Parylene N
- Product Name
- Parylene N
- CAS No.
- 1633-22-3
- Chemical Name
- Parylene N
- Synonyms
- Paracyclophane;1,4(1,4)-dibenzenacyclohexaphane;parylene N;PCF;DI-P-XYLYLENE;DI-P-XYLENE;PLANYLENE N;Paracyclophan;Di-1,4-xylylene;Parylene N ,99%
- CBNumber
- CB4691420
- Molecular Formula
- C16H16
- Formula Weight
- 208.3
- MOL File
- 1633-22-3.mol
Parylene N Property
- Melting point:
- 285-288 °C(lit.)
- Boiling point:
- 282.51°C (rough estimate)
- Density
- 1.0102 (estimate)
- vapor pressure
- 0.001Pa at 25℃
- refractive index
- 1.5000 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- White to Almost white
- Water Solubility
- INSOLUBLE
- BRN
- 1910888
- InChI
- InChI=1S/C16H16/c1-2-14-4-3-13(1)9-10-15-5-7-16(8-6-15)12-11-14/h1-8H,9-12H2
- InChIKey
- OOLUVSIJOMLOCB-UHFFFAOYSA-N
- SMILES
- C12C=CC(=CC=1)CCC1C=CC(=CC=1)CC2
- LogP
- 5.14 at 20℃
- NIST Chemistry Reference
- [2.2]Paracyclophane(1633-22-3)
- EPA Substance Registry System
- Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (1633-22-3)
Safety
- Hazard Codes
- Xi,C,F
- Risk Statements
- 11-34
- Safety Statements
- 24/25-45-36/37/39-26-16
- WGK Germany
- 3
- RTECS
- YD2404000
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29029080
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- P225
- Product name
- [2.2]Paracyclophane
- Purity
- 97%
- Packaging
- 5G
- Price
- $36.4
- Updated
- 2024/03/01
- Product number
- P1165
- Product name
- [2.2]Paracyclophane
- Purity
- >99.0%(GC)
- Packaging
- 1g
- Price
- $99
- Updated
- 2024/03/01
- Product number
- B20136
- Product name
- [2.2]Paracyclophane, 99%
- Packaging
- 1g
- Price
- $54.65
- Updated
- 2024/03/01
- Product number
- B20136
- Product name
- [2.2]Paracyclophane, 99%
- Packaging
- 5g
- Price
- $201
- Updated
- 2024/03/01
- Product number
- P205825
- Product name
- [2.2]Paracyclophane
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
Parylene N Chemical Properties,Usage,Production
Description
[2.2]Paracyclophane is used as an intermediate in organic synthesis or as a reagent in chemical reactions. It serves as the structural backbone of 4-toluenesulfinyl [2.2]p-dicyclohexane and can be used in the synthesis of various mono- and disubstituted [2.2]p-dicyclohexane derivatives. It can also be used for the preparation of metal complexes, and the interaction of the Ag+ cation with the cation -π of [2.2]paracyclophane can be used to synthesise Ag+ - [2.2]paracyclophane complexes using the Ag+ cation. The complex is formed by binding the cation Ag+ to three carbon atoms on a benzene ring of the [2.2]paracyclophane ligand using a cation-π interaction[1].
Chemical Properties
WHITE TO LIGHT BEIGE CRYSTALS OR CRYSTAL. POWDER
Uses
2,2]-Paracyclophane is the raw material for the synthesis of parylene which is widely used in microelectronic integrated circuit.
Synthesis Reference(s)
The Journal of Organic Chemistry, 46, p. 1043, 1981 DOI: 10.1021/jo00318a047
Flammability and Explosibility
Not classified
Purification Methods
Purify it by recrystallisation from AcOH. 1H-NMR : 1.62 (Ar-H) and -1.71 (CH2) [Waugh & Fessenden J Am Chem Soc 79 846 1957, IR and UV: Cram et al. J Am Chem Soc 76 6132 1954, Cram & Steinberg J Am Chem Soc 73 5691 1951. It complexes with unsaturated compounds: Cram & Bauer J Am Chem Soc 81 5971 1959, Syntheses: Brink Synthesis 807 1975, Givens et al. J Org Chem 44 16087 1979, Kaplan et al. Tetrahedron Lett 3665 1976]. [Beilstein 5 IV 2223.]
References
[1] DR. PETR VA?URA; Dr. T U; Prof David Sykora. Interaction of the Silver(I) Cation with [2.2]Paracyclophane: Experimental and Theoretical Study[J]. ChemistrySelect, 2022. DOI:10.1002/slct.202203008.
Parylene N Preparation Products And Raw materials
Raw materials
Preparation Products
Parylene N Suppliers
- Tel
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- Country
- Switzerland
- ProdList
- 6896
- Advantage
- 91
View Lastest Price from Parylene N manufacturers
- Product
- [2.2]Paracyclophane 1633-22-3
- Price
- US $0.00-0.00/Kg/Drum
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 TONS
- Release date
- 2021-06-16
- Product
- Parylene N 1633-22-3
- Price
- US $0.00-0.00/g
- Min. Order
- 500g
- Purity
- 99.7%
- Supply Ability
- 100kg
- Release date
- 2024-07-12
- Product
- [2.2]Paracyclophane,Parylene N Dimer 1633-22-3
- Price
- US $0.00-0.00/g
- Min. Order
- 500g
- Purity
- 99.7%
- Supply Ability
- 100kg
- Release date
- 2024-07-10