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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE

Product Name
METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE
CAS No.
26107-80-2
Chemical Name
METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE
Synonyms
BUTTPARK 89\07-68;RARECHEM AL BF 0207;Methyl 3,5-bis(trifluoromethyl);METHYL 3,5-DI(TRIFLUOROMETHYL)BENZOATE;METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE;Methyl3,5-bis(trifluoromethyl)benzoate98%;Methyl 3,5-bis(trifluoromethyl)benzoate 98%;3,5-BIS(TRIFLUOROMETHYL)BENZOIC ACID METHYL ESTER;Benzoic acid, 3,5-bis(trifluoromethyl)-, methyl ester
CBNumber
CB3212910
Molecular Formula
C10H6F6O2
Formula Weight
272.14
MOL File
26107-80-2.mol
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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Property

Boiling point:
85 °C
Density 
1.400±0.06 g/cm3 (20 ºC 760 Torr)
Flash point:
85-87°C/15mm
storage temp. 
Sealed in dry,Room Temperature
Appearance
Colorless to light yellow Liquid
CAS DataBase Reference
26107-80-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
Hazard Note 
Irritant
HS Code 
2916310090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
M337685
Product name
Methyl3,5-bis(Trifluoromethyl)benzoate
Packaging
50mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
002681
Product name
Methyl 3,5-bis(trifluoromethyl)benzoate
Purity
98%
Packaging
5g
Price
$9
Updated
2021/12/16
AK Scientific
Product number
J50373
Product name
Methyl3,5-bis(trifluoromethyl)benzoate
Packaging
1g
Price
$10
Updated
2021/12/16
AK Scientific
Product number
W4943
Product name
Methyl3,5-bis(trifluoromethyl)benzoate
Packaging
1g
Price
$14
Updated
2021/12/16
AK Scientific
Product number
J50373
Product name
Methyl3,5-bis(trifluoromethyl)benzoate
Packaging
5g
Price
$15
Updated
2021/12/16
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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Chemical Properties,Usage,Production

Synthesis

67-56-1

401-96-7

26107-80-2

To the reaction system was added 25.9 g (0.8 mol) of methanol, and after chlorine-fluorine exchange using HF according to the method of Example 2, 13.8 g (0.053 mol) of 3,5-bis(trifluoromethyl)benzoyl fluoride fraction was obtained, which was added slowly and dropwise to the reaction system over 60 minutes. Subsequently, the reaction mixture was stirred at 40°C for 4 hours. The generation of 14.2 g (0.052 mol) of methyl 3,5-bis(trifluoromethyl)benzoate was confirmed by gas chromatographic analysis (yield: 98%, selectivity: 100%). By vacuum distillation, 13.9 g (0.05 mol) of methyl 3,5-bis(trifluoromethyl)benzoate was isolated (yield: 96%). Examples 17-31 Various (fluoroalkyl)benzene derivatives were prepared with reference to the methods of Examples 2-16. To improve the purity of the product, Example 17 was purified by crystallization twice, and the final distillation step was repeated in the remaining Examples. The purity, residual halogen content and residual metal content of all (fluoroalkyl)benzene derivatives are summarized in Table 2.

References

[1] Patent: EP1500641, 2005, A1. Location in patent: Page 10; 15

METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
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China
ProdList
96815
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
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China
ProdList
30123
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Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
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China
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44801
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Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2806
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Wuhan Chemwish Technology Co., Ltd
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86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
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Beijing Ouhe Technology Co., Ltd
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010-010-82967028 13522913783
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+86-10-82967029
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2355560935@qq.com
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China
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Shanghai Sinch Parmaceuticals Tech. Co. Ltd.
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+86-21-54098501
Fax
+86-21-54096319
Email
sales@sinch.com.cn
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China
ProdList
11598
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Shanghai Harvest Chemical Industrial Co., Ltd.
Tel
021-31038972,31038973 17321035817
Fax
+86-21-51385350
Email
sales@harvest-chem.com
Country
China
ProdList
2816
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64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
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View Lastest Price from METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE manufacturers

Career Henan Chemical Co
Product
METHYL 3,5-BIS(TRIFLUOROMETHYL)BENZOATE 26107-80-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2020-03-05