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N-Methyl methanesulfonamide

Product Name
N-Methyl methanesulfonamide
CAS No.
1184-85-6
Chemical Name
N-Methyl methanesulfonamide
Synonyms
N-methylmethylsulfonamide;AKOS 91020;N-Methylmethane;N-Methyl methanesulf;N - Methyl sulfonaMide;N-Methyl methanesulfomide;n-methyl-methanesulfonamid;Methy sulfonyl methylamine;METHYL SULFONYL METHYLAMINE;N-METHYL METHANESULFONAMIDE
CBNumber
CB3188242
Molecular Formula
C2H7NO2S
Formula Weight
109.15
MOL File
1184-85-6.mol
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N-Methyl methanesulfonamide Property

Boiling point:
118°C/0.3mmHg(lit.)
Density 
1.194±0.06 g/cm3(Predicted)
refractive index 
1.4500 to 1.4540
Flash point:
53 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
pka
11.57±0.40(Predicted)
Specific Gravity
1.28
color 
Colorless to Almost colorless
Sensitive 
Air Sensitive
InChI
InChI=1S/C2H7NO2S/c1-3-6(2,4)5/h3H,1-2H3
InChIKey
UHNHTTIUNATJKL-UHFFFAOYSA-N
SMILES
CS(NC)(=O)=O
CAS DataBase Reference
1184-85-6(CAS DataBase Reference)
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Safety

RIDADR 
UN 1993 9/PG III
RTECS 
PB0476750
HazardClass 
9
PackingGroup 
III
HS Code 
2935909099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2170
Product name
N-Methylmethanesulfonamide
Purity
>98.0%(GC)
Packaging
25g
Price
$58
Updated
2025/07/31
TRC
Product number
M339058
Product name
N-MethylMethanesulfonamide
Packaging
10g
Price
$75
Updated
2021/12/16
TRC
Product number
M339058
Product name
N-MethylMethanesulfonamide
Packaging
1g
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
8169-1-11
Product name
N-Methylmethanesulfonamide
Packaging
25g
Price
$80
Updated
2021/12/16
Apolloscientific
Product number
OR52265
Product name
N-Methylmethanesulphonamide
Purity
97%
Packaging
100g
Price
$135
Updated
2021/12/16
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N-Methyl methanesulfonamide Chemical Properties,Usage,Production

Uses

N-Methyl methanesulfonamide is used as a pharmaceutical or pesticide intermediate.

Synthesis

124-63-0

74-89-5

1184-85-6

Methanesulfonyl chloride (100 g, 1.0 eq.) was added slowly and dropwise to a stirred ethanol solution of monomethylamine (8 M in EtOH, 525 mL, 4.8 eq.) at 0 °C. After the dropwise addition, the reaction mixture was warmed to room temperature and stirred continuously for 16 hours. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was diluted with dichloromethane (200 mL) and the isolated solid was filtered. The filtrate was concentrated to afford the target product, N-methylsulfonylmethylamine, as an orange oil (82 g, yield not indicated). The product was characterized by 1H NMR (CDCl3, 400 MHz): δ 4.819 (broad single peak, 1H), 2.929 (single peak, 3H), 2.789 (single peak, 3H).

Toxics Screening Level

The initial threshold screening level (ITSL) for methyl methane sulfonamide is 0.1 μg/m3(annual averaging time).

References

[1] Patent: WO2015/38417, 2015, A1. Location in patent: Page/Page column 82
[2] Journal of Organic Chemistry, 2003, vol. 68, # 13, p. 5300 - 5309
[3] Journal of the Chemical Society, 1955, p. 669,674
[4] Journal of the Chemical Society, 1965, p. 3228 - 3234
[5] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986, p. 1211 - 1216

N-Methyl methanesulfonamide Preparation Products And Raw materials

Raw materials

Preparation Products

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N-Methyl methanesulfonamide Suppliers

Molekula Limited
Tel
--
Fax
--
Email
o@molekula.com
Country
United Kingdom
ProdList
6127
Advantage
58
Melrob Ltd (part of Nordmann)
Tel
--
Fax
--
Email
nquiries@melrob.com
Country
United Kingdom
ProdList
3065
Advantage
58
Manchester Organics
Tel
--
Fax
--
Email
info@manchesterorganics.com
Country
United Kingdom
ProdList
6834
Advantage
67
Biosynth Carbosynth
Tel
--
Fax
--
Email
ales@carbosynth.com
Country
United Kingdom
ProdList
2598
Advantage
58
Apollo Scientific Ltd.
Tel
--
Fax
--
Email
sales@apolloscientific.co.uk
Country
United Kingdom
ProdList
6084
Advantage
88
Leancare Ltd.
Tel
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Fax
--
Email
enquiry@leancare.co.uk
Country
United Kingdom
ProdList
6446
Advantage
42
MOLEKULA Ltd.
Tel
--
Fax
--
Email
kevinbanks@molekula.com
Country
United Kingdom
ProdList
6140
Advantage
66
CARBONE SCIENTIFIC CO.,LTD
Tel
--
Fax
--
Email
sales@carbonesci.com
Country
United Kingdom
ProdList
6666
Advantage
30
Eurolabs Limited
Tel
--
Fax
--
Country
United Kingdom
ProdList
6309
Advantage
46
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View Lastest Price from N-Methyl methanesulfonamide manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
N-Methyl methanesulfonamide 1184-85-6
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 mt
Release date
2024-11-21
Hebei Chuanghai Biotechnology Co., Ltd
Product
N-Methyl methanesulfonamide 1184-85-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-30
Henan Aochuang Chemical Co.,Ltd.
Product
N-Methyl methanesulfonamide 1184-85-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-10-12

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