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4-BROMOCATECHOL

Product Name
4-BROMOCATECHOL
CAS No.
17345-77-6
Chemical Name
4-BROMOCATECHOL
Synonyms
4-broMobenzene-1,2-diol;RMA-436;-Bromocatechol;4-BROMOCATECHOL;4-Bromocatechol>4-bromopyrocatechol;4-Bromo-1,2-benzenediol;1,2-Benzenediol, 4-broMo-;4-BROMO-1,2-DIHYDROXYBENZENE
CBNumber
CB3200564
Molecular Formula
C6H5BrO2
Formula Weight
189.01
MOL File
17345-77-6.mol
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4-BROMOCATECHOL Property

Melting point:
87 °C
Boiling point:
280.5±20.0 °C(Predicted)
Density 
1.844±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
DMSO
form 
Solid
pka
8.84±0.10(Predicted)
color 
Brown
Stability:
Light Sensitive
InChI
InChI=1S/C6H5BrO2/c7-4-1-2-5(8)6(9)3-4/h1-3,8-9H
InChIKey
AQVKHRQMAUJBBP-UHFFFAOYSA-N
SMILES
C1(O)=CC=C(Br)C=C1O
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-24/25
HS Code 
29081990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B2173
Product name
4-Bromocatechol
Purity
>98.0%(GC)
Packaging
1g
Price
$46
Updated
2025/07/31
TCI Chemical
Product number
B2173
Product name
4-Bromocatechol
Purity
>98.0%(GC)
Packaging
5g
Price
$156
Updated
2025/07/31
TRC
Product number
B682105
Product name
4-Bromocatechol
Packaging
2.5g
Price
$130
Updated
2021/12/16
TRC
Product number
B682105
Product name
4-Bromocatechol
Packaging
25g
Price
$870
Updated
2021/12/16
Apolloscientific
Product number
OR400662
Product name
4-Bromocatechol
Packaging
1g
Price
$57
Updated
2021/12/16
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4-BROMOCATECHOL Chemical Properties,Usage,Production

Chemical Properties

Grey powder

Uses

A type of human dopamine sulfotransferase, belonging to the catechol family of molecules.

Definition

ChEBI: 4-Bromocatechol is a member of catechols.

Synthesis

120-80-9

17345-77-6

GENERAL METHODS: Catechol (1 mmol) was dissolved in acetonitrile (5 mL) and a magnetic stirrer was added to form a magnetically stirred solution. Subsequently, OXBTEATB (0.233 g, 0.5 mmol) was added to the solution and the reaction was stirred at room temperature for the reaction time referred to in Table 1.The reaction progress was monitored by thin layer chromatography (TLC) with an eluent ratio of hexane/ethyl acetate (5:1). Upon completion of the reaction, OXBTEATB was removed by filtration, and the filtrate was transferred to a partition funnel and extracted sequentially with water (15 mL) and dichloromethane (20 mL). The organic layer was collected and dried with anhydrous Na2SO4 and subsequently concentrated in a rotary evaporator to remove solvent. The crude product was purified by silica gel column chromatography, the eluent being a solvent mixture of hexane and ethyl acetate. To regenerate the reagents, the resulting white solid was treated with liquid bromine. The structures of all products were confirmed by determination of melting points or 1H NMR spectra and comparison with data reported in the literature [29a-29e].

References

[1] Synthetic Communications, 2007, vol. 37, # 2, p. 323 - 328
[2] Organic letters, 2002, vol. 4, # 22, p. 3975 - 3978
[3] Molecules, 2014, vol. 19, # 3, p. 3401 - 3416
[4] Patent: US4791139, 1988, A
[5] Letters in Organic Chemistry, 2018, vol. 15, # 8, p. 682 - 687

4-BROMOCATECHOL Preparation Products And Raw materials

Raw materials

Preparation Products

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4-BROMOCATECHOL Suppliers

Tianjin Ji Ping Jia Chemical Co., Ltd.
Tel
18622448868
Fax
022-58620773
Email
jpjchem@163.com
Country
China
ProdList
490
Advantage
62
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
15883
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Suzhou Sibian Chemical Technology Co.,Ltd.
Tel
0512-65617459 18915409046
Fax
0512-65617459
Email
sales@sibian-chem.com
Country
China
ProdList
1922
Advantage
55
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View Lastest Price from 4-BROMOCATECHOL manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
4-BROMOCATECHOL 17345-77-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-18
Career Henan Chemical Co
Product
4-BROMOCATECHOL 17345-77-6
Price
US $2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customise
Release date
2018-08-09