3-Bromo-2-pyridinecarboxaldehyde
- Product Name
- 3-Bromo-2-pyridinecarboxaldehyde
- CAS No.
- 405174-97-2
- Chemical Name
- 3-Bromo-2-pyridinecarboxaldehyde
- Synonyms
- 3-bromopicolinaldehyde;3-Bromo-2-formylpyridine;3-BroMo-2-carboxaldehyde p;3-bromo-2-pyridineformaldehyde;3-Bromo-2-pyridinecarbaldehyde;3-Bromo-2-pyridinecarboxaldehyde;3-Bromopyridine-2-carboxaldehyde;3-BroMo-2-carboxaldehyde pyridine;3-Bromolpyridine-2-carboxaldehyde;2-Pyridinecarboxaldehyde, 3-bromo-
- CBNumber
- CB31501402
- Molecular Formula
- C6H4BrNO
- Formula Weight
- 186.01
- MOL File
- 405174-97-2.mol
3-Bromo-2-pyridinecarboxaldehyde Property
- Boiling point:
- 223.0±20.0 °C(Predicted)
- Density
- 1.683±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 1.12±0.10(Predicted)
- form
- crystalline solid
- color
- Faint orange
- InChI
- InChI=1S/C6H4BrNO/c7-5-2-1-3-8-6(5)4-9/h1-4H
- InChIKey
- DCOPXKMVVJNPSW-UHFFFAOYSA-N
- SMILES
- C1(C=O)=NC=CC=C1Br
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B694870
- Product name
- 3-Bromopyridine-2-carboxaldehyde
- Packaging
- 500mg
- Price
- $155
- Updated
- 2021/12/16
- Product number
- 187784
- Product name
- 3-Bromopyridine-2-carbaldehyde
- Packaging
- 1g
- Price
- $166
- Updated
- 2021/12/16
- Product number
- FB151005
- Product name
- 3-Bromo-2-formylpyridine
- Packaging
- 1g
- Price
- $200
- Updated
- 2021/12/16
- Product number
- FB151005
- Product name
- 3-Bromo-2-formylpyridine
- Packaging
- 250mg
- Price
- $85
- Updated
- 2021/12/16
- Product number
- J94577
- Product name
- 3-Bromo-2-formylpyridine
- Packaging
- 1g
- Price
- $89
- Updated
- 2021/12/16
3-Bromo-2-pyridinecarboxaldehyde Chemical Properties,Usage,Production
Synthesis
38749-79-0
405174-97-2
General procedure for the synthesis of 3-bromopyridine-2-carbaldehyde from 2-methyl-3-bromopyridine: 3-bromo-2-methylpyridine (258 mg, 1.5 mmol) was dissolved in dioxane (5 mL), followed by the addition of selenium dioxide (666 mg, 6.0 mmol) under stirring conditions. The reaction mixture was heated to reflux for 48 hours. Upon completion of the reaction, the mixture was allowed to cool to room temperature and the filtrate was collected by filtration. The residue was purified by column chromatography to give a light yellow solid product (175 mg, 63% yield).
References
[1] Organic and Biomolecular Chemistry, 2012, vol. 10, # 6, p. 1239 - 1245
[2] Patent: CN103570683, 2018, B. Location in patent: Paragraph 0687; 0691-0694
[3] Patent: US2016/176882, 2016, A1. Location in patent: Paragraph 0361; 0362
[4] Patent: WO2017/221100, 2017, A1. Location in patent: Paragraph 00170
[5] Tetrahedron Letters, 2005, vol. 46, # 36, p. 6033 - 6036
3-Bromo-2-pyridinecarboxaldehyde Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Bromo-2-pyridinecarboxaldehyde manufacturers
- Product
- 3-bromopicolinaldehyde 405174-97-2
- Price
- US $1.10-9.90/KG
- Min. Order
- 1KG
- Purity
- 99% min
- Supply Ability
- 100kg
- Release date
- 2025-08-18
- Product
- 3-Bromo-2-pyridinecarboxaldehyde 405174-97-2
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-14
- Product
- 3-Bromo-2-pyridinecarboxaldehyde 405174-97-2
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons Min
- Release date
- 2021-10-27