COBALT(III) FLUORIDE

Product Name: COBALT(III) FLUORIDE
CAS No.: 10026-18-3
Chemical Name: COBALT(III) FLUORIDE
Synonyms: CoF3;COBALT FLUORIDE;Cobalt(Ⅲ)fluoride;COBALTIC FLUORIDE;COBALT TRIFLUORIDE;Trifluoride cobalt;Kobalt(III)-fluorid;COBALT(III) FLUORIDE;Cobaltic trifluoride;cobaltfluoride(cof3)
CBNumber: CB3181935
Molecular Formula: CoF3
Formula Weight: 115.93
MOL File: 10026-18-3.mol

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COBALT(III) FLUORIDE Property

Melting point:

927°C

Density

3.88 g/mL at 25 °C(lit.)

solubility

reacts with H2O; soluble in ethanol,ethyl ether, benzene

form

Powder

color

Light brown

Specific Gravity

3.88

Water Solubility

Insoluble in water.

Sensitive

Hygroscopic

Crystal Structure

VF3 type

crystal system

Three sides

Merck

14,2430

Space group

R3c

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.504	0.504	1.322	90	90	120	0.2903

Exposure limits

ACGIH: TWA 0.02 mg/m3; TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3

Stability:

hygroscopic

CAS DataBase Reference

10026-18-3(CAS DataBase Reference)

EPA Substance Registry System

Cobalt fluoride (CoF3) (10026-18-3)

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Safety

Hazard Codes: C,T,O
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: UN 3260 8/PG 2
WGK Germany: 3
F: 21
Hazard Note: Toxic/Corrosive/Oxidiser
TSCA: Yes
HazardClass: 5.1
PackingGroup: III
HS Code: 28261990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 236136
Product name: Cobalt(III) fluoride
Packaging: 5g
Price: $39.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 236136
Product name: Cobalt(III) fluoride
Packaging: 25g
Price: $110
Updated: 2024/03/01

Alfa Aesar

Product number: 011490
Product name: Cobalt(III) fluoride, 99%
Packaging: 25g
Price: $90.4
Updated: 2024/03/01

Alfa Aesar

Product number: 011490
Product name: Cobalt(III) fluoride, 99%
Packaging: 100g
Price: $256
Updated: 2023/06/20

Strem Chemicals

Product number: 93-2740
Product name: Cobalt(III) fluoride, 99%
Packaging: 10g
Price: $69
Updated: 2024/03/01

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COBALT(III) FLUORIDE Chemical Properties,Usage,Production

Chemical Properties

brown powder

Chemical Properties

The heat of formation is —187 kcal mole-1 and the magnetic moment is 1-60 B.M. at 90°K rising to 2.46 B.M. at 293°K; it is thus a high spin compound but not magnetically dilute.
Anhydrous cobalt(III) fluoride turns dark in the presence of traces of water and reacts violently with the liquid-evolving oxygen. When heated in an inert atmosphere above 350°, cobalt(II) fluoride is formed. It reacts vigorously with many elements, e.g. Al, P, As, S, I, being reduced to cobalt(II) fluoride. It is insoluble in alcohol, ether and benzene and is a useful fluorinating agent in organic chemistry.

Physical properties

Light brown hexagonal crystal; density 3.88 g/cm³; moisture sensitive; stable in dry air; melts at 927°C; reacts with water.

Uses

Important fluorinating agent, particularly for complete fluorination of hydrocarbons by the Fowler process.

Uses

Cobalt(III) fluoride is a powerful fluorinating agent.

Preparation

Cobalt(III) fluoride may be prepared by reaction of elemental fluorine with cobalt(II) fluoride, cobalt(II) chloride or cobalt(III) oxide at 300 to 400°C.
2CoF₂ + F₂ → 2CoF₃
2CoCl₂ + 3F₂ → 2CoF₃ + 2Cl₂
It should be stored in a sealed glass ampule, free from moisture.
Electrolytic oxidation of cobalt(II) fluoride in 40% hydrofluoric acid yields hydrated cobalt(III) fluoride, CoF₃·3.5H₂O (3.5 is the stoichiometric amount of water per CoF3 molecule in the crystal lattice).

Hazard

Strong irritant to tissue.

Structure and conformation

It forms hexagonal crystals of density 3.89, isomorphous with iron(III) and aluminium(III) fluorides, the cobalt atoms being octahedraily surrounded by fluorine atoms.

COBALT(III) FLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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COBALT(III) FLUORIDE Suppliers

Belgium 1 China 29 France 2 Germany 6 India 5 Switzerland 1 United Kingdom 11 United States 26 Global 81

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View Lastest Price from COBALT(III) FLUORIDE manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: COBALT(III) FLUORIDE 10026-18-3
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2023-02-25

Career Henan Chemical Co

Product: COBALT(III) FLUORIDE 10026-18-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 10 tons
Release date: 2020-01-10

10026-18-3, COBALT(III) FLUORIDERelated Search:

Cobalt(II) hydroxide Nickel chloride Cobalt oxide Cobalt chloride Triiron tetraoxide LITHIUM COBALT(III) OXIDE COBALT(II) SULFATE HYDRATE COBALT(II) SULFATE HYDRATE Cobalt sulfate heptahydrate Manganese sulfide Tricobalt tetraoxide COBALT(III) OXIDE BLACK Cobaltous nitrate hexahydrate COBALT(II) BROMIDE trisodium nitride Cobalt COBALT(III) FLUORIDE Cobalt(II) fluoride

Cobalt(Ⅲ)fluoride

COBALT FLUORIDE

COBALT FLUORIDE BROWN

COBALTIC FLUORIDE

COBALT(III) FLUORIDE

COBALT TRIFLUORIDE

Cobalt fluoride (CoF3)

cobaltfluoride(cof3)

Cobaltic trifluoride

CoF3

Cobalt(III)fluoride,99%

Cobalt(III) fluoride 99%

Cobalt(III) trifluoride

Cobaltfluoridetanpowder

Cobalt(III)fluorideanhydrous

Kobalt(III)-fluorid

Trifluoride cobalt

Cobalt Trifluoride,99%

5-Bromo-288-fluorobenzylamine&hydrochloride

10026-18-3

Co3F

Fluorination

C-X Bond Formation (Halogen)

Synthetic Reagents

Inorganic Fluorides

metal halide