ChemicalBook > CAS DataBase List > Z-TYR(BZL)-OH

Z-TYR(BZL)-OH

Product Name: Z-TYR(BZL)-OH
CAS No.: 16677-29-5
Chemical Name: Z-TYR(BZL)-OH
Synonyms: Z-TYR(BZL)-OH;CBZ-TYR(BZL)-OH;Z-L-Tyr(Bzl)-OH;Cbz-L-Tyr(Bzl)-OH;CBZ-O-BENZYL-L-TYR;Z-TYROSINE(BZL)-OH;Z-O-BENZYL-L-TYROSINE;CBZ-O-BENZYL-L-TYROSINE;Z-O-Benzyl-L-tyrosine, 98%+;N-ALPHA-CBZ-O-BENZYL-L-TYROSINE
CBNumber: CB3175990
Molecular Formula: C24H23NO5
Formula Weight: 405.44
MOL File: 16677-29-5.mol

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Z-TYR(BZL)-OH Property

Boiling point:: 624.4±55.0 °C(Predicted)
Density: 1.249±0.06 g/cm3(Predicted)
storage temp.: Store at 0°C
solubility: Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form: Solid
pka: 2.98±0.10(Predicted)

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

AK Scientific

Product number: E207
Product name: Z-Tyr(Bzl)-OH
Packaging: 1g
Price: $13
Updated: 2021/12/16

Chem-Impex

Product number: 02269
Product name: Z-O-benzyl-L-tyrosine,98%(HPLC)
Purity: 98%(HPLC)
Packaging: 1G
Price: $17.36
Updated: 2021/12/16

Chem-Impex

Product number: 02269
Product name: Z-O-benzyl-L-tyrosine,≥98%(HPLC)
Purity: ≥98%(HPLC)
Packaging: 5G
Price: $48.22
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB47320
Product name: Z-O-benzyl-L-tyrosine
Packaging: 5G
Price: $79.1
Updated: 2021/12/16

Matrix Scientific

Product number: 093615
Product name: Z-Tyr(Bzl)-OH
Purity: 95+%
Packaging: 1g
Price: $95
Updated: 2021/12/16

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Z-TYR(BZL)-OH Chemical Properties,Usage,Production

Synthesis

16652-64-5

501-53-1

86827-18-1

General procedure for the synthesis of the compound (CAS: 86827-18-1) from O-benzyl-L-tyrosine and benzyl chloroformate: (S)-O-benzyl-tyrosine (8.14 g, 30 mmol) was dissolved in THF (60 mL) and cooled to 0 °C. Subsequently, an aqueous solution of NaOH (3 g, 75 mmol) was added (60 mL). A solution of benzyl chloroformate (4.65 mL, 5.63 g, 33 mmol) in THF (30 mL) was slowly added dropwise at 0 °C. The reaction mixture was stirred at 0 °C for 2 h, then gradually warmed to room temperature and continued stirring overnight. After the reaction was completed, water (50 mL) was added and the pH was adjusted to 1-2 with 10% HCl, then the aqueous phase was extracted with EtOAc (3 × 100 mL). The organic phases were combined, washed with brine (2 × 100 mL) and dried over Na2SO4. The solvent was removed by concentration under reduced pressure to give pure (S)-N-Benzyloxycarbonyl-O-benzyl-tyrosine (11.57 g, 95% yield) as a pale yellow solid, melting point: 128-130°C. The product could be used in the next reaction without further purification.1H NMR (400 MHz, CDCl3) δ: 2.85 (dd, J = 13.2, 8.4 Hz, 1H, CH2), 3.10 (dd, J = 13.2, 12.0 Hz, 1H, CH2), 4.43 (dd, J = 12.0, 8.4 Hz, 1H, CH). 4.80 (d, J = 12.4 Hz, 1H, CH2O), 4.82 (s, 2H, CH2O), 5.00 (d, J = 12.4 Hz, 1H, CH2O), 5.60 (d, J = 4.8 Hz, 1H, NH), 6.65-7.35 (m, 14H, ArH).13C NMR (100 MHz, CDCl3) δ : 36.9, 56.2, 66.8, 69.8, 114.8, 127.5, 127.83, 127.89, 127.93, 128.4, 128.5, 128.9, 130.3, 136.2, 137.0, 156.6, 157.7, 177.5. HRMS (ESI) C24H24NO5 [M + H ]+ m/z calculated value: 406.1649; measured value: 406.1641.

References

[1] Tetrahedron, 2014, vol. 70, # 34, p. 5197 - 5206
[2] Chemische Berichte, 1958, vol. 91, p. 542,546
[3] Monatshefte fuer Chemie, 1974, vol. 105, p. 1110 - 1135
[4] Tetrahedron, 2014, vol. 70, # 34, p. 5197 - 5206

Z-TYR(BZL)-OH Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Z-TYR(BZL)-OH manufacturers

Career Henan Chemical Co

Product: Z-TYR(BZL)-OH 16677-29-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20kg
Release date: 2018-08-15

Career Henan Chemical Co

Product: Z-TYR(BZL)-OH 16677-29-5
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2018-08-15

16677-29-5, Z-TYR(BZL)-OHRelated Search:

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N-CBZ-O-BENZYL-L-TYROSINE CRYSTALLINE

N-alpha-Benzyloxycarbonyl-O-benzyl-L-tyrosine

Z-L-Tyr(Bzl)-OH

(S)-3-(4-(benzyloxy)phenyl)-2-(benzyloxycarbonylamino)propanoic acid

Cbz-L-Tyr(Bzl)-OH

Z-O-benzyl-L-tyrosine≥ 98% (HPLC)

(S)-2-(((Benzyloxy)carbonyl)aMino)-3-(4-(benzyloxy)phenyl)propanoic acid

2-(phenylmethoxycarbonylamino)-3-(4-phenylmethoxyphenyl)propanoic acid

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Z-O-Benzyl-L-tyrosine, 98%+

Z-O-Benzyl-L-Tyrosine extrapure, 98%

16677-29-5

Amino Acid Derivatives

Peptide Synthesis

Specialty Synthesis

Tyrosine