ChemicalBook > CAS DataBase List > 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane

Product Name
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
CAS No.
3345-29-7
Chemical Name
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
Synonyms
AC1L3BM1;PARYLENE HT;Parylene-AF4;Parylene HT/AF4;Parylene AF4/HT;2,2,3,3,8,8,9,9-Octa;parylene AF4(parylene HT);2,2,3,3,8,8,9,9-octafluoro-;1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane;2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene
CBNumber
CB32128628
Molecular Formula
C16H8F8
Formula Weight
352.22
MOL File
3345-29-7.mol
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1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane Property

Melting point:
240-250°C
Boiling point:
259.3±40.0 °C(Predicted)
Density 
1.47±0.1 g/cm3(Predicted)
form 
powder
InChI
InChI=1S/C16H8F8/c17-13(18)9-1-2-10(4-3-9)14(19,20)16(23,24)12-7-5-11(6-8-12)15(13,21)22/h1-8H
InChIKey
KCKIWSAAWFKXMA-UHFFFAOYSA-N
SMILES
C12C=CC(=CC=1)C(F)(F)C(F)(F)C1C=CC(=CC=1)C(F)(F)C2(F)F
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
799297
Product name
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
Packaging
1g
Price
$218.4
Updated
2024/03/01
SynQuest Laboratories
Product number
1700-3-88
Product name
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
Purity
99.0%
Packaging
5G
Price
$495
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-3-88
Product name
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
Purity
99.0%
Packaging
250mg
Price
$95
Updated
2021/12/16
SynQuest Laboratories
Product number
1700-3-88
Product name
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
Purity
99.0%
Packaging
1g
Price
$195
Updated
2021/12/16
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1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane Chemical Properties,Usage,Production

Uses

Parylen AF4 is extremely useful in high temperature applications and those in which long-term UV stability is required.

  • Aerospace
  • Military
  • Electronic
  • Medical
  • Industrial
  • Semiconductor (3D IC TSV electrical insulation , AMOLED De-bonding layer , Barrier layer )
  • Bio-MEMS electrode protection film
  • EWD (Electro Wetting Device) Liquid lens

Preparation

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane is synthesised using 1,4-Bis(bromodifluoromethyl)benzene as a raw material by chemical reaction.

Application

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane can be used:
(1) cross-coupling reactions. 4-iodo-1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane is successfully coupled to a variety of arylboronic acids and boronic acid pinacol esters with the exception of sterically-demanding systems such as mesityl. Using the standard Suzuki method, dicyclophane containing two octafluoro[2.2]paracyclophane units separated by one and two benzene rings can be prepared.
(2) Spectroscopic studies. It is an isomer of 1-fluorocyclopropane and has a shorter reaction time compared to 1-fluorocyclopropane. The spectral properties of this compound are similar to those of 1-fluorocyclopropane. Its mass spectrum shows peaks corresponding to molecular ions with m/e=256 and its fragmentation pattern corresponds to monosubstituted aromatic hydrocarbons.

General Description

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane is a synthetic chemical compound used in cross-coupling reactions. It is an isomer of the more common 1-fluorocyclopropane and has been shown to have a shorter reaction time than 1-fluorocyclopropane. The compound's spectroscopic properties are similar to those of 1-fluorocyclopropane. The compound was synthesized by reacting nitrobenzene with cyclopentadiene in the presence of boronic acids and aluminum chloride. The mass spectrum of this compound shows peaks corresponding to the molecular ion at m/e=256, and its fragmentation pattern corresponds to a monosubstituted aromatic hydrocarbon.

General Description

Characteristics of Parylen AF4 coating:
Specialties:

  • Unmatched UV stability
  • Excellent thermal stability at high service temperature (350)
  • Unmatched oxidation stability
  • Completely conformal coating
  • Superior crevice penetration, pin hole free
  • Anti-saline damage
  • Anti-stick ion

Barrier properties:
  • Chemical insolubility and solvent resistant
  • Low water absorption
  • Hydrophobic properties
  • Low gas permeability , no out-gassing

Physical & mechanical properties:
  • Transparent
  • Light-weight and ultra-thin
  • Low CTE
  • Low coefficient of friction
  • Good dry lubricity
  • Abrasion resistance
  • Stabilization of components and structures
  • Particulate immobilization

Electrical properties:
  • Electrical insulation
  • High dielectric strength
  • High volume resistivity ,ohm-cm
  • Low dissipation factor
  • Low dielectric constant
  • Mitigation of tin whisker growth

Biocompatibility and bio-stability
  • USP class VI
  • Microorganism resistance

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane Suppliers

Suzhou yacoo science co.,Ltd
Tel
0512-87182056 13451648594
Fax
0512-87182056
Email
sales@yacoo.com.cn
Country
China
ProdList
4578
Advantage
58
Shanghai QiXin New Materials Technology Co.,Ltd
Tel
+86 181 2706 2053 18127062053
Email
derrickguo@sh-qixin.cn
Country
China
ProdList
59
Advantage
58
SHENZHEN FCD TECHNOLOGY CO., LTD
Tel
0755-28747669 18668616292
Email
fcd-sd@fcdtech.com
Country
China
ProdList
6
Advantage
58
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
Advantage
58
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58
Finetech Industry Limited
Tel
027-87465837 19945049750
Fax
027-8777-2287
Email
sales@finetechnology-ind.com
Country
China
ProdList
9648
Advantage
58
Suzhou yacoo science co.,Ltd
Tel
0512-87182056 18013166090
Fax
0512-87182056
Email
lingling.qi@yacoo.com.cn
Country
China
ProdList
7295
Advantage
60
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
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View Lastest Price from 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane manufacturers

Shenzhen FCD Technology Co., Ltd
Product
Parylene AF4 3345-29-7
Price
US $0.00-0.00/g
Min. Order
100g
Purity
99.7%
Supply Ability
100kg
Release date
2024-11-06
Hebei Yanxi Chemical Co., Ltd.
Product
AC1L3BM1 3345-29-7
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100kg
Release date
2023-09-15
Shaanxi Dideu Medichem Co. Ltd
Product
1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane 3345-29-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-07-18

3345-29-7, 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophaneRelated Search:


  • 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
  • Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 2,2,3,3,8,8,9,9-octafluoro-
  • 2,2,3,3,8,8,9,9-Octa
  • PARYLENE HT
  • Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 2,2,3,3,8,8,9,9-octafluoro Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, octafluoro
  • parylene AF4(parylene HT)
  • 2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene
  • Parylene-AF4
  • AC1L3BM1
  • TIANFU-CHEM CAS:3345-29-7 2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene
  • 2,2,3,3,8,8,9,9-octafluoro-
  • Parylene HT/AF4
  • Parylene AF4/HT
  • 3345-29-7
  • C16H8F8