4-FLUOROPHENYLMAGNESIUM BROMIDE
- Product Name
- 4-FLUOROPHENYLMAGNESIUM BROMIDE
- CAS No.
- 352-13-6
- Chemical Name
- 4-FLUOROPHENYLMAGNESIUM BROMIDE
- Synonyms
- 4-FL;uorophenyL;4-FluorophenylMagnes;4-FLUOROPHENYLMAGNESIUM BROMIDE;4-flourophenylmagnesium bromide;magnesium,fluorobenzene,bromide;p-Fluoro-phenylmagnesium bromide;Magnesium, bromo(4-fluorophenyl)-;4-fluorophenylmagnesiumbromidesol.;4-Fluorophenylmagnesium bromide 1.0
- CBNumber
- CB3166792
- Molecular Formula
- C6H4BrFMg
- Formula Weight
- 199.3
- MOL File
- 352-13-6.mol
4-FLUOROPHENYLMAGNESIUM BROMIDE Property
- Melting point:
- 5 °C
- Boiling point:
- 66°C
- Density
- 1.043 g/mL at 25 °C
- Flash point:
- −40 °F
- storage temp.
- Flammables + water-Freezer (-20°C)e area
- form
- Solution
- color
- Clear yellow to red-brown
- Water Solubility
- It reacts violently with water.
- Sensitive
- Air & Moisture Sensitive
- BRN
- 636802
- InChIKey
- QYBFFRXNNFXREA-UHFFFAOYSA-M
- CAS DataBase Reference
- 352-13-6
- EPA Substance Registry System
- Magnesium, bromo(4-fluorophenyl)- (352-13-6)
Safety
- Hazard Codes
- F+,C,F
- Risk Statements
- 12-14-22-34-66-67-11-40-37-19
- Safety Statements
- 16-26-36/37/39-43-45-7/8-33-8-7
- RIDADR
- UN 2924 3/PG 2
- WGK Germany
- 1
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H335May cause respiratory irritation
H336May cause drowsiness or dizziness
H351Suspected of causing cancer
H371May cause damage to organs
H372Causes damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P370+P378In case of fire: Use … for extinction.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 328820
- Product name
- 4-Fluorophenylmagnesium bromide solution
- Purity
- 1.0?M in THF
- Packaging
- 4X25ML
- Price
- $99.6
- Updated
- 2024/03/01
- Product number
- 245550
- Product name
- 4-Fluorophenylmagnesium bromide solution
- Purity
- 2.0M in diethyl ether
- Packaging
- 100ml
- Price
- $97.2
- Updated
- 2024/03/01
- Product number
- 245550
- Product name
- 4-Fluorophenylmagnesium bromide solution
- Purity
- 2.0M in diethyl ether
- Packaging
- 800ml
- Price
- $207
- Updated
- 2024/03/01
- Product number
- F0673
- Product name
- 4-Fluorophenylmagnesium Bromide (ca. 19% in Tetrahydrofuran, ca. 1.0mol/L)
- Packaging
- 250g
- Price
- $103
- Updated
- 2024/03/01
- Product number
- 328820
- Product name
- 4-Fluorophenylmagnesium bromide solution
- Purity
- 1.0 M in THF
- Packaging
- 100ml
- Price
- $68.2
- Updated
- 2024/03/01
4-FLUOROPHENYLMAGNESIUM BROMIDE Chemical Properties,Usage,Production
Chemical Properties
clear yellow to red-brown solution
Uses
4-Fluorophenylmagnesium bromide is used as a reagent for the introduction of the 4-Fluorophenyl group.
Uses
4-Fluorophenylmagnesium bromide solution (Grignard reagent) can be used as a reagent in the synthesis of:
- Useful key intermediate in the synthesis of paroxetine.
- Arylsulfides via cross-coupling reaction with thiols.
- 4-Arylmethyl-1-phenylpyrazole and 4-aryloxy-1-phenylpyrazole derivatives as androgen receptor antagonists.
- Grignard intermediate for preparing aprepitant.
4-FLUOROPHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-FLUOROPHENYLMAGNESIUM BROMIDE manufacturers
- Product
- 4-Fluorophenylmagnesium bromide 352-13-6
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2018-12-25