(1S)-(+)-3-Carene

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(1S)-(+)-3-Carene

Product Name: (1S)-(+)-3-Carene
CAS No.: 498-15-7
Chemical Name: (1S)-(+)-3-Carene
Synonyms: (+)-3-CARENE;(+)-3-Carene;(1S,6R)-3-Carene;()-3-Carene;(+)-car-3-ene;(+)-3-Δ-CARENE;(+)-D-3-Carene;Einecs 207-856-6;(1S)-(+)-3-CARENE;(1S)-(+)-car-3-ene
CBNumber: CB3208717
Molecular Formula: C10H16
Formula Weight: 136.23
MOL File: 498-15-7.mol

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(1S)-(+)-3-Carene Property

Melting point:: 25°C (estimate)
Boiling point:: 170-172 °C(lit.)
alpha: 17 º (NEAT)
Density: 0.865 g/mL at 25 °C(lit.)
vapor pressure: 2.73hPa at 20℃
refractive index: n20/D 1.473
Flash point:: 131 °F
storage temp.: -20°C
solubility: soluble in Acetone,Ethanol,Benzene
form: liquid (clear)
color: clear very slightly yellow
Odor: sweet
optical activity: [α]20/D +17°, neat
Water Solubility: 3.7mg/L at 20℃
Merck: 14,1836
BRN: 1902767
LogP: 4.38 at 37℃
CAS DataBase Reference: 498-15-7(CAS DataBase Reference)
NIST Chemistry Reference: Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S)-(498-15-7)
EPA Substance Registry System: Bicyclo[4.1.0]hept-3-ene, 3,7,7-trimethyl-, (1S,6R)- (498-15-7)

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Safety

Hazard Codes: Xi,N
Risk Statements: 10-50/53-43
Safety Statements: 36/37-60-61
RIDADR: UN 2319 3/PG 3
WGK Germany: 2
RTECS: FH8400000
F: 10-23
HS Code: 2902.19.0050
HazardClass: 3
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 21986
Product name: (+)-3-Carene
Purity: analytical standard
Packaging: 5ml
Price: $147
Updated: 2024/03/01

Sigma-Aldrich

Product number: 00410590
Product name: (+)-3-δ-Carene
Purity: primary reference standard
Packaging: 100mg
Price: $314
Updated: 2023/06/20

Sigma-Aldrich

Product number: CRM40416
Product name: (+)-3-Carene solution
Purity: certified reference material, 2000?μg/mL in methanol, ampule of 1?mL
Packaging: 1mL
Price: $159
Updated: 2022/05/15

TCI Chemical

Product number: C0047
Product name: (+)-3-Carene
Purity: >90.0%(GC)
Packaging: 25mL
Price: $24
Updated: 2024/03/01

TCI Chemical

Product number: C0047
Product name: (+)-3-Carene
Purity: >90.0%(GC)
Packaging: 500mL
Price: $76
Updated: 2024/03/01

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(1S)-(+)-3-Carene Chemical Properties,Usage,Production

Uses

Chiral building block for the preparation of bicyclo[3.2.0]heptenes that are useful intermediates in the synthesis of (+)-lineatin and both enantiomers of capnellene. Has been converted to its corresponding allenyl allylic ether for studies of its thermal isomerization chemistry. Precursor to di(4-isocaranyl)borane, an asymmetric hydroboration reagent for olefins.

Production Methods

3-Carene is obtained exclusively by fractional distillation of certain turpentines.

Definition

ChEBI: A car-3-ene (3,7,7-trimethylbicyclo[4.1.0]hept-3-ene) that has S configuration at position 1 and R configuration at position 6.

General Description

(1S)-(+)-3-Carene is a monoterpene.

Chemical Reactivity

3-Carene readily undergoes autoxidation and resinification in air. Addition of pyrogallol or resorcinol as stabilizers is recommended. On treatment with peracetic acid in glacial acetic acid and subsequent saponification, 3-carene is oxidized to 3,4- caranediol. Pyrolysis at 300–580 ℃ in the presence of Fe(III) oxide on carriers gives p-cymene as the main product.

(1S)-(+)-3-Carene Preparation Products And Raw materials

Raw materials

Benzotrifluoride Toluene Chlorine Ferric chloride Iron chloride hexahydrate

Preparation Products

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View Lastest Price from (1S)-(+)-3-Carene manufacturers

Career Henan Chemical Co

Product: (1S)-(+)-3-Carene 498-15-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kgs
Release date: 2020-02-13

498-15-7, (1S)-(+)-3-CareneRelated Search:

Norandrostenedione Dicyclopentadiene 6-Methyl-5-hepten-2-one Allyl methacrylate Methyl cyclopentenolone METHYLCYCLOPENTADIENE DIMER 3-CARENE 4-ACETYL CARENE (+)-2-CARENE WITH GC,CARENE, (1S-CIS)-2-,(1S-CIS)-2-CARENE,(+)-2-CARENE,2-CARENE 95+% 4-delta-carene,delta-2-Carene,delta-4-carene,2-CARENE [1S,3S,6R,(-)]-4-Carene,(1S,3S)-TRANS-4-CARENE,4-Carene, (1S, 2S, 6R)-(-)- 3-Carene oxide 4-Carene,[1S,3R,6R,(-)]-4-Carene,(1S,3R)-CIS-4-CARENE (±)-Car-3-ene-2,5-dione Carene-4 (1S)-(+)-3-Carene CARENE, (1S-cis)-2-(SG) CIS-CARENE

(1S)-(+)-car-3-ene

(+)-3-CARENE

(1S)-3,7,7-TRIMETHYLBICYCLO[4.1.0]HEPT-3-ENE

(1S)-(+)-3-CARENE

(+)-3-CARENE, TERPENE STANDARD

Bicyclo4.1.0hept-3-ene, 3,7,7-trimethyl-, (1S,6R)-

(+)-3-Carene, (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene

(1S,6R)-3-Carene

(1S,6α)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene

(1α,6α)-3,7,7-Trimethylbicyclo[4.1.0]hepta-3-ene

3-Carene, (1S,6R)-(+)-

Bicyclo(4.1.0)hept-3-ene, 3,7,7-trimethyl-, (1S)-

Einecs 207-856-6

(1S)-(+)-3-Carene,(+)-3-Carene, (1S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene

(1S)-(+)-3-Carene 99%

(+)-3-CARENE SOLUTION

(+)-3-Δ-CARENE

(1S)-(+)-3-Carene Solution

(+)-3-Carene@100 μg/mL in Methanol

(+)-3-delta-Carene

(+)-car-3-ene

(+)-3-Carene

(+)-D-3-Carene

(+)-3-Carene 1000 μg/mL in Isopropanol

()-3-Carene

498-15-7

Terpenes

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Chiral Building Blocks

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Asymmetric Synthesis

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