tons
Release date: 2022-01-17

1205-39-6, 2-METHYLDIPHENYLAMINERelated Search:

N-(2-AMINO-4-CHLOROPHENYL)ANTHRANILIC ACID Flufenamic acid 10-METHYL-9(10H)-ACRIDONE REACTIVE BLUE 4 REACTIVE BLACK 5 ACID BLUE 41 9(10H)-ACRIDONE ACID GREEN 27 (C.I. 61580) Carbamazepine Solvent Green 3 ACID VIOLET 34 ACID BLUE 40 Iminodibenzyl ACID BLUE 80 ACID BLUE 25 10,11-DIHYDROCARBAMAZEPINE Acid Green 25 N-Phenylanthranilic acid

2-Methyl-N-phenylaniline

2-Methyl-N-phenylbenzenamine

N-(2-Methylphenyl)benzenamine

N-Phenyl-2-methylaniline

Phenyl o-tolylamine

2-METHYLDIPHENYLAMINE

Benzenamine, 2-methyl-N-phenyl-

2-Methyl-N-phenylephrine

1205-39-6