ChemicalBook > CAS DataBase List > (1S)-(+)-3-Carene

(1S)-(+)-3-Carene

Product Name
(1S)-(+)-3-Carene
CAS No.
498-15-7
Chemical Name
(1S)-(+)-3-Carene
Synonyms
(+)-3-CARENE;(+)-3-Carene;(1S,6R)-3-Carene;()-3-Carene;(+)-car-3-ene;(+)-3-Δ-CARENE;(+)-D-3-Carene;(+)-Δ-3-Carene;Einecs 207-856-6;(1S)-(+)-3-CARENE
CBNumber
CB3208717
Molecular Formula
C10H16
Formula Weight
136.23
MOL File
498-15-7.mol
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(1S)-(+)-3-Carene Property

Melting point:
25°C (estimate)
Boiling point:
170-172 °C(lit.)
alpha 
17 º (NEAT)
Density 
0.865 g/mL at 25 °C(lit.)
vapor pressure 
2.73hPa at 20℃
refractive index 
n20/D 1.473
Flash point:
131 °F
storage temp. 
-20°C
solubility 
soluble in Acetone,Ethanol,Benzene
form 
liquid (clear)
color 
clear very slightly yellow
Odor
sweet
optical activity
[α]20/D +17°, neat
Water Solubility 
3.7mg/L at 20℃
Merck 
14,1836
BRN 
1902767
LogP
4.38 at 37℃
CAS DataBase Reference
498-15-7(CAS DataBase Reference)
NIST Chemistry Reference
Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S)-(498-15-7)
EPA Substance Registry System
Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S,6R)- (498-15-7)
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Safety

Hazard Codes 
Xi,N
Risk Statements 
10-50/53-43
Safety Statements 
36/37-60-61
RIDADR 
UN 2319 3/PG 3
WGK Germany 
2
RTECS 
FH8400000
F 
10-23
HS Code 
2902.19.0050
HazardClass 
3
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
21986
Product name
(+)-3-Carene
Purity
analytical standard
Packaging
5ml
Price
$147
Updated
2024/03/01
Sigma-Aldrich
Product number
00410590
Product name
(+)-3-δ-Carene
Purity
primary reference standard
Packaging
100mg
Price
$314
Updated
2023/06/20
Sigma-Aldrich
Product number
CRM40416
Product name
(+)-3-Carene solution
Purity
certified reference material, 2000?μg/mL in methanol, ampule of 1?mL
Packaging
1mL
Price
$159
Updated
2022/05/15
TCI Chemical
Product number
C0047
Product name
(+)-3-Carene
Purity
>90.0%(GC)
Packaging
25mL
Price
$24
Updated
2024/03/01
TCI Chemical
Product number
C0047
Product name
(+)-3-Carene
Purity
>90.0%(GC)
Packaging
500mL
Price
$76
Updated
2024/03/01
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(1S)-(+)-3-Carene Chemical Properties,Usage,Production

Uses

Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene. Has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.

Production Methods

3-Carene is obtained exclusively by fractional distillation of certain turpentines.

Definition

ChEBI: A car-3-ene (3,7,7-trimethylbicyclo[4.1.0]hept-3-ene) that has S configuration at position 1 and R configuration at position 6.

General Description

(1S)-(+)-3-Carene is a monoterpene.

Chemical Reactivity

3-Carene readily undergoes autoxidation and resinification in air. Addition of pyrogallol or resorcinol as stabilizers is recommended. On treatment with peracetic acid in glacial acetic acid and subsequent saponification, 3-carene is oxidized to 3,4- caranediol. Pyrolysis at 300–580 ℃ in the presence of Fe(III) oxide on carriers gives p-cymene as the main product.

(1S)-(+)-3-Carene Preparation Products And Raw materials

Raw materials

Benzotrifluoride Toluene Chlorine Ferric chloride Iron chloride hexahydrate

Preparation Products

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View Lastest Price from (1S)-(+)-3-Carene manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
(1S)-(+)-3-Carene 498-15-7
Price
US $30.00-20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
3000KG
Release date
2024-07-24
Career Henan Chemical Co
Product
(1S)-(+)-3-Carene 498-15-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kgs
Release date
2020-02-13

498-15-7, (1S)-(+)-3-CareneRelated Search:

Norandrostenedione Dicyclopentadiene 6-Methyl-5-hepten-2-one Allyl methacrylate Methyl cyclopentenolone METHYLCYCLOPENTADIENE DIMER 3-CARENE 4-ACETYL CARENE (+)-2-CARENE WITH GC,CARENE, (1S-CIS)-2-,(1S-CIS)-2-CARENE,(+)-2-CARENE,2-CARENE 95+% 4-delta-carene,delta-2-Carene,delta-4-carene,2-CARENE [1S,3S,6R,(-)]-4-Carene,(1S,3S)-TRANS-4-CARENE,4-Carene, (1S, 2S, 6R)-(-)- 3-Carene oxide 4-Carene,[1S,3R,6R,(-)]-4-Carene,(1S,3R)-CIS-4-CARENE (±)-Car-3-ene-2,5-dione Carene-4 (1S)-(+)-3-Carene CARENE, (1S-cis)-2-(SG) CIS-CARENE

  • (1S)-(+)-car-3-ene
  • (+)-3-CARENE
  • (1S)-3,7,7-TRIMETHYLBICYCLO[4.1.0]HEPT-3-ENE
  • (1S)-(+)-3-CARENE
  • (+)-3-CARENE, TERPENE STANDARD
  • Bicyclo4.1.0hept-3-ene, 3,7,7-trimethyl-, (1S,6R)-
  • (+)-3-Carene, (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene
  • (1S,6R)-3-Carene
  • (1S,6α)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene
  • (1α,6α)-3,7,7-Trimethylbicyclo[4.1.0]hepta-3-ene
  • 3-Carene, (1S,6R)-(+)-
  • Bicyclo(4.1.0)hept-3-ene, 3,7,7-trimethyl-, (1S)-
  • Einecs 207-856-6
  • (1S)-(+)-3-Carene,(+)-3-Carene, (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene
  • (1S)-(+)-3-Carene 99%
  • (+)-3-CARENE SOLUTION
  • (+)-3-Δ-CARENE
  • (1S)-(+)-3-Carene Solution
  • (+)-3-Carene@100 μg/mL in Methanol
  • (+)-3-delta-Carene
  • (+)-car-3-ene
  • (+)-3-Carene
  • (+)-D-3-Carene
  • (+)-3-Carene 1000 μg/mL in Isopropanol
  • ()-3-Carene
  • (+)-Δ-3-Carene
  • (+)-Δ-3-Carene-RM
  • CA11042000 (1S,6R)-3-Carene
  • 498-15-7
  • Terpenes
  • Bicyclic Monoterpenes
  • Chiral Building Blocks
  • CA - CG
  • Asymmetric Synthesis
  • Analytical Standards
  • Analytical Chromatography Product Catalog
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