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1-NITROHEXANE

Product Name
1-NITROHEXANE
CAS No.
646-14-0
Chemical Name
1-NITROHEXANE
Synonyms
Nitrohexane;1-NITROHEXANE;Hexane, 1-nitro-;1-Nitrohexane 98%;1-NITROHEXANE, STANDARD FOR GC
CBNumber
CB3181450
Molecular Formula
C6H13NO2
Formula Weight
131.17
MOL File
646-14-0.mol
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1-NITROHEXANE Property

Melting point:
23.5°C (estimate)
Boiling point:
91-92 °C/24 mmHg (lit.)
Density 
0.94 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.423(lit.)
Flash point:
72 °C
storage temp. 
-20°C Freezer
solubility 
Dichloromethane, Chloroform, Ethyl Acetate, Methanol
form 
Clear Colourless Liquid
pka
8.65±0.29(Predicted)
BRN 
1749466
Stability:
Stable. Incompatible with strong bases, strong oxidizing agents.
EPA Substance Registry System
1-Nitrohexane (646-14-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
2810
WGK Germany 
3
8
HazardClass 
6.1(b)
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
259497
Product name
1-Nitrohexane
Purity
98%
Packaging
1g
Price
$72.9
Updated
2024/03/01
Sigma-Aldrich
Product number
259497
Product name
1-Nitrohexane
Purity
98%
Packaging
5g
Price
$170
Updated
2024/03/01
TRC
Product number
N496125
Product name
1-Nitrohexane
Packaging
500mg
Price
$280
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
12560
Product name
1-Nitrohexane
Packaging
5G
Price
$845
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0006915
Product name
1-NITROHEXANE
Purity
95.00%
Packaging
2.5G
Price
$869
Updated
2021/12/16
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1-NITROHEXANE Chemical Properties,Usage,Production

Chemical Properties

Colourless Liquid

Uses

1-Nitrohexane is used in method for preparing amine by reducing nitro compound with pinacolborane under catalysis of cyclic (alkyl) (amino) carbene chromium complex.

Definition

ChEBI: 1-nitrohexane is a primary nitroalkane that is hexane substituted by a nitro group at position 1. It has a role as a human urinary metabolite. It derives from a hydride of a hexane.

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 659, 1979 DOI: 10.1021/jo01318a050
Synthesis, p. 835, 1978 DOI: 10.1055/s-1978-24907

General Description

Clear colorless liquid. Insoluble in water.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Nitroalkanes, such as 1-NITROHEXANE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water. Flammable/combustible material. May be ignited by heat, sparks or flames.

Fire Hazard

Flash point data for 1-NITROHEXANE are not available. 1-NITROHEXANE is combustible.

1-NITROHEXANE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-NITROHEXANE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
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jkinfo@jkchemical.com
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China
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96815
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3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
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Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
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Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
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Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
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Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
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China
ProdList
51456
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Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
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China
ProdList
52693
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Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 +86-13028896684;
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sales@rrkchem.com
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China
ProdList
57412
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CONIER CHEM AND PHARMA LIMITED
Tel
+8618523575427
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sales@conier.com
Country
China
ProdList
49374
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Ningbo jinuo chemical co., LTD
Tel
0574-87314919 057487319282
Email
info@nbinno.com
Country
China
ProdList
7027
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58

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