Parylene N

Product Name: Parylene N
CAS No.: 1633-22-3
Chemical Name: Parylene N
Synonyms: Paracyclophane;1,4(1,4)-dibenzenacyclohexaphane;parylene N;PCF;DI-P-XYLYLENE;DI-P-XYLENE;PLANYLENE N;Paracyclophan;Di-1,4-xylylene;Parylene N ,99%
CBNumber: CB4691420
Molecular Formula: C16H16
Formula Weight: 208.3
MOL File: 1633-22-3.mol

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Parylene N Property

Melting point:: 285-288 °C(lit.)
Boiling point:: 282.51°C (rough estimate)
Density: 1.0102 (estimate)
vapor pressure: 0.001Pa at 25℃
refractive index: 1.5000 (estimate)
storage temp.: Sealed in dry,Room Temperature
form: powder to crystal
color: White to Almost white
Water Solubility: INSOLUBLE
BRN: 1910888
InChI: InChI=1S/C16H16/c1-2-14-4-3-13(1)9-10-15-5-7-16(8-6-15)12-11-14/h1-8H,9-12H2
InChIKey: OOLUVSIJOMLOCB-UHFFFAOYSA-N
SMILES: C12C=CC(=CC=1)CCC1C=CC(=CC=1)CC2
LogP: 5.14 at 20℃
NIST Chemistry Reference: [2.2]Paracyclophane(1633-22-3)
EPA Substance Registry System: Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (1633-22-3)

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Safety

Hazard Codes: Xi,C,F
Risk Statements: 11-34
Safety Statements: 24/25-45-36/37/39-26-16
WGK Germany: 3
RTECS: YD2404000
Hazard Note: Irritant
TSCA: Yes
HS Code: 29029080

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: P225
Product name: [2.2]Paracyclophane
Purity: 97%
Packaging: 5G
Price: $36.4
Updated: 2024/03/01

TCI Chemical

Product number: P1165
Product name: [2.2]Paracyclophane
Purity: >99.0%(GC)
Packaging: 1g
Price: $99
Updated: 2024/03/01

Alfa Aesar

Product number: B20136
Product name: [2.2]Paracyclophane, 99%
Packaging: 1g
Price: $54.65
Updated: 2024/03/01

Alfa Aesar

Product number: B20136
Product name: [2.2]Paracyclophane, 99%
Packaging: 5g
Price: $201
Updated: 2024/03/01

TRC

Product number: P205825
Product name: [2.2]Paracyclophane
Packaging: 50mg
Price: $60
Updated: 2021/12/16

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Parylene N Chemical Properties,Usage,Production

Description

[2.2]Paracyclophane is used as an intermediate in organic synthesis or as a reagent in chemical reactions. It serves as the structural backbone of 4-toluenesulfinyl [2.2]p-dicyclohexane and can be used in the synthesis of various mono- and disubstituted [2.2]p-dicyclohexane derivatives. It can also be used for the preparation of metal complexes, and the interaction of the Ag+ cation with the cation -π of [2.2]paracyclophane can be used to synthesise Ag+ - [2.2]paracyclophane complexes using the Ag+ cation. The complex is formed by binding the cation Ag+ to three carbon atoms on a benzene ring of the [2.2]paracyclophane ligand using a cation-π interaction^[1].

Chemical Properties

WHITE TO LIGHT BEIGE CRYSTALS OR CRYSTAL. POWDER

Uses

2,2]-Paracyclophane is the raw material for the synthesis of parylene which is widely used in microelectronic integrated circuit.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 1043, 1981 DOI: 10.1021/jo00318a047

Flammability and Explosibility

Not classified

Purification Methods

Purify it by recrystallisation from AcOH. 1H-NMR : 1.62 (Ar-H) and -1.71 (CH2) [Waugh & Fessenden J Am Chem Soc 79 846 1957, IR and UV: Cram et al. J Am Chem Soc 76 6132 1954, Cram & Steinberg J Am Chem Soc 73 5691 1951. It complexes with unsaturated compounds: Cram & Bauer J Am Chem Soc 81 5971 1959, Syntheses: Brink Synthesis 807 1975, Givens et al. J Org Chem 44 16087 1979, Kaplan et al. Tetrahedron Lett 3665 1976]. [Beilstein 5 IV 2223.]

