ChemicalBook > CAS DataBase List > 4-FLUOROPHENYLMAGNESIUM BROMIDE

4-FLUOROPHENYLMAGNESIUM BROMIDE

Product Name
4-FLUOROPHENYLMAGNESIUM BROMIDE
CAS No.
352-13-6
Chemical Name
4-FLUOROPHENYLMAGNESIUM BROMIDE
Synonyms
4-FL;uorophenyL;4-FluorophenylMagnes;4-FLUOROPHENYLMAGNESIUM BROMIDE;4-flourophenylmagnesium bromide;magnesium,fluorobenzene,bromide;p-Fluoro-phenylmagnesium bromide;Magnesium, bromo(4-fluorophenyl)-;4-fluorophenylmagnesiumbromidesol.;4-Fluorophenylmagnesium bromide 1.0
CBNumber
CB3166792
Molecular Formula
C6H4BrFMg
Formula Weight
199.3
MOL File
352-13-6.mol
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4-FLUOROPHENYLMAGNESIUM BROMIDE Property

Melting point:
5 °C
Boiling point:
66°C
Density 
1.043 g/mL at 25 °C
Flash point:
−40 °F
storage temp. 
Flammables + water-Freezer (-20°C)e area
form 
Solution
color 
Clear yellow to red-brown
Water Solubility 
It reacts violently with water.
Sensitive 
Air & Moisture Sensitive
BRN 
636802
InChIKey
QYBFFRXNNFXREA-UHFFFAOYSA-M
CAS DataBase Reference
352-13-6
EPA Substance Registry System
Magnesium, bromo(4-fluorophenyl)- (352-13-6)
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Safety

Hazard Codes 
F+,C,F
Risk Statements 
12-14-22-34-66-67-11-40-37-19
Safety Statements 
16-26-36/37/39-43-45-7/8-33-8-7
RIDADR 
UN 2924 3/PG 2
WGK Germany 
1
F 
10-21
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P370+P378In case of fire: Use … for extinction.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
328820
Product name
4-Fluorophenylmagnesium bromide solution
Purity
1.0?M in THF
Packaging
4X25ML
Price
$99.6
Updated
2024/03/01
Sigma-Aldrich
Product number
245550
Product name
4-Fluorophenylmagnesium bromide solution
Purity
2.0M in diethyl ether
Packaging
100ml
Price
$97.2
Updated
2024/03/01
Sigma-Aldrich
Product number
245550
Product name
4-Fluorophenylmagnesium bromide solution
Purity
2.0M in diethyl ether
Packaging
800ml
Price
$207
Updated
2024/03/01
TCI Chemical
Product number
F0673
Product name
4-Fluorophenylmagnesium Bromide (ca. 19% in Tetrahydrofuran, ca. 1.0mol/L)
Packaging
250g
Price
$103
Updated
2024/03/01
Sigma-Aldrich
Product number
328820
Product name
4-Fluorophenylmagnesium bromide solution
Purity
1.0 M in THF
Packaging
100ml
Price
$68.2
Updated
2024/03/01
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4-FLUOROPHENYLMAGNESIUM BROMIDE Chemical Properties,Usage,Production

Chemical Properties

clear yellow to red-brown solution

Uses

4-Fluorophenylmagnesium bromide is used as a reagent for the introduction of the 4-Fluorophenyl group.

Uses

4-Fluorophenylmagnesium bromide solution (Grignard reagent) can be used as a reagent in the synthesis of:

  • Useful key intermediate in the synthesis of paroxetine.
  • Arylsulfides via cross-coupling reaction with thiols.
  • 4-Arylmethyl-1-phenylpyrazole and 4-aryloxy-1-phenylpyrazole derivatives as androgen receptor antagonists.
  • Grignard intermediate for preparing aprepitant.

4-FLUOROPHENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-FLUOROPHENYLMAGNESIUM BROMIDE Suppliers

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View Lastest Price from 4-FLUOROPHENYLMAGNESIUM BROMIDE manufacturers

Career Henan Chemical Co
Product
4-Fluorophenylmagnesium bromide 352-13-6
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-25

352-13-6, 4-FLUOROPHENYLMAGNESIUM BROMIDERelated Search:

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  • 4-FL
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  • 352-13-6
  • C6H4BrFMg
  • FC6H4MgBr
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