References

[1] DR. PETR VA?URA; Dr. T U; Prof David Sykora. Interaction of the Silver(I) Cation with [2.2]Paracyclophane: Experimental and Theoretical Study[J]. ChemistrySelect, 2022. DOI:10.1002/slct.202203008.

Parylene N Preparation Products And Raw materials

Raw materials

Preparation Products

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Parylene N Suppliers

Americas 1 Belgium 1 China 233 Czech 1 Europe 1 Germany 5 India 3 Japan 2 South Korea 2 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 10 United States 29 Global 291

Jiangsu Qiaoqi Chemical Co., Ltd

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INTATRADE GmbH

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

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Suzhou Chireach Biomedical Technology Co., Ltd.

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View Lastest Price from Parylene N manufacturers

Shenzhen FCD Technology Co., Ltd

Product: Parylene N UVtrace 1633-22-3
Price: US $0.00-0.00/g
Min. Order: 500g
Purity: 99.7%
Supply Ability: 100kg
Release date: 2024-12-17

Shenzhen FCD Technology Co., Ltd

Product: [2.2]Paracyclophane,Parylene N Dimer 1633-22-3
Price: US $0.00-0.00/g
Min. Order: 500g
Purity: 99.7%
Supply Ability: 100kg
Release date: 2024-07-10

Shenzhen FCD Technology Co., Ltd

Product: Parylene N 1633-22-3
Price: US $0.00-0.00/g
Min. Order: 500g
Purity: 99.7%
Supply Ability: 100kg
Release date: 2024-07-12

1633-22-3, Parylene NRelated Search:

1,2,5,6,9,10-Hexabromocyclododecane C36 Dimer acid CYCLODODECANE P-XYLENE P-MENTHANE Poly(dimethylsiloxane) POLY(ETHYLENE TEREPHTHALATE) Dichlorodi-p-xylylene (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE racemic-4,12-Dihydroxy[2.2]paracyclophane,min.97% Racemic-4,12-dibromo[2.2]paracyclophane DICHLORO[(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2,2]-PARACYCLOPHANE][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM Dichloro[2,2]paracyclophane (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS poly-p-xylene 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane (R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS 4,16-DIBROMO[2.2]PARACYCLOPHANE

TRICYCLO[8.2.2.24,7]HEXADECA-4,6,10,12,13,15-HEXAENE

TRICYCLO[8.2.2.2]HEXADECA-4,6,10,12,13,15-HEXAENE

[2.2]paracylophan

Cyclobis(benzene-1,4-dimethylene)

Di-1,4-xylylene

Tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene

4,4'-DIMETHYLENE-1,2-DIPHENYLETHANE

[2.2]PARACYCLOPHAN

[2.2]PARACYCLOPHANE

DI-P-XYLENE

DI-P-XYLYLENE

[2.2]Paracylophane

Tricyclo[8,2,2,24,7]hexadeca-4,6,1,12,13,15-hexaene

Parylene N ([2,2]Paracyclophane)

(2.2)PARACYCLOPHAN 97%

[2.2]-PARACYCLOPHANE 99+%

DI-PARA-XYLYLENE

PCF

Dimer,Parylene N

Parylene N ,99%

[2.2](1,4)Cyclophane

Di-p-xylylene Tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaene

Tricyclo[8,2,2,2]4,7 hexa-4,6,10,12,13,15-decane

2.2ü-Paracyclophane, 99%

4,4'-Ethylene(1,1'-ethylenebisbenzene)

Dicyclo-p-xylylene

Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12(1),13,15-hexaene

[2.2]Paracyclophane,98%

PLANYLENE N

Paracyclophane

[2.2]-paracyclophane (Parylene N)

Paracyclophan

TwodiMericp-xylene

[2.2]Paracyclophane&gt

1,4(1,4)-dibenzenacyclohexaphane

Parylene N dimer

tricyclo[8.2.2.2??]hexadeca-1(13),4(16),5,7(15),10(14),11-hexaene

Di-p-xylylene, Parylene N

[2.2]Paracyclophane,Parylene N Dimer

parylene N

Parylene N UVtrace

1633-22-3

C16H16

Organic Building Blocks

Cyclophanes

Macrocycles for Host-Guest Chemistry

Building Blocks

Arenes

coating

Arenes

Building Blocks

Chemical Synthesis

Organic Building Blocks

fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials

Cyclophanes

Functional Materials

Macrocycles for Host-Guest Chemistry

